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Ultra Dry Titanium(IV) Iodide

CAS #:

Linear Formula:

TiI4

MDL Number:

MFCD00043077

EC No.:

231-754-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Ultra Dry Titanium Iodide
TI4-I-02-P.UD
Pricing > SDS > Data Sheet >
(3N) 99.9% Ultra Dry Titanium Iodide
TI4-I-03-P.UD
Pricing > SDS > Data Sheet >
(4N) 99.99% Ultra Dry Titanium Iodide
TI4-I-04-P.UD
Pricing > SDS > Data Sheet >
(5N) 99.999% Ultra Dry Titanium Iodide
TI4-I-05-P.UD
Pricing > SDS > Data Sheet >

Ultra Dry Titanium(IV) Iodide Properties (Theoretical)

Compound Formula I4Ti
Molecular Weight 555.49
Appearance red-brown crystals
Melting Point 150 °C (302 °F)
Boiling Point 377 °C (711 °F)
Density 4.3 g/cm3
Solubility in H2O N/A
Exact Mass 555.565819
Monoisotopic Mass 555.565819

Ultra Dry Titanium(IV) Iodide Health & Safety Information

Signal Word Danger
Hazard Statements H314
Hazard Codes C
Risk Codes 34-37
Safety Statements 26-36/37/39-45
RTECS Number N/A
Transport Information UN 3260 8/PG 1
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Ultra Dry Titanium(IV) Iodide

Product Number: All applicable American Elements product codes, e.g. TI4-I-02-P.UD 02 , TI4-I-03-P.UD 03 , TI4-I-04-P.UD 04 , TI4-I-05-P.UD 05

CAS #: 7720-83-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1
H318 Causes serious eye damage.
GHS07
STOT SE 3
H335 May cause respiratory irritation.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

Corrosion - GHS05 Exclamation Mark - GHS07

GHS05
GHS07
Signal word
Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
7720-83-4 Titanium (IV) iodide
Identification number(s):
EC number:
231-754-0


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen iodide (HI)
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
No data available
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
No data available
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Not required.
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Eye protection:
Tightly sealed goggles
Full face protection
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form:
Powder
Color:
Red
Odor:
Acrid
Odor threshold:
No data available.
pH:
N/A
Melting point/Melting range:
150 °C (302 °F)
Boiling point/Boiling range:
377 °C (711 °F)
Sublimation temperature / start:
No data available
Flash point:
N/A
Flammability (solid, gas)
No data available.
Ignition temperature:
No data available
Decomposition temperature:
No data available
Autoignition:
No data available.
Danger of explosion:
Product does not present an explosion hazard.
Explosion limits:
Lower:
No data available
Upper:
No data available
Vapor pressure:
N/A
Density at 20 °C (68 °F):
4.3 g/cm3 (35.884 lbs/gal)
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in / Miscibility with
Water:
No data available
Partition coefficient (n-octanol/water):
No data available.
Viscosity:
Dynamic:
N/A
Kinematic:
N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with water
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
Hydrogen iodide (HI)


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Swallowing will lead to a strong corrosive effect on mouth and
throat and to the danger of perforation of esophagus and stomach
.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Causes severe skin burns.
Eye irritation or corrosion:
Causes serious
eye irritation.
Causes serious eye damage.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properti
es of this material is available fr
om the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
Titanium and titanium compounds are consi
dered physiologically inert. There are no r
eported cases in the literature where tita
nium as such has caused human
intoxication.
Prolonged exposure to iodides may
cause skin rash, running nose, headac
he and irritation of the mucous membranes. In severe ca
ses the skin may show pimples,
boils, redness, black and blue spots, hives and blisters
. Iodides are readily di
ffused across the placenta.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic to
xicity of this subst
ance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow material to be released to the
environment without official permits.
Do not allow undiluted product or large quantities to
reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official r
egulations to ensur
e proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made accordi
ng to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3260
UN proper shipping name
DOT
Corrosive solid, acidic, inorganic,
n.o.s. (Titanium (IV) iodide)
IMDG, IATA
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Titanium (IV) iodide)
Transport hazard class(es)
DOT
Class
8 Corrosive substances.
Label
8
Class
8 (C2) Corrosive substances
Label
8
IMDG, IATA
Class
8 Corrosive substances.
Label
8
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
N/A
Special precautions for user
Warning: Corrosive substances
Segregation groups
Acids
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3260, Corrosive solid, acidic, inorganic,
n.o.s. (Titanium (IV) iodide), 8, I


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legi
slation specific for the substance or mixture
GHS label elements
The product is classified and labeled in
accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS05
GHS07
Signal word
Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take
off immediately all contaminated clot
hing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse c
autiously with water for several minutes. Remove
contact lenses, if present and easy to do. Co
ntinue rinsing.
P301+P330+P331 IF SWALLOWED: rins
e mouth. Do NOT induce vomiting.
P405
Store locked up.
P501
Dispose of contents/container
in accordance with local/regional/
national/internati
onal regulations.
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substanc
es Control Act Chemical sub
stance Inventory.
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technica
lly qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) accord
ing to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and A
nnex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manuf
acturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Ultra Dry Titanium(IV) Iodide

Iodide IonAmerican Elements specializes in producing Titanium Iodide in an ultra dry form for use as a compound in semiconductors and other high purity applications. Ultra Dry Titanium Iodide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Iodide compounds are water soluble; however, iodide-rich solutions act as better dissolution agents for creating iodide solutions. Iodides are often used in internal medicine. Treating an iodide with manganese dioxide and sulfuric acid sublimes the iodine. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Ultra Dry Titanium(IV) Iodide Synonyms

Titanium(4+) tetraiodide, tetraiodotitanium, titanium tetraiodide

Chemical Identifiers

Linear Formula TiI4
MDL Number MFCD00043077
EC No. 231-754-0
Beilstein Registry No. N/A
Pubchem CID 111328
IUPAC Name tetraiodotitanium
SMILES [Ti+4].[I-].[I-].[I-].[I-]
InchI Identifier InChI=1S/4HI.Ti/h4*1H;/q;;;;+4/p-4
InchI Key NLLZTRMHNHVXJJ-UHFFFAOYSA-J

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

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