Two KBBF-Type Beryllium Borates MBe2B2O6 (M = Sr, Ba) with a Three-Dimensional (Be2B2O6)? Network.

Title Two KBBF-Type Beryllium Borates MBe2B2O6 (M = Sr, Ba) with a Three-Dimensional (Be2B2O6)? Network.
Authors Z. Fang; F. Liang; M. Xia; L. Liu; Q. Huang; S. Guo; X. Wang; Z. Lin; C. Chen
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b01743
Abstract

Two new polyborates, BaBe2B2O6 and SrBe2B2O6, in a three-dimensional (Be2B2O6)? network featuring KBBF-type two-dimensional planes are synthesized. Compared with KBBF, both compounds possess comparable optical birefringence and deep-ultraviolet (deep-UV) cutoff edges and exhibit better bulk growth habits owing to their three-dimensional networks, which make them applicable deep-UV optical materials.

Citation Z. Fang; F. Liang; M. Xia; L. Liu; Q. Huang; S. Guo; X. Wang; Z. Lin; C. Chen.Two KBBF-Type Beryllium Borates MBe2B2O6 (M = Sr, Ba) with a Three-Dimensional (Be2B2O6)? Network.. Inorg Chem. 2017;56(20):1209012093. doi:10.1021/acs.inorgchem.7b01743

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Beryllium

See more Beryllium products. Beryllium (atomic symbol: Be, atomic number: 4) is a Block S, Group 2, Period 2 element with an atomic weight of 9.012182. Beryllium Bohr ModelThe number of electrons in each of Beryllium's shells is [2, 2] and its electron configuration is [He] 2s2. The beryllium atom has a radius of 112 pm and a Van der Waals radius of 153 pm. Beryllium is a relatively rare element in the earth's crust; it can be found in minerals such as bertrandite, chrysoberyl, phenakite, and beryl, its most common source for commercial production. Beryllium was discovered by Louis Nicolas Vauquelin in 1797 and first isolated by Friedrich Wöhler and Antoine Bussy in 1828. Elemental BerylliumIn its elemental form, beryllium has a gray metallic appearance. It is a soft metal that is both strong and brittle; its low density and high thermal conductivity make it useful for aerospace and military applications. It is also frequently used in X-ray equipment and particle physics. The origin of the name Beryllium comes from the Greek word "beryllos," meaning beryl.

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

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