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Vanadium(V) Oxytriisopropoxide

CAS #:

Linear Formula:

OV(OCH(CH3)2)3

MDL Number:

MFCD00015017

EC No.:

226-997-4

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Vanadium(V) Oxytriisopropoxide
V5-OXTIPID-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Vanadium(V) Oxytriisopropoxide
V5-OXTIPID-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Vanadium(V) Oxytriisopropoxide
V5-OXTIPID-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Vanadium(V) Oxytriisopropoxide
V5-OXTIPID-05
Pricing > SDS > Data Sheet >

Vanadium(V) Oxytriisopropoxide Properties (Theoretical)

Compound Formula C9H24O4V
Molecular Weight 247.23
Appearance Colorless liquid
Melting Point N/A
Boiling Point 80-82 °C
Density 1.035 g/mL at 25 °C
Solubility in H2O N/A
Exact Mass 247.111419
Monoisotopic Mass 247.111419

Vanadium(V) Oxytriisopropoxide Health & Safety Information

Signal Word Warning
Hazard Statements H226-h315-h319-h335
Hazard Codes Xi
Risk Codes 10-36/37/38
Safety Statements 16-26-36
RTECS Number N/A
Transport Information UN1993 3/PG III
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Vanadium(V) Oxytriisopropoxide

Product Number: All applicable American Elements product codes, e.g. V5-OXTIPID-02 02 , V5-OXTIPID-03 03 , V5-OXTIPID-04 04 , V5-OXTIPID-05 05

CAS #: 5588-84-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

OSHA Haz Com: CFR 1910.1200: Skin Corrosion/Irritation [Category 2]
Eye Damage/Irritation [Category 2A]
Flammable Liquids [Category 4]
Signal word: Warning!
Hazard Statement(s): Causes serious eye irritation
Causes skin irritation
Combustible liquid
Pictogram(s) or Symbol(s):

Exclamation Mark - GHS07

Precautionary Statement(s):
[Prevention] Wash hands and face thoroughly after handling. Wear protective gloves. Wear eye and face protection.
Keep away from heat, sparks, open flames or other hot surfaces. - No smoking. Wear protective gloves,
eye protection and face protection.
[Response] If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice or attention. In case of fire: Use dry chemical, CO2, water spray or alcohol-resistant foam to
extinguish.
[Storage] Store in well-ventilated place. Keep cool.
[Disposal] Dispose of contents and container in accordance with US EPA guidelines for the classification and
determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance/Mixture: Substance
Components: Triisopropoxyvanadium(V) Oxide
Percent: >97.0%(T)
CAS Number: 5588-84-1
Molecular Weight: 244.20
Chemical Formula: C9H21O4V
Synonyms: Vanadium(V) Oxytriisopropoxide , Vanadium(V) Triisopropoxide Oxide


SECTION 4. FIRST AID MEASURES

Inhalation: Call emergency medical service. Move victim to fresh air. Give artificial respiration if victim is not breathing.
Administer oxygen if breathing is difficult. Keep victim warm and quiet. Treat symptomatically and
supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.
Skin contact: Call a poison center or doctor if you feel unwell. Remove and wash contaminated clothing before re-use. In
case of contact with substance, immediately flush skin with running water for at least 20 minutes. Treat
symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and
take precautions to protect themselves.
Eye contact: IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Contact with
material may irritate or burn eyes. Call emergency medical service. Move victim to fresh air. Check for and
remove any contact lenses. Keep victim warm and quiet. Treat symptomatically and supportively. Effects of
exposure to substance may be delayed. Ensure that medical personnel are aware of the material(s)
involved and take precautions to protect themselves.
Ingestion: Do not induce vomiting with out medical advice. If swallowed, seek medical advice immediately and show
the container or label. Do not use mouth-to-mouth method if victim ingested the substance; give artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
medical device. Loosen tight clothing such as a collar, tie, belt or waistband. If a person vomits place them
in the recovery position so that vomit will not reenter the mouth and throat. Rinse mouth. Keep victim warm
and quiet. Treat symptomatically and supportively. Ensure that medical personnel are aware of the
material(s) involved and take precautions to protect themselves.
Symptoms/effects:
Acute: Redness.
Delayed: No data available
Immediate medical attention: If breathing has stopped, perform artificial respiration. Use first aid treatment according to the nature of the
injury. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.


SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media: Dry chemical, CO2 , water spray, or alcohol-resistant foam. Consult with local fire authorities before
attempting large scale fire fighting operations.
Specific hazards arising from the chemical
Hazardous combustion products: These products include: Carbon oxides
Other specific hazards: Closed containers may explode from heat of a fire.
Special precautions for fire-fighters:
Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. CAUTION: All these products
have a very low flash point: Use of water spray when fighting fire may be inefficient. Do not use straight streams. Runoff to sewer may create fire or
explosion hazard. Containers may explode when heated. Move containers from fire area if you can do it without risk.
Special protective equipment for fire-fighters:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire fighters' protective clothing provides limited protection in fire situations
ONLY; it may not be effective in spill situations. Wear chemical protective clothing which is specifically recommended by the manufacturer. It may
provide little or no thermal protection.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid contact with skin, eyes, and clothing. Keep people away from and upwind of spill/leak. Use sparkproof
tools and explosion-proof equipment. Remove all sources of ignition. Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing (Section 8). Warn
unnecessary personnel to move away. Stop leak if you can do it without risk. Ensure adequate ventilation.
Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Personal protective equipment: Wear eye protection (splash goggles) and face protection (full length face shield). Lab coat. Vapor
respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Wear protective gloves
(nitrile).
Emergency procedures: Isolate area until gas has dispersed. In case of a spill and/or a leak, always shut off any sources of ignition,
ventilate the area, and excercise caution. Do not touch damaged containers or spilled material unless
wearing appropriate protective clothing. Warn personnel to move away. Prevent entry into sewers,
basements or confined areas; dike if needed.
Methods and materials for containment and cleaning up:
ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in immediate area). All equipment used when handling the product must be
grounded. Stop leak if without risk. Ventilate the area. Absorb with an inert material and put the spilled material in an appropriate waste disposal
container. Use clean non-sparking tools to collect absorbed material.
Environmental precautions:
Prevent further leakage or spillage if safe to do so. Water runoff can cause environmental damage. Prevent entry into sewers, basements or confined
areas; dike if needed.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling: Do NOT breath gas, fumes, vapor, or spray. Avoid contact with skin and eyes. Keep away from heat and
sources of ignition. Use explosion-proof equipment. Use only non-sparking hand tool when handling this
product. Ground all equipment containing material. Take measures to prevent build up of electrostatic
charge. Good general ventilation should be sufficient to control airborne levels. Keep container dry. Handle
and open container with care. Wear suitable protective clothing, gloves and eye/face protection. When
using do not eat, drink, or smoke. Keep away from sources of ignition.
Conditions for safe storage: Keep only in the original container in a cool well-ventilated place. Keep away from sources of ignition.
Store and use away from heat, sparks, open flame, or any other ignition source. Keep away from
incompatibles. Containers which are opened must be carefully resealed and kept upright to prevent
leakage. Avoid prolonged storage periods. Store under inert gas (e.g. Argon). Moisture sensitive.
Storage incompatibilities: Combustible substances, Store away from oxidizing agents


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limits: No data available
Appropriate engineering controls:
Good general ventilation should be sufficient to control airborne levels. Ventilation is normally required when handling or using this product. Eyewash
fountains should be provided in areas where there is any possibility that workers could be exposed to the substance. Follow safe industrial
engineering/laboratory practices when handling any chemical.
Personal protective equipment
Respiratory protection: Vapor respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
Hand protection: Wear protective gloves.
Eye protection: Splash goggles.
Skin and body protection: Lab coat.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state (20°C): Liquid
Form: Clear
Color: Pale yellow - Deep yellow
Odor: Alcoholic
Odor threshold: No data available
Melting point/freezing point: -2°C (28°F)
Boiling point/range: 102°C (216°F)/1.2kPa
Decomposition temperature: No data available
Relative density: 1.04
Kinematic Viscosity: No data available
Partition coefficient: No data available
n-octanol/water (log Pow)
Flash point: 70°C (158°F)
Flammability (solid, gas): No data available

pH: No data available
Vapor pressure: 0.1kPa/60°C
Vapor density: No data available
Dynamic Viscosity: No data available
Evaporation rate: No data available
(Butyl Acetate = 1)
Autoignition temperature: No data available
Flammability or explosive limits: No data available
Lower: No data available
Upper: No data available

Solubility(ies):
Soluble: Toluene, Hexane, Isopropanol


SECTION 10. STABILITY AND REACTIVITY

Reactivity: Not Available.
Chemical Stability: Moisture sensitive.
Possibility of Hazardous Reactions: In use, may form flammable/explosive vapor-air mixture.
Conditions to avoid: Exposure to moisture. Moisture sensitive.
Incompatible materials: Moisture, Oxidizing agents
Hazardous Decomposition Products: No data available


