Tuning the upconversion light emission by bandgap engineering in bismuth oxide-based upconverting nanoparticles.

Title Tuning the upconversion light emission by bandgap engineering in bismuth oxide-based upconverting nanoparticles.
Authors M. Back; E. Trave; N. Mazzucco; P. Riello; A. Benedetti
Journal Nanoscale
DOI 10.1039/c6nr09350g
Abstract

In the field of novel applications involving upconverting processes, the determination of new strategies for realizing emission-tunable nanomaterials is a challenge. In this work the design of Y(3+) and Er(3+) codoped bismuth oxide-based upconverting nanoparticles is presented, evidencing that the active role of the matrix allows for the emission selectivity with chromaticity control. The bandgap of the bismuth oxide-based host can be manipulated in the range of 0.65 eV, consequently leading to upconversion emission color tunability from red to yellow-greenish. The resulting fine control of the nanoparticle chromaticity through accurate host bandgap engineering reveals a novel concept for the development of a new generation of upconverting nanophosphors.

Citation M. Back; E. Trave; N. Mazzucco; P. Riello; A. Benedetti.Tuning the upconversion light emission by bandgap engineering in bismuth oxide-based upconverting nanoparticles.. Nanoscale. 2017. doi:10.1039/c6nr09350g

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

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