Thulium(III) Oxalate Hydrate

CAS #:

Linear Formula:

Tm2(C2O4)3•xH2O

MDL Number:

MFCD00150492

EC No.:

221-887-2

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Thulium(III) Oxalate Hydrate
TM-OXL-02-C.XHYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Thulium(III) Oxalate Hydrate
TM-OXL-03-C.XHYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Thulium(III) Oxalate Hydrate
TM-OXL-04-C.XHYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Thulium(III) Oxalate Hydrate
TM-OXL-05-C.XHYD
Pricing > SDS > Data Sheet >

Thulium(III) Oxalate Hydrate Properties (Theoretical)

Compound Formula C6H2O13Tm2
Molecular Weight 619.94
Appearance White solid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 619.818 g/mol
Monoisotopic Mass 619.818 g/mol
Charge N/A

Thulium(III) Oxalate Hydrate Health & Safety Information

Signal Word Warning
Hazard Statements H302-H312
Hazard Codes Xn
Precautionary Statements P280
Risk Codes 21/22
Safety Statements 24/25
RTECS Number N/A
Transport Information NONH for all modes of transport
WGK Germany 1
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Thulium(III) Oxalate Hydrate

Product Number: All applicable American Elements product codes, e.g. TM-OXL-02-C.XHYD , TM-OXL-03-C.XHYD , TM-OXL-04-C.XHYD , TM-OXL-05-C.XHYD

CAS #: 58176-73-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word Warning
Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/if you feel unwell.
P312 Call a POISON CENTER/doctor/if you feel unwell.
P363 Wash contaminated clothing before reuse.
P322 Specific measures (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
58176-73-1 Thulium (III) oxalate
Identification number(s):
EC number: 221-887-2
Index number: 607-007-00-3


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available


SECTION 5. FIREFIGHTING MEASURES


Extinguishing media
Suitable extinguishing agents Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup: Dispose of contaminated material as waste according to section 13.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: No data available
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from water/moisture.
Further information about storage conditions:
This product is hygroscopic.
Store under dry inert gas.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Crystalline
Odor: No data available
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: N/A
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density: No data available
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No data available
Incompatible materials:
Oxidizing agents
Water/moisture
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful in contact with skin.
Harmful if swallowed.
Danger through skin absorption.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Irritant to skin and mucous membranes.
Eye irritation or corrosion: Irritating effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Oxalates are powerful irritants and corrosive to tissue. They have a caustic effect on the mouth, esophagus and stomach. Readily absorbed, they can cause severe
kidney damage.
Lanthanons can cause delayed blood clotting leading to hemorrhages. Exposure may also lead to sensitivity to heat, itching, increased awareness of odor and taste,
and liver damage.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3288
UN proper shipping name
DOT Toxic solid, inorganic, n.o.s. (Thulium (III) oxalate)
IMDG, IATA TOXIC SOLID, INORGANIC, N.O.S. (Thulium (III) oxalate)
Transport hazard class(es)
DOT
Class 6.1 Toxic substances.
Label 6.1
Class 6.1 (T5) Toxic substances
Label 6.1
IMDG, IATA
Class 6.1 Toxic substances.
Label 6.1
Packing group
DOT, IMDG, IATA III
Environmental hazards: N/A
Special precautions for user Warning: Toxic substances
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3288, Toxic solid, inorganic, n.o.s. (Thulium (III) oxalate), 6.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements, including precautionary statements
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word Warning
Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/if you feel unwell.
P312 Call a POISON CENTER/doctor/if you feel unwell.
P363 Wash contaminated clothing before reuse.
P322 Specific measures (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Thulium(III) Oxalate Hydrate

Oxalate IonThulium(III) Oxalate Hydrate is highly insoluble in water and converts to the oxide when heated (calcined). Thulium(III) Oxalate Hydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Thulium emits blue upon excitation in flat panel screens and under X-ray bombardment emits both the 375 nm (ultra violet) and 465 (visible blue) wave lengths giving it useful applications in low radiation detection for detection badges and similar uses. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Thulium(III) Oxalate Hydrate Synonyms

ethanedioic acid, thulium salt (3:2:1), Thulium ethanedioate hydrate (2:3:1), oxalic acid; thulium; hydrate, dithulium trioxalate hydrate, CAS 26677-68-9 (Thulium oxalate decahydrate)

Chemical Identifiers

Linear Formula Tm2(C2O4)3•xH2O
MDL Number MFCD00150492
EC No. 221-887-2
Beilstein/Reaxys No. N/A
Pubchem CID 45052048
IUPAC Name oxalate; thulium(3+); hydrate
SMILES C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].O.[Tm+3].[Tm+3]
InchI Identifier InChI=1S/3C2H2O4.H2O.2Tm/c3*3-1(4)2(5)6;;;/h3*(H,3,4)(H,5,6);1H2;;/q;;;;2*+3/p-6
InchI Key DUELVSSHRTZSBY-UHFFFAOYSA-H

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Thulium

See more Thulium products. Thulium (atomic symbol: Tm, atomic number: 69) is a Block F, Group 3, Period 6 element with an atomic weight of 168.93421. Thulium Bohr ModelThe number of electrons in each of Thulium's shells is [2, 8, 18, 31, 8, 2] and its electron configuration is [Xe]4f136s2. The thulium atom has a radius of 176 pm and a Van der Waals radius of 227 pm.Elemental Thulium Picture In its elemental form, thulium has a silvery-gray appearance. Thulium is representative of the other lanthanides (rare earths) and similar in chemistry to yttrium. It is the least abundant of the rare earth elements. Thulium emits blue upon excitation, and is used in flat panel screens that depend critically on bright blue emitters. Thulium was discovered and first isolated by Per Teodor Cleve in 1879. It is named after "Thule," which is the ancient name of Scandinavia.

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