The effects of altering reaction conditions in green sonochemical synthesis of a thallium(I) coordination polymer and in achieving to different morphologies of thallium(III) oxide nanostructures via solid-state process.

Title The effects of altering reaction conditions in green sonochemical synthesis of a thallium(I) coordination polymer and in achieving to different morphologies of thallium(III) oxide nanostructures via solid-state process.
Authors Z. Hazrati; K. Akhbari; A. Phuruangrat
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.05.037
Abstract

In order to studies the effects of solvent and concentration of initial reagents on formation of [Tl(?4-AB)]n (1), [HAB=4-aminobenzoic acid] coordination polymer, some experiments were designed and four samples of 1 were synthesized by sonochemical process. High concentration of initial reagents resulted in formation of compound 1 microrods. With low concentration of initial reagents, various morphologies of 1 were obtained. These four samples had been used as new precursors for preparation of thallium(III) oxide nanostructures via solid-state thermal decomposition process. One- and two-dimensional nanostructures of thallium(III) oxide can be prepared from 1. These micro and nanostructures were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and Scanning Electron Microscopy (SEM).

Citation Z. Hazrati; K. Akhbari; A. Phuruangrat.The effects of altering reaction conditions in green sonochemical synthesis of a thallium(I) coordination polymer and in achieving to different morphologies of thallium(III) oxide nanostructures via solid-state process.. Ultrason Sonochem. 2017;39:662668. doi:10.1016/j.ultsonch.2017.05.037

Related Elements

Thallium

See more Thallium products. Thallium (atomic symbol: Tl, atomic number: 81) is a Block P, Group 13, Period 6 element with an atomic weight of 204.38. Thallium Bohr ModelThe number of electrons in each of thallium's shells is 2, 8, 18, 32, 18, 3 and its electron configuration is [Xe] 4f14 5d10 6s2 6p1. The thallium atom has a radius of 170 pm and a Van der Waals radius of 196 pm. Thallium was discovered by Sir William Crookes in 1861 and first isolated by Claude-Auguste Lamy in 1862. Thallium is a post-transition metal that is not found free in nature. Thallium is primarily used for its electrical conductivity as thallium sulfide, which changes with exposure to infrared light. This ability makes the compound useful in photocells. Elemental ThalliumThallium bromide-iodide crystals have been used as infrared optical materials. Thallium has also been used with sulfur, selenium or arsenic to produce low melting glasses which become fluid between 125 and 150 °C, while thallium oxide has been used to produce glasses with a high index of refraction, and is also used in the manufacture of photo cells. Its name is derived from the Greek word thallos, which means twig or green shoot.

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