Tin(II) 2-Ethylhexanoate

CAS #

C16H30O4

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About

Tin 2-Ethylhexanoate is a Tin source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). Ethylhexanoates are carboxylates with many commercial applications. They are commonly used in various catalysts for oxidation, hydrogenation and polymerization and as an adhesion promoter. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Tin 2-Ethylhexanoate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Stannous Octoate, Stannous 2-ethylhexanoate, Hexanoic acid, 2-ethyl-, tin(2+) salt, tin(2+) bis(2-ethylhexanoate), Tin octoate, Stannous 2-ethylhexoate, Tin(II) 2-ethylhexanoate, Tin ethylhexanoate

Chemical Identifiers

Formula C16H30O4
CAS 301-10-0
Pubchem CID 9318
MDL MFCD00002676
EC No. 206-108-6
IUPAC Name 2-ethylhexanoate; tin(2+)
Beilstein Registry No. N/A
SMILES [Sn+4].[O-]C(=O)C(CC)CCCC.CCC(CCCC)C([O-])=O.CCC(CCCC)C([O-])=O.CCC(CCCC)C([O-])=O
InchI Identifier InChI=1S/4C8H16O2.Sn/c4*1-3-5-6-7(4-2)8(9)10;/h4*7H,3-6H2,1-2H3,(H,9,10);/q;;;;+4/p-4
InchI Key HXYDAOXNYINGCS-UHFFFAOYSA-J

Properties

Compound Formula [CH3(CH2)3CH(C2H5)CO2]2Sn
Molecular Weight 405.11
Appearance Viscous Liquid
Melting Point N/A
Boiling Point N/A
Density 1.25 g/cm3
Exact Mass 406.116606
Monoisotopic Mass 406.116606

Health & Safety Info  |  MSDS / SDS

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes 36/37/38
Safety Statements 26-36/37/39
RTECS Number MO7870000
Transport Information N/A
WGK Germany 1
Globally Harmonized System of Classification and Labelling (GHS) N/A
MSDS / SDS

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

Related Products

SnSee more Tin products. Tin (atomic symbol: Sn, atomic number: 50) is a Block P, Group 14, Period 5 element with an atomic weight of 118.710. The number of electrons in each of tin's shells is 2, 8, 18, 18, 4 and its electron configuration is [Kr] 4d10 5s2 5p2. The tin atom has a radius of 140.5 pm and a Van der Waals radius of 217 pm.In its elemental form, tin has a silvery-gray metallic appearance. It is malleable, ductile and highly crystalline. Tin has nine stable isotopes and 18 unstable isotopes. Under 3.72 degrees Kelvin, Tin becomes a superconductor. Applications for tin include soldering, plating, and such alloys as pewter. The first uses of tin can be dated to the Bronze Age around 3000 BC in which tin and copper were combined to make the alloy bronze. The origin of the word tin comes from the Latin word Stannum which translates to the Anglo-Saxon word tin. For more information on tin, including properties, safety data, research, and American Elements' catalog of tin products, visit the Tin element page.

Research

Recent Research & Development for Tin

  • Formation mechanism of rutile tio2 rods on fluorine doped tin oxide glass. Meng X, Shin DW, Yu SM, Park MH, Yang C, Lee JH, Yoo JB. J Nanosci Nanotechnol. 2014 Nov
  • Epitaxial growth of GaN nanowires with high structural perfection on a metallic TiN film. Wölz M, Hauswald C, Flissikowski T, Gotschke T, Fernandez-Garrido S, Brandt O, Grahn HT, Geelhaar L, Riechert H. Nano Lett. 2015 May 22.
  • Microstructural characteristics of tin oxide-based thin films on (0001) Al2O3 substrates: effects of substrate temperature and RF power during co-sputtering. Hwang S, Lee JH, Kim YY, Yun MG, Lee KH, Lee JY, Cho HK. J Nanosci Nanotechnol. 2014 Dec
  • Enzyme-free glucose sensor based on Au nanobouquet fabricated indium tin oxide electrode. Lee JH, El-Said WA, Oh BK, Choi JW. J Nanosci Nanotechnol. 2014 Nov
  • Voltage-Controlled Ring Oscillators Based on Inkjet Printed Carbon Nanotubes and Zinc Tin Oxide. Kim B, Park J, Geier M, Hersam MC, Dodabalapur A. ACS Appl Mater Interfaces. 2015 May 12.
  • A durable surface-enhanced Raman scattering substrate: ultrathin carbon layer encapsulated Ag nanoparticle arrays on indium-tin-oxide glass. Bian J, Li Q, Huang C, Guo Y, Zaw M, Zhang RQ. Phys Chem Chem Phys. 2015 May 18.
  • Co-solvent enhanced zinc oxysulfide buffer layers in Kesterite copper zinc tin selenide solar cells. Steirer KX, Garris RL, Li JV, Dzara MJ, Ndione PF, Ramanathan K, Repins I, Teeter G, Perkins CL. Phys Chem Chem Phys. 2015 May 22.
  • Solution-processed silver nanowire/indium-tin-oxide nanoparticle hybrid transparent conductors with high thermal stability. Hong SJ, Kim JW, Kim YH. J Nanosci Nanotechnol. 2014 Dec
  • Formation of Copper Zinc Tin Sulfide Thin Films from Colloidal Nanocrystal Dispersions via Aerosol-Jet Printing and Compaction. Williams BA, Mahajan A, Smeaton MA, Holgate CS, Aydil ES, Francis LF. ACS Appl Mater Interfaces. 2015 May 19.
  • Nanotubular Heterostructure of Tin Dioxide/Titanium Dioxide as a Binder-Free Anode in Lithium-Ion Batteries. Kim M, Lee J, Lee S, Seo S, Bae C, Shin H. ChemSusChem. 2015 Mar 20.: ChemSusChem

