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Thallium Oxide Nanoparticles / Nanopowder

Tl2O3

MDL Number:

MFCD00011276

EC No.:

215-229-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Thallium Oxide Nanopowder
TL-OX-02-NP
Pricing > SDS > Data Sheet >
(3N) 99.9% Thallium Oxide Nanopowder
TL-OX-03-NP
Pricing > SDS > Data Sheet >
(4N) 99.99% Thallium Oxide Nanopowder
TL-OX-04-NP
Pricing > SDS > Data Sheet >
(5N) 99.999% Thallium Oxide Nanopowder
TL-OX-05-NP
Pricing > SDS > Data Sheet >

Thallium Oxide Nanoparticles / Nanopowder Properties

Compound Formula

O3Tl2

Molecular Weight

456.76

Appearance

Dark brown or black powder

Melting Point

717° C

Boiling Point

875° C

Density

10.19 g/cm3

Exact Mass

457.933599

Monoisotopic Mass

457.933599

Thallium Oxide Nanoparticles / Nanopowder Health & Safety Information

Signal Word Danger
Hazard Statements H300 + H330-H373-H411
Hazard Codes T+,N
Precautionary Statements P260-P264-P273-P284-P301 + P310-P310
Risk Codes 26/28-33-51/53
Safety Statements 13-28-45-61
RTECS Number XG2975000
Transport Information UN 1707 6.1 / PGII
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/17/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Thallium Oxide Nanoparticles / Nanopowder

Product Number: All applicable American Elements product codes, e.g. TL-OX-02-NP , TL-OX-03-NP , TL-OX-04-NP , TL-OX-05-NP

CAS #: 1314-32-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS06 Skull and crossbones
Acute Tox. 2 H300 Fatal if swallowed.
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
STOT RE 2 H373 May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Skull and Crossbones - GHS06 Health Hazard - GHS08

GHS06 GHS08
Signal word Danger
Hazard statements
H300+H330 Fatal if swallowed or if inhaled.
H373 May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/…
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3

1
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
1314-32-5 Thallium(III) oxide
Identification number(s):
EC number: 215-229-3
Index number: 081-002-00-9


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Do not induce vomiting; immediately call for medical help.
Information for doctor
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released:
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use self-contained respiratory protective device in emergency situations.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) Not determined
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder or solid in various forms
Color: Brown to black
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 717 °C (1323 °F)
Boiling point/Boiling range: 875 °C (1607 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 9.65 g/cm³ (80.529 lbs/gal)
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Not determined
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No information known.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No further relevant information available.
Incompatible materials: Oxidizing agents


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Fatal if inhaled.
Fatal if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification:
Oral LD50 44 mg/kg (rat)
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Toxic for aquatic organisms
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN1707
UN proper shipping name
DOT Thallium compounds, n.o.s. (Thallium(III) oxide)
IMDG THALLIUM COMPOUND, N.O.S. (Thallium(III) oxide), MARINE POLLUTANT
IATA THALLIUM COMPOUND, N.O.S. (Thallium(III) oxide)
Transport hazard class(es)
DOT
Class 6.1 Toxic substances.
Label 6.1
Class 6.1 (T5) Toxic substances
Label 6.1
IMDG
Class 6.1 Toxic substances.
Label 6.1
IATA
Class 6.1 Toxic substances.
Label 6.1
Packing group
DOT, IMDG, IATA II
Environmental hazards: Environmentally hazardous substance, solid; Marine Pollutant
Marine pollutant (IMDG): Symbol (fish and tree)
Special precautions for user Warning: Toxic substances
EMS Number: F-A,S-A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
Remarks: Special marking with the symbol (fish and tree).
UN "Model Regulation": UN1707, Thallium compounds, n.o.s. (Thallium(III) oxide), 6.1, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS06 GHS08
Signal word Danger
Hazard statements
H300+H330 Fatal if swallowed or if inhaled.
H373 May cause damage to the blood through prolonged or repeated exposure. Route of exposure: Oral.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/…
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
1314-32-5 Thallium(III) oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Thallium Oxide Nanoparticles / Nanopowder

Thallium Oxide (Tl2O3) Nanopowder or Nanoparticles, nanodots or nanocrystals are spherical or faceted high surface area oxide magnetic nanostructured particles. Nanoscale Thallium Oxide Particles are typically 20-80 nanometers (nm) with specific surface area (SSA) in the 10 - 50 m2/g range and also available in with an average particle size of 100 nm range with a specific surface area of approximately 7- 10 m2/g. Nano Thallium Oxide Particles are also available in ultra high purity and high purity, transparent, and coated and dispersed forms. They are also available as a nanofluid through the AE Nanofluid production group. Nanofluids are generally defined as suspended nanoparticles in solution either using surfactant or surface charge technology. Nanofluid dispersion and coating selection technical guidance is also available. Other nanostructures include nanorods, nanowhiskers, nanohorns, nanopyramids and other nanocomposites. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers.

Thallium Oxide Nanoparticles / Nanopowder Synonyms

Thallium(III) oxide; Thallic oxide; Dithallium trioxide; Thallium(3+) oxide; Thallium oxide; oxo(oxothallanyloxy)thallane

Thallium Oxide Nanoparticles / Nanopowder Chemical Identifiers

Linear Formula

Tl2O3

Pubchem CID

3579754

MDL Number

MFCD00011276

EC No.

215-229-3

IUPAC Name

oxo(oxothallanyloxy)thallane

SMILES

O=[Tl]O[Tl]=O

InchI Identifier

InChI=1S/3O.2Tl

InchI Key

QTQRFJQXXUPYDI-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Thallium products. Thallium (atomic symbol: Tl, atomic number: 81) is a Block P, Group 13, Period 6 element with an atomic weight of 204.38. Thallium Bohr ModelThe number of electrons in each of thallium's shells is 2, 8, 18, 32, 18, 3 and its electron configuration is [Xe] 4f14 5d10 6s2 6p1. The thallium atom has a radius of 170 pm and a Van der Waals radius of 196 pm. Thallium was discovered by Sir William Crookes in 1861 and first isolated by Claude-Auguste Lamy in 1862. Thallium is a post-transition metal that is not found free in nature. Thallium is primarily used for its electrical conductivity as thallium sulfide, which changes with exposure to infrared light. This ability makes the compound useful in photocells. Elemental ThalliumThallium bromide-iodide crystals have been used as infrared optical materials. Thallium has also been used with sulfur, selenium or arsenic to produce low melting glasses which become fluid between 125 and 150 °C, while thallium oxide has been used to produce glasses with a high index of refraction, and is also used in the manufacture of photo cells. Its name is drived from the Greek word thallos, which means twig or green shoot.

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August 17, 2017
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