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Zirconium Oxynitrate Solution

CAS #:

Linear Formula:

ZrO(NO3)2

MDL Number:

MFCD00011308

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Zirconium Oxynitrate Solution
ZR-ONAT-02-SOL
Pricing > SDS > Data Sheet >
(3N) 99.9% Zirconium Oxynitrate Solution
ZR-ONAT-03-SOL
Pricing > SDS > Data Sheet >
(4N) 99.99% Zirconium Oxynitrate Solution
ZR-ONAT-04-SOL
Pricing > SDS > Data Sheet >
(5N) 99.999% Zirconium Oxynitrate Solution
ZR-ONAT-05-SOL
Pricing > SDS > Data Sheet >

Zirconium Oxynitrate Solution Properties (Theoretical)

Compound Formula N2O7Zr
Molecular Weight 231.23
Appearance Liquid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass 231.8909
Charge N/A

Zirconium Oxynitrate Solution Health & Safety Information

Signal Word Danger
Hazard Statements H272-H314
Hazard Codes C
Risk Codes 34
Safety Statements 26-36/37/39-45
RTECS Number N/A
Transport Information UN 3098 5.1/PG 2
WGK Germany 2
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Zirconium Oxynitrate Solution

Product Number: All applicable American Elements product codes, e.g. ZR-ONAT-02-SOL 02 , ZR-ONAT-03-SOL 03 , ZR-ONAT-04-SOL 04 , ZR-ONAT-05-SOL 05

CAS #: 13826-66-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Oxidizing liquids(Category 2), H272
Skin corrosion(Category 1A), H314
Serious eye damage(Category 1), H318
For the full text of the H-Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Pictogram

Flame - GHS02Corrosion - GHS05

Signal word
Danger
Hazard statement(s)
H272
May intensify fire; oxidizer.
H314
Causes severe skin burns and eye damage.
Precautionary statement(s)
P210
Keep away from heat.
P220
Keep/Store away from clothing/ combustible materials.
P221
Take any precaution to avoid mixing with combustibles.
P264
Wash skin thoroughly after handling.
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER or doctor/ physician.
P321
Specific treatment (see supplemental first aid instructions on this label).
P363
Wash contaminated clothing before reuse.
P370 + P378
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula: N2O7Zr
Molecular weight: 231.23 g/mol
Zirconium dinitrate oxide
CAS-No.
13826-66-9
EC-No.
237-529-3
Nitric acid
CAS-No.
7697-37-2
EC-No.
231-714-2


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Nitrogen oxides (NOx), Zirconium oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
Use water spray to cool unopened containers.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid inhalation of vapor or mist.
Keep away from sources of ignition -No smoking.
Keep away from heat and sources of ignition.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye
protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: liquid
Odor
No data available
Odor Threshold
No data available
pH
No data available
Melting point/freezing point
No data available
Initial boiling point and boiling range
No data available
Flash point
N/A
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Relative density
1.450 g/cm3
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Bases, Alkali metals, Acetic anhydride, Iron, Copper, Amines, Reducing agents, Organic materials, Alcohols, Brass, Aluminum, Acetonitrile, Acrylonitrile
Hazardous decomposition products
Other decomposition products-
No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
2A-Group 2A: Probably carcinogenic to humans(Zirconium dinitrate oxide)
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea
Liver-Irregularities-Based on Human Evidence
Liver-Irregularities-Based on Human Evidence(Nitric acid)


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability:
No data available
Bioaccumulative potential:
No data available
Mobility in soil:
No data available
Results of PBT and vPvB assessment:
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable.
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. EXPOSURE CONTROLS/PERSONAL PROTECTION

DOT (US)
UN number: 2031
Class: 8
Packing group: II
Proper shipping name: Nitric acid
Reportable Quantity(RQ):
10000 lbs
Poison Inhalation Hazard: No
IMDG
UN number: 2031
Class: 8
Packing group: II
EMS-No: F-A, S-B
Proper shipping name:
NITRIC ACID
IATA
UN number: 2031
Class: 8
Packing group: II
Proper shipping name:
Nitric acid


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
The following components are subject to reporting levels established by SARA Title III, Section 302:
Nitric acid
CAS-No.
7697-37-2
Revision Date
2007-07-01
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Nitric acid
CAS-No.
7697-37-2
Revision Date
2007-07-01
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Nitric acid
CAS-No.
7697-37-2
Revision Date
2007-07-01
Pennsylvania Right To Know Components
Water
CAS-No.
7732-18-5
Zirconium dinitrate oxide
13826-66-9
Nitric acid
7697-37-2
New Jersey Right To Know Components
Water
7732-18-5
Zirconium dinitrate oxide
13826-66-9
Nitric acid
7697-37-2
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Zirconium Oxynitrate Solution

Zirconium Oxynitrate Solution is generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Zirconium Oxynitrate Solution Synonyms

Bis(nitrato)oxozirconium, Zirconium oxide nitrate, Zirconium oxide dinitrate, Zircosol ZN, Bis(nitrato-O)oxozirconium

Chemical Identifiers

Linear Formula ZrO(NO3)2
MDL Number MFCD00011308
EC No. N/A
Beilstein Registry No. N/A
Pubchem CID 83761
IUPAC Name N/A
SMILES O=[N+]([O-])O.[O-][N+](=O)O.O=[Zr]
InchI Identifier InChI=1S/2HNO3.O.Zr/c2*2-1(3)4;;/h2*(H,2,3,4);;
InchI Key UJVRJBAUJYZFIX-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Zirconium products. Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr] 4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. In its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Elemental ZirconiumZirconium is commercially produced as a byproduct of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian wordzargun, meaning gold-like.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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