Recent Research & Development for Ethylhexanoates

  • The use of lead methacrylate 2-ethylhexanoate to create a radio-opaque resin suitable for microvascular corrosion casting. Burton GJ, Ingram SC, Palmer ME. J Microsc. 1986 Sep
  • Enantioselective hydrolysis of butyl 2-ethylhexanoate by a strain of Nocardia corynebacteroides. Labeda DP, Jackson MA, Kuo TM, Nakamura LK. Curr Microbiol. 2004 Aug
  • A chromium precursor for the Phillips ethylene trimerization catalyst: (2-ethylhexanoate)2CrOH. Jeon JY, Park DS, Lee DH, Eo SC, Park SY, Jeong MS, Kang YY, Lee J, Lee BY. Dalton Trans. 2015 May 21.
  • Interplay between lead carboxylate and Ti or Zr isopropoxides in solution routes to perovskites: synthesis, molecular structures and reactivity of single source non-oxo Pb-Zr and Pb-Ti carboxylatoalkoxides supported by 2-ethylhexanoate ligands. Brethon A, Hubert-Pfalzgraf LG, Daran JC. Dalton Trans. 2006 Jan 7
  • Triethylene glycol bis(2-ethylhexanoate) - a new contact allergen identified in a spectacle frame. Andersen KE, Vestergaard ME, Christensen LP. Contact Dermatitis. 2014 Feb
  • Cyclohexanediol bis-ethylhexanoate inhibits melanogenesis of murine B16 melanoma and UV-induced pigmentation in human skin. Lim JH, Park SH, Kim MR, Yoo BS, Yang JC, Cheong IW, Kim JH, Cho JH. Biol Pharm Bull. 2013
  • Murine teratology and pharmacokinetics of the enantiomers of sodium 2-ethylhexanoate. Collins MD, Scott WJ, Miller SJ, Evans DA, Nau H. Toxicol Appl Pharmacol. 1992 Feb
  • Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis. Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Özkar S, Yih KH, Johnson KA, Finke RG. Langmuir. 2011 May 17
  • Murine teratology and pharmacokinetics of the enantiomers of sodium 2-ethylhexanoate. Collins MD, Scott WJ, Miller SJ, Evans DA, Nau H. Toxicol Appl Pharmacol. 1992 Feb
  • Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis. Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Özkar S, Yih KH, Johnson KA, Finke RG. Langmuir. 2011 May 17

Free Test Sample Program

We recognize many of our customers are purchasing small quantities directly online as trial samples in anticipation of placing a larger future order or multiple orders as a raw material for production. Since our primary business is the production of industrial quantities and/or highly consistent batches which can be used for commercial production and purchased repeatedly in smaller quantity, American Elements offers trial samples at no charge on the following basis. Within 6 months of purchasing materials directly online from us, you have the option to refer back to that order and advise that it is the intention of your company, institution or lab to either purchase a larger quantity, purchase the material in regular intervals or purchase more on some other basis.

We will then evaluate your future needs and assuming the quantity or number of future purchases qualify, we will fully credit your purchase price with the next order. Because of the many variables in the quantity and number of orders you may place, it is impossible to evaluate whether your future order(s) will qualify for this program prior to your placing your next order. Please know American Elements strongly desires to make this free sample program available to you and will make every effort to do so once your next order is placed.