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity:
No data available
Skin corrosion/irritation:
No data available
Serious eye damage/irritation:
No data available
Respiratory or skin sensitization:
No data available
Germ cell mutagenicity:
No data available
Carcinogenicity:
No data available
IARC: No data available NTP: No data available OSHA: No data available
Reproductive toxicity:
No data available
Routes of Exposure: Inhalation, Eye contact, Ingestion, Skin contact.
Symptoms related to exposure:
Skin contact may result in inflammation; characterized by itching, scaling, reddening, or occasionally blistering. Skin contact may result in redness, pain
or dry skin. Eye contact may result in redness or pain.
Potential Health Effects:
Skin and eye contact may result in irritation.
Target organ(s): No data available


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Fish: No data available
Crustacea: No data available
Algae: No data available
Persistence and degradability: No data available
Bioaccumulative potential (BCF): No data available
Mobillity in soil: No data available
Partition coefficient:
n-octanol/water (log Pow)
No data available
Soil adsorption (Koc): No data available
Henry's Law:
constant (PaM3/mol)
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Disposal of product: Recycle to process if possible. It is the generator's responsibility to comply with Federal, State and Local
rules and regulations. You may be able to dissolve or mix material with a combustible solvent and burn in a
chemical incinerator equipped with an afterburner and scrubber system. This section is intended to provide
assistance but does not replace these laws, nor does compliance in accordance with this section ensure
regulatory compliance according to the law. US EPA guidelines for Identification and Listing of Hazardous
Waste are listed in 40 CFR Parts 261. The product should not be allowed to enter the environment, drains,
water ways, or the soil.
Disposal of container: Dispose of as unused product. Do not re-use empty containers.
Other considerations: Observe all federal, state and local regulations when disposing of the substance.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number:
UN1993
Proper Shipping Name:
Flammable liquids, n.o.s.
Class or Division:
3 Flammable liquid
Packing Group:
III
IATA
UN number:
UN1993
Proper Shipping Name:
Flammable liquids, n.o.s.
Class or Division:
3 Flammable liquid
Packing Group:
III
IMDG
UN number:
UN1993
Proper Shipping Name:
Flammable liquids, n.o.s.
Class or Division:
3 Flammable liquid
Packing Group:
III
EmS number: F-E, S-E


SECTION 15. REGULATORY INFORMATION

Toxic Substance Control Act (TSCA 8b.):
This product is ON the EPA Toxic Substances Control Act (TSCA) inventory.
US Federal Regulations
CERCLA Hazardous substance and Reportable Quantity:
SARA 313: Not Listed
SARA 302: Not Listed
State Regulations
State Right-to-Know
Massachusetts Not Listed
New Jersey Not Listed
Pennsylvania Not Listed
California Proposition 65: Not Listed
Other Information
NFPA Rating:
Health: 2
Flammability: 2
Instability: 0
HMIS Classification:
Health: 2
Flammability: 2
Physical: 0
International Inventories
WHMIS hazard class: B2: Flammable Liquid.
D2B: Materials causing other toxic effects. (Toxic)
Canada: NDSL On NDSL
EC-No: 226-997-4


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Vanadium(V) Oxytriisopropoxide

Vanadium(V) Oxytriisopropoxide is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Vanadium(V) Oxytriisopropoxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Vanadium(V) Oxytriisopropoxide Synonyms

Triisopropoxyvanadium(V) oxide, VTIP, Oxotri(isopropoxo)vanadium, Vanadium(V) trisisopropoxide oxide, oxotris(propan-2-olato)vanadium, Vanadium, oxotris(2-propanolato)-, (T-4)-, 863098-64-0, Vanadic acid (H3VO4) tris(1-methylethyl) ester

Chemical Identifiers

Linear Formula OV(OCH(CH3)2)3
MDL Number MFCD00015017
EC No. 226-997-4
Beilstein Registry No. N/A
Pubchem CID 79702
IUPAC Name oxovanadium; propan-2-ol
SMILES CC(C)O.CC(C)O.CC(C)O.O=[V]
InchI Identifier InChI=1S/3C3H8O.O.V/c3*1-3(2)4;;/h3*3-4H,1-2H3;;
InchI Key JOUSPCDMLWUHSO-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in naturehowever, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

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