ZIF-67, 2-methylimidazole Cobalt Salt

Linear Formula:

C8H10N4Co

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
ZIF-67, 2-methylimidazole Cobalt Salt
CO-OMX-01-P
Pricing > SDS > Data Sheet >

ZIF-67, 2-methylimidazole Cobalt Salt Properties (Theoretical)

Compound Formula C8H10N4Co
Molecular Weight 221.1
Appearance Purple powder
Melting Point N/A
Boiling Point N/A
Density N/A
Specific Surface Area ~1500 m2/g
Solubility in H2O N/A

ZIF-67, 2-methylimidazole Cobalt Salt Health & Safety Information

Signal Word Danger
Hazard Statements H302-H314-H318
Hazard Codes C, Xi
Precautionary Statements P260-P280-P301-P301+P312+P330-P303+P361+P353-P304+P340+P310-P305+P351+P338
Risk Codes N/A
Safety Statements N/A
Transport Information UN 3263 8/PG III
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Created: 5/15/2015
Date Revised: 5/15/2015

SECTION 1. IDENTIFICATION

Product Name: ZIF-67, 2-methylimidazole Cobalt Salt

Product Number: All applicable American Elements product codes, e.g. CO-OMX-01-P

Relevant identified uses of the substance: Scientific research and development


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 4), H302
Skin corrosion (Category 1B), H314
For the full text of the H-Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram

Corrosion - GHS05 Exclamation Mark - GHS07

Hazard statement(s)
H302
Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P312 + P330
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310
IF INHALED: Remove person to fresh air and keep comfortable for reathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 I
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard
Statements None
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels
of 0.1% or higher.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Substance name : Zeolite Imidazolate Framework-67 (ZIF-67)
Synonyms : 2-Methylimidazole Cobalt Salts, ZIF-67, MOFs
Linear formula : Co(Hmim)2, Hmim=2-methylimidazole, C8H10N4Co
Hazardous impurities: None known.


SECTION 4. FIRST AID MEASURES

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of
water.
Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11.
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or
gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust.
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Suitable extinguishing media
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate
exhaust ventilation at places where dust is formed. Normal measures for preventive fire
protection. For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before
breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.
Body Protection
Impervious clothing recommended. The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.
For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator
cartridges. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
1) Appearance Form: Solid, Purple
Powder
2) Odour No data available
3) Odour Threshold No data available
4) pH No data available
5) Melting point/freezing point No data available
6) Initial boiling point and boiling range No data available
7) Flash point Not applicable
8) Evaporation rate No data available
9) Flammability (solid, gas) No data available
10) Upper/lower flammability or explosive
limits
No data available
11) Vapour pressure No data available
12) Vapour density No data available
13) Relative density No data available
14) Water solubility No data available
15) Partition coefficient: n- octanol/water No data available
16) Auto-ignition temperature No data available
17) Decomposition temperature No data available
18) Viscosity No data available
19) Explosive properties No data available
20) Oxidizing properties No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Stable under recommended storage conditions.
Possibility of hazardous
reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong acids, Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Cobalt / cobalt oxide.
Other decomposition products - No data available
In the event of fire: see section 5.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
LD50 Oral - Mouse - 1.400 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: No available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Toxicity to fish LC50 - other fish - 286 mg/l - 96 h
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels
of 0.1% or higher.
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

UN number
ADR/RID: 3263
IMDG: 3263
IATA: 3263
UN proper shipping name
ADR
RID: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2-Methylimidazole zinc salt)
IMDG: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2-Methylimidazole zinc salt)
IATA: Corrosive solid, basic, organic, n.o.s. (2-Methylimidazole zinc salt)
Transport hazard class(es)
ADR/RID: 8
IMDG: 8
IATA: 8
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precaution for user
No data available


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance
or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About ZIF-67, 2-methylimidazole Cobalt Salt

ZIF-67 (zeolitic imidazolate framework-67, or 2-methylimidazole cobalt salt) , is one of numerous metal-organic frameworks (MOFs) manufactured by American Elements. MOFs are porous, extremely high surface area materials in which a metal is bonded to organic ligands, making them ideal candidates for gas absorption and catalysis. American Elements supplies organometallic compounds in most volumes including bulk quantities and also can produce materials to customer specifications. Most materials can be produced in high and ultra high purity forms (99%, 99.9%, 99.99%, 99.999%, and higher) and to many standard grades when applicable including Mil Spec (military grade), ACS, Reagent and Technical Grades, Pharmaceutical Grades, Optical, Semiconductor, and Electronics Grades. Please request a quote above for more information on pricing and lead time.

ZIF-67, 2-methylimidazole Cobalt Salt Synonyms

Zeolite Imidazolate Framework-67, Co(Hmim)2, ZIF67

Chemical Identifiers

Linear Formula C8H10N4Co
MDL Number N/A
EC No. N/A
Pubchem CID N/A

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit." For more information on cobalt, including properties, safety data, research, and American Elements' catalog of cobalt products, visit the Cobalt element page.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Recent Research

TODAY'S SCIENCE POST!

January 25, 2020
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day
Salting down the cost of protein-polymer drugs

Salting down the cost of protein-polymer drugs