20th anniversary seal20th anniversary seal20th anniversary seal

Vanadium(V) Oxychloride

CAS #:

Linear Formula:

VOCl3

MDL Number:

MFCD00011459

EC No.:

231-780-2

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Vanadium(V) Oxychloride
V-OCLI-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Vanadium(V) Oxychloride
V-OCLI-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Vanadium(V) Oxychloride
V-OCLI-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Vanadium(V) Oxychloride
V-OCLI-05
Pricing > SDS > Data Sheet >

Vanadium(V) Oxychloride Properties (Theoretical)

Compound Formula Cl3OV
Molecular Weight 173.299 g/mol
Appearance Fuming Red Liquid
Melting Point -79.0 °C
Boiling Point 126-127 °C
Density 1.829 g/cc
Solubility in H2O Reacts with H2O; Soluble in MeOH, Ethyl Ether and Acetone
Heat of Vaporization 212.2 J/g
Specific Heat 0.5188 J/g-°C
Thermal Conductivity 0.139 W/m-K (20.0 °C)
Exact Mass 173.299896
Monoisotopic Mass 171.845444

Vanadium(V) Oxychloride Health & Safety Information

Signal Word Danger
Hazard Statements H301-H314
Hazard Codes T
Precautionary Statements P280-P301 + P310-P305 + P351 + P338-P310
Flash Point Not applicable
Risk Codes 14-25-34
Safety Statements 26-27-28-36/37/39-45
RTECS Number N/A
Transport Information UN 2443 8 / PGII
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Vanadium(V) Oxychloride

Product Number: All applicable American Elements product codes, e.g. V-OCLI-02 02 , V-OCLI-03 03 , V-OCLI-04 04 , V-OCLI-05 05

CAS #: 7727-18-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Skin Corrosion/irritation: Category 1 B
Serious Eye Damage/Eye Irritation: Category 1
Specific target organ toxicity (single exposure): Category 3
Target Organs: Respiratory system
Label Elements

Corrosion - GHS05 Skull and Crossbones - GHS06

Signal Word:
Danger
Hazard Statements:
Causes severe skin burns and eye damage
May cause respiratory irritation
Precautionary Statements
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Response:
Immediately call a POISON CENTER or doctor/physician
Inhalation:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin:
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion:
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Storage:
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal:
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Harmful to aquatic life with long lasting effects
Reacts violently with water
Contact with water liberates toxic gas


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component:
Vanadium oxytrichloride
CAS-No:
7727-18-6
Weight:
< 100%


SECTION 4. FIRST AID MEASURES

General Advice:
Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.
Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.
Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing before re-use. Call a physician immediately.
Inhalation:
If not breathing, give artificial respiration. Remove from exposure, lie down. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician immediately.
Ingestion:
Do not induce vomiting. Clean mouth with water. Never give anything by mouth to an unconscious person. Call a physician immediately.
Most important symptoms and effects:
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation
Notes to Physician:
Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media:
Dry sand. Carbon dioxide (CO 2). Dry powder. Do not use water or foam. CO 2, dry chemical, dry sand, alcohol-resistant foam.
Unsuitable Extinguishing Media: No information available
Flash Point: No information available
Method - No information available
Autoignition Temperature: No information available
Explosion Limits
Upper: No data available
Lower: No data available
Sensitivity to Mechanical Impact: No information available
Sensitivity to Static Discharge: No information available
Specific Hazards Arising from the Chemical:
Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Contact with water liberates toxic gas. Reacts violently with water.
Hazardous Combustion Products:
Hydrogen chloride Vanadium oxides
Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health: 3
Flammability: 0
Instability: 2
Physical hazards: W


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Environmental Precautions: Should not be released into the environment. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system.
Methods for Containment and Clean Up:
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Do
not expose spill to water.


SECTION 7. HANDLING AND STORAGE

Handling:
Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe vapors or spray mist. Do not ingest. Do not allow contact with water.
Storage:
Corrosives area. Keep away from water. Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Component: Vanadium oxytrichloride
ACGIH TLV: -
OSHA PEL: -
NIOSH: -
IDLH: Ceiling: 0.05 mg/m3
Mexico OEL (TWA): -
Engineering Measures: None under normal use conditions. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection:
Long sleeved clothing.
Respiratory Protection:
No protective equipment is needed under normal use conditions.
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Appearance: No information available
Odor: Chlorine
Odor Threshold: No information available
pH: No information available
Melting Point/Range: -77 °C / -106.6 °F
Boiling Point/Range: 126 - 127 °C / 258.8 - 260.6 °F
Flash Point: No information available
Evaporation Rate: No information available
Flammability (solid,gas): Not applicable
Flammability or explosive limits
Upper: No data available
Lower: No data available
Vapor Pressure: 21 hPa @ 25 °C
Vapor Density: No information available
Specific Gravity: 1.829 g/cm3
Solubility: No information available
Partition coefficient; n-octanol/water: No data available
Autoignition Temperature: No information available
Decomposition Temperature: No information available
Viscosity: No information available
Molecular Formula: VOCl3
Molecular Weight: 173.30


