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Yttrium Oxalate

CAS #:

Linear Formula:

Y2(C2O4)3•xH2O

MDL Number:

MFCD00150500 / MFCD00150502

EC No.:

212-767-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Yttrium Oxalate
Y-OXL-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Yttrium Oxalate
Y-OXL-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Yttrium Oxalate
Y-OXL-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Yttrium Oxalate
Y-OXL-05
Pricing > SDS > Data Sheet >

Yttrium Oxalate Properties (Theoretical)

Compound Formula C6O12Y2
Molecular Weight 441.869
Appearance White crystals
Melting Point Decomposes
Boiling Point N/A
Density N/A
Solubility in H2O Insoluble
Exact Mass 441.751
Monoisotopic Mass 441.751

Yttrium Oxalate Health & Safety Information

Signal Word Warning
Hazard Statements H302+H312
Hazard Codes Xi
Precautionary Statements P280h-P264-P270-P301+P312a-P321-P501a
Risk Codes N/A
Safety Statements N/A
Harmonized Tariff Code 2846.90
Transport Information UN3288 6.1/PG III
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/19/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Yttrium Oxalate

Product Number: All applicable American Elements product codes, e.g. Y-OXL-02 02 , Y-OXL-03 03 , Y-OXL-04 04 , Y-OXL-05 05

CAS #: 13266-82-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Hazards not otherwise classified
No data available
GHS label elements
The product is classified and labeled in
accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word
Warning
Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
Precautionary statements
P280
Wear protective gloves/protective
clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell.
P312
Call a POISON CENTER/doctor/.../if you feel unwell.
P363
Wash contaminated clothing before reuse.
P322
Specific measures
(see on this label).
P501
Dispose of contents/container
in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
13266-82-5 Yttrium(III) oxalate nonahydrate
Identification number(s):
Index number:
607-007-00-3


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water spray.
Fight larger fires with water spray.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Dispose of contaminated material
as waste according to section 13.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
No data available
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
No data available
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Yttrium and compounds, as Y mg/m3
ACGIH TLV 1
Austria MAK 1
Belgium TWA 1
Denmark TWA 1
Finland TWA 1
France VME 1
Germany TWA 5
Korea TLV 1
Netherlands MAC-TGG 1
Norway TWA 1
Poland TWA 1
Switzerland MAK-W 1
United Kingdom TWA 1; 3-STEL
OSHA PEL 1
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form:
Powder
Color:
White
Odor:
No data available
Odor threshold:
No data available.
pH:
N/A
Melting point/Melting range:
Decomposes before melting.
Boiling point/Boiling range:
No data available
Sublimation temperature / start:
No data available
Flash point:
N/A
Flammability (solid, gas)
No data available.
Ignition temperature:
No data available
Decomposition temperature:
No data available
Autoignition:
No data available.
Danger of explosion:
Product does not present
an explosion hazard.
Explosion limits:
Lower:
No data available
Upper:
No data available
Vapor pressure:
N/A
Density:
No data available
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in / Miscibility with
Water:
Insoluble
Partition coefficient (n-octanol/water):
No data available.
Viscosity:
Dynamic:
N/A
Kinematic:
N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
Oxidizing agents
No data available
Hazardous decomposition products:
Carbon monoxide and carbon dioxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful in contact with skin.
Harmful if swallowed.
Danger through skin absorption.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Irritant to skin and mucous membranes.
Eye irritation or corrosion:
Irritating effect.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
Yttrium is similar to the lanthanons and may have an anticoagulant effect on blood. Exposure to lanthanons may also lead to sensitivity to heat, itching, increased awareness of odor and taste, and liver damage.
Oxalates are powerful irritants and corrosive to tissue. They have a caustic effect on the mouth, esophagus and stomach. Readily absorbed, they can cause severe kidney damage.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to
reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3288
UN proper shipping name
DOT
Toxic solid, inorganic, n.o.s. (yttrium oxalate)
IMDG, IATA
TOXIC SOLID, INORGANIC, N.O.S. (yttrium oxalate)
Transport hazard class(es)
DOT
Class
6.1 Toxic substances.
Label
6.1
Class
6.1 (T5) Toxic substances
Label
6.1
IMDG, IATA
Class
6.1 Toxic substances.
Label
6.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
N/A
Special precautions for user
Warning: Toxic substances
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3288, Toxic solid, inorganic, n.o.s. (yttrium oxalate), 6.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS07
Signal word
Warning
Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
Precautionary statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell.
P312
Call a POISON CENTER/doctor/.../if you feel unwell.
P363
Wash contaminated clothing before reuse.
P322
Specific measures
(see on this label).
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Yttrium Oxalate

Oxalate IonYttrium Oxalate is highly insoluble in water and converts to the oxide when heated (calcined). Yttrium Oxalate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. Yttrium has the highest thermo-dynamic affinity for oxygen, useful in ceramics for crucibles for molten reactive metals, in florescent phosphors, computer displays and automotive fuel sensors. Yttria stabilized zirconia is used in high temperature applications and as an electrolyte in fuel cells. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Yttrium Oxalate Synonyms

diyttrium trioxalate, Ethanedioic acid, yttrium(3+) salt (3:2), yttrium oxalate nonahydrate, ttrium oxalate decahydrate, CAS 867-68-5, yttrium oxalate tetrahydrate, yttrium oxalate hydrate (CAS 252900-41-7 )

Chemical Identifiers

Linear Formula Y2(C2O4)3•xH2O
MDL Number MFCD00150500 / MFCD00150502
EC No. 212-767-0
Beilstein Registry No. N/A
Pubchem CID 164745
IUPAC Name oxalate; yttrium(3+)
SMILES [Y+3].[Y+3].O=C([O-])C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O
InchI Identifier InChI=1S/3C2H2O4.2Y/c3*3-1(4)2(5)6;;/h3*(H,3,4)(H,5,6);;/q;;;2*+3/p-6
InchI Key IBSDADOZMZEYKD-UHFFFAOYSA-H

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Yttrium products. Yttrium (atomic symbol: Y, atomic number: 39) is a Block D, Group 3, Period 5 element with an atomic weight of 88.90585. Yttrium Bohr ModelThe number of electrons in each of yttrium's shells is [2, 8, 18, 9, 2] and its electron configuration is [Kr] 4d1 5s2. The yttrium atom has a radius of 180 pm and a Van der Waals radius of 219 pm. Yttrium was discovered by Johann Gadolin in 1794 and first isolated by Carl Gustav Mosander in 1840. In its elemental form, Yttrium has a silvery white metallic appearance. Yttrium has the highest thermodynamic affinity for oxygen of any element. Elemental YttriumYttrium is not found in nature as a free element and is almost always found combined with the lanthanides in rare earth minerals. While not part of the rare earth series, it resembles the heavy rare earths which are sometimes referred to as the "yttrics" for this reason. Another unique characteristic derives from its ability to form crystals with useful properties. The name yttrium originated from a Swedish village near Vaxholm called Yttbery where it was discovered.

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August 19, 2019
Los Angeles, CA
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