Thulium Acetate Tetrahydrate

CAS #:

Linear Formula:

Tm(O2C2H3)3• 4H2O

MDL Number:

MFCD00150125

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Thulium Acetate Tetrahydrate
TM-AC-02-P.4HYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Thulium Acetate Tetrahydrate
TM-AC-03-P.4HYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Thulium Acetate Tetrahydrate
TM-AC-04-P.4HYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Thulium Acetate Tetrahydrate
TM-AC-05-P.4HYD
Pricing > SDS > Data Sheet >

Thulium Acetate Tetrahydrate Properties (Theoretical)

Compound Formula C6H17O10Tm
Molecular Weight 418.13
Appearance White powder
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass N/A

Thulium Acetate Tetrahydrate Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/29/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Thulium Acetate Tetrahydrate

Product Number: All applicable American Elements product codes, e.g. TM-AC-02-P.4HYD , TM-AC-03-P.4HYD , TM-AC-04-P.4HYD , TM-AC-05-P.4HYD

CAS #: 34431-47-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word Warning
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
1


Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
1


Health = 1
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
34431-47-5 Thulium(III) acetate tetrahydrate


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled: In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed: If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: No special measures required.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: No special measures required.
Methods and materials for containment and cleanup: Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling No special precautions are necessary if used correctly.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Tightly sealed goggles


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Off-white to white
Odor: No data available
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density: No data available
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Soluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Organic solvents: 0.0 %
Solids content: 100.0 %
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user N/A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code N/A
UN "Model Regulation": -


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is not listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal word Warning
Hazard-determining components of labeling:
Thulium(III) acetate tetrahydrate
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Thulium Acetate Tetrahydrate

Acetate Formula StructureThulium Acetate Tetrahydrate is a moderately water soluble crystalline Thulium source that decomposes to Thulium oxide on heating. It is generally immediately available in most volumes. All metallic acetates are inorganic salts containing a metal cation and the acetate anion, a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Acetates are excellent precursors for production of ultra high purity compounds, catalysts, and nanoscale materials. We also produce Thulium Acetate Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Thulium Acetate Tetrahydrate Synonyms

Thulium(III) acetate tetrahydrate, Thulium triacetate tetrahydrate, Thulium(3+) acetate tetrahydrate, Acetic acid, thulium(3+) salt, tetrahydrate, thulium acetate hydrate

Chemical Identifiers

Linear Formula Tm(O2C2H3)3• 4H2O
MDL Number MFCD00150125
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 57377122
IUPAC Name thulium(3+); triacetate; hydrate
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O.[Tm+3]
InchI Identifier InChI=1S/3C2H4O2.H2O.Tm/c3*1-2(3)4;;/h3*1H3,(H,3,4);1H2;/q;;;;+3/p-3
InchI Key GKCQSJXCECKBHO-UHFFFAOYSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Thulium

See more Thulium products. Thulium (atomic symbol: Tm, atomic number: 69) is a Block F, Group 3, Period 6 element with an atomic weight of 168.93421. Thulium Bohr ModelThe number of electrons in each of Thulium's shells is [2, 8, 18, 31, 8, 2] and its electron configuration is [Xe]4f136s2. The thulium atom has a radius of 176 pm and a Van der Waals radius of 227 pm.Elemental Thulium Picture In its elemental form, thulium has a silvery-gray appearance. Thulium is representative of the other lanthanides (rare earths) and similar in chemistry to yttrium. It is the least abundant of the rare earth elements. Thulium emits blue upon excitation, and is used in flat panel screens that depend critically on bright blue emitters. Thulium was discovered and first isolated by Per Teodor Cleve in 1879. It is named after "Thule," which is the ancient name of Scandinavia.

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