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard: Yes
Stability: Moisture sensitive
Conditions to Avoid: Exposure to moist air or water. Exposure to moisture.
Incompatible Materials: Oxidizing agents
Hazardous Decomposition Products: Hydrogen chloride, Vanadium oxides
Hazardous Polymerization: Hazardous polymerization does not occur.
Hazardous Reactions: None under normal processing. Reacts violently with water


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component: Vanadium oxytrichloride
LD50 Oral: LD50 = 140 mg/kg ( Rat )
LD50 Dermal: Not listed
LC50 Inhalation: Not listed
Toxicologically Synergistic Product:
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation: No information available
Sensitization: No information available
Carcinogenicity
Component:Vanadium oxytrichloride
CAS-No: 7727-18-6
IARC: Not listed
NTP: Not listed
ACGIH: Not listed
OSHA: Not listed
Mexico: Not listed
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
STOT - single exposure: Respiratory system
STOT - repeated exposure: None known
Aspiration hazard: No information available
Symptoms / effects,both acute and delayed:
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.
Endocrine Disruptor Information: No information available
Other Adverse Effects: The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.
Persistence and Degradability: May persist
Bioaccumulation/ Accumulation: No information available.
Mobility: No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No: UN2443
Proper Shipping Name: VANADIUM OXYTRICHLORIDE
Hazard Class: 8
Packing Group: II
TDG
UN-No: UN2443
Proper Shipping Name: VANADIUM OXYTRICHLORIDE
Hazard Class: 8
Packing Group: II
IATA
UN-No: UN2443
Proper Shipping Name: VANADIUM OXYTRICHLORIDE
Hazard Class: 8
Packing Group: II
IMDG/IMO
UN-No: UN2443
Proper Shipping Name: VANADIUM OXYTRICHLORIDE
Hazard Class: 8
Packing Group: II


SECTION 15. REGULATORY INFORMATION

International Inventories
Component: Vanadium oxytrichloride
TSCA: X
DSL: X
NDSL: -
EINECS: 231-780-2
ELINCS: -
NLP: X
PICCS: X
ENCS: X
AICS: X
IECSC: X
KECL: X
U.S. Federal Regulations
TSCA 12(b): Not applicable
SARA 313
Component: Vanadium oxytrichloride
CAS-No: 7727-18-6
Weight: < 100%
SARA 313 - Threshold Values: 1.0%
CWA (Clean Water Act): Not applicable
Clean Air Act: Not applicable
OSHA: Not applicable
CERCLA: Not applicable
California Proposition 65: This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Component: Vanadium oxytrichloride
Massachusetts: -
New Jersey: X
Pennsylvania: -
Illinois: -
Rhode Island: -
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant: N
DOT Severe Marine Pollutant: N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Vanadium(V) Oxychloride

Vanadium(V) Oxychloride is one of numerous organo-metallic compounds sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Vanadium(V) Oxychloride is generally immediately available in most volumes, including bulk quantities. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data. Please contact us for information on lead time and pricing above.

Vanadium(V) Oxychloride Synonyms

Vanadyl chloride, Vanadyl trichloride, Vanadium(V) oxytrichloride, Trichlorooxovanadium, vanadium oxytrichloride, Vanadium, trichlorooxo-

Chemical Identifiers

Linear Formula VOCl3
MDL Number MFCD00011459
EC No. 231-780-2
Beilstein Registry No. N/A
Pubchem CID 24410
IUPAC Name oxovanadium; trihydrochloride
SMILES Cl[V](Cl)(Cl)=O
InchI Identifier InChI=1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3
InchI Key JBIQAPKSNFTACH-UHFFFAOYSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. it has the third highest electronegativity and the highest electron affinity of all the elements making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in naturehowever, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

TODAY'S SCIENCE POST!

October 22, 2019
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day

Re­searchers de­vel­op a com­pact in­frared spec­trom­e­ter that is smaller than a coin