CAS #:

Linear Formula:

(C6H5)3SnCl

MDL Number:

MFCD00000519

EC No.:

211-358-4

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Triphenyltin Chloride
TPHLSN-CL-01-C
Pricing > SDS > Data Sheet >

Triphenyltin Chloride Properties (Theoretical)

Compound Formula C18H15ClSn
Molecular Weight 385.478
Appearance Beige solid
Melting Point 108 °C
Boiling Point 240 °C/13.5 mmHg
Density N/A
Solubility in H2O N/A
Exact Mass 385.988 g/mol
Monoisotopic Mass 385.988 g/mol

Triphenyltin Chloride Health & Safety Information

Signal Word Danger
Hazard Statements H301 + H311 + H331-H315-H318-H410
Hazard Codes T, Xn
Precautionary Statements P261-P280-P301 + P310 + P330-P305 + P351 + P338 + P310-P403 + P233
Risk Codes N/A
Safety Statements N/A
Transport Information UN 3146 6.1 / PG III
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/28/2021
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Triphenyltin Chloride

Product Number: All applicable American Elements product codes, e.g. TPHLSN-CL-01-C

CAS #: 639-58-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute oral toxicity Category 3
Acute dermal toxicity Category 3
Acute Inhalation Toxicity - Dusts and Mists Category 3

Signal Word
Danger
Hazard Statements
Toxic if swallowed, in contact with skin or if

Skull and Crossbones - GHS06 Health Hazard - GHS08

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Response
Get medical attention/advice if you feel unwell
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician
Skin
IF ON SKIN: Wash with plenty of soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
Remove/Take off immediately all contaminated clothing
Wash contaminated clothing before reuse
Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Rinse mouth
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component / CAS-No / Weight %
Triphenyl tin chloride / 639-58-7 / 95


SECTION 4. FIRST AID MEASURES

General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.

Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.

Skin Contact
Immediate medical attention is required. Wash off immediately with soap and plenty of water.

Inhalation
Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Immediate medical attention is required. If
not breathing, give artificial respiration.

Ingestion
Do NOT induce vomiting. Call a physician or poison control center immediately.

Most important symptoms and effects
No information available. Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media
Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available

Autoignition Temperature Not applicable >250 °C / >482 °F

Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical
Do not allow run-off from fire-fighting to enter drains or water courses.
Hazardous Combustion Products
Carbon monoxide (CO). Carbon dioxide (CO2). Metal oxides. Hydrogen chloride gas. Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

NFPA
Health
3
Flammability
1
Instability
0
Physical hazards
N/A


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions
Ensure adequate ventilation. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Avoid dust formation.

Environmental Precautions
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be released into the environment.

Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation


SECTION 7. HANDLING AND STORAGE

Handling
Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Wear
personal protective equipment/face protection. Do not breathe (dust, vapor, mist, gas). Avoid dust formation. Do not ingest. If swallowed then seek immediate medical assistance.

Storage
Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures
Ensure adequate ventilation, especially in confined areas.

Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Powder Solid
Appearance Off-white
Odor Characteristic
Odor Threshold No information available
pH No information available
Melting Point/Range 103 - 108 °C / 217.4 - 226.4 °F
Boiling Point/Range 240 °C / 464 °F @ 13.5 mmHg
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature Not applicable >250 °C / >482 °F
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula C18 H15 Cl Sn
Molecular Weight 385.47


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Excess heat
ncompatible Materials Strong oxidizing agents
Hazardous Decomposition Products
Carbon monoxide (CO), Carbon dioxide (CO2), Metal oxides, Hydrogen chloride gas
Hazardous Polymerization
Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available. Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure None known
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following
substances which are hazardous for the environment. May cause long-term adverse effects in the environment. Do not allow
material to contaminate ground water system. Persistence and Degradability May persist
Bioaccumulation/ Accumulation No information available.
Mobility Is not likely mobile in the environment due its low water solubility


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN3146
Proper Shipping Name Organotin compound, solid, n.o.s. Hazard Class 6.1
Packing Group III
TDG
UN-No UN3146
Proper Shipping Name Organotin compound, solid, n.o.s. Hazard Class 6.1
Packing Group III
IATA
UN-No UN3146
Proper Shipping Name Organotin compound, solid, n.o.s. Hazard Class 6.1
Packing Group III
IMDG/IMO
UN-No UN3146
Proper Shipping Name Organotin compound, solid, n.o.s. Hazard Class 6.1
Subsidiary Hazard Class P
Packing Group III


SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals. Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2021 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Triphenyltin Chloride

Triphenyltin Chloride (Fentin Chloride) is one of numerous organometallic compounds manufactured by American Elements under the trade name AE Organometallics™. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies organometallic compounds in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Triphenyltin Chloride Synonyms

Fentin chloride, Chlorotriphenyltin, Triphenylchlorotin, Chlorotriphenylstannane, PESTANAL, Sn(C6H5)3Cl

Chemical Identifiers

Linear Formula (C6H5)3SnCl
MDL Number MFCD00000519
EC No. 211-358-4
Beilstein/Reaxys No. 524762
Pubchem CID 12540
IUPAC Name chloro(triphenyl)stannane
SMILES C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)Cl
InchI Identifier InChI=1S/3C6H5.ClH.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H;/q;;;;+1/p-1
InchI Key NJVOZLGKTAPUTQ-UHFFFAOYSA-M

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine ModelIn its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Tin

Tin Bohr ModelSee more Tin products. Tin (atomic symbol: Sn, atomic number: 50) is a Block P, Group 14, Period 5 element with an atomic weight of 118.710. The number of electrons in each of tin's shells is 2, 8, 18, 18, 4 and its electron configuration is [Kr] 4d10 5s2 5p2. The tin atom has a radius of 140.5 pm and a Van der Waals radius of 217 pm.In its elemental form, tin has a silvery-gray metallic appearance. It is malleable, ductile and highly crystalline. High Purity (99.9999%) Tin (Sn) MetalTin has nine stable isotopes and 18 unstable isotopes. Under 3.72 degrees Kelvin, Tin becomes a superconductor. Applications for tin include soldering, plating, and such alloys as pewter. The first uses of tin can be dated to the Bronze Age around 3000 BC in which tin and copper were combined to make the alloy bronze. The origin of the word tin comes from the Latin word Stannum which translates to the Anglo-Saxon word tin. For more information on tin, including properties, safety data, research, and American Elements' catalog of tin products, visit the Tin element page.

Recent Research

TODAY'S SCIENCE POST!

October 28, 2021
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day
Infant planet discovered using Maunakea telescopes

Infant planet discovered using Maunakea telescopes