Gallium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
 Gallium is one of three elements that naturally occur as a liquid at room temperature. The other two are mercury and cesium. The application of gallium that has received the most attention is the production of semiconducting compounds. Of these, the most important are the compounds of gallium with antimony, arsenic or phosphor . Nowadays gallium arsenide (Ga-As) is undoubtedly the most used. This compound is used in the production of several electronic parts such as diodes and transistors, made for voltage rectification, signal amplification, etc. Other gallium arsenide applications are the semiconductor "lasing" and microwave generation and also in sensors to measure temperature, light or magnetic field. Gallium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.
Gallium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for  such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Gallium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Gallium is a Block P, Group 13, Period 4 element. The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electronic configuration is [Ar] 3d10 4s2 4p1. In its elemental form gallium's CAS number is 7440-55-3. The gallium atom has a radius of 122.1.pm and it's Van der Waals radius is 187.pm. Gallium is not toxic.
 All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, thin fillm deposition using sputtering targets and evaporation materials, metallurgy and optical materials and other high technology applications. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Gallium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Gallium was first discovered by Hans Christian Oersted in 1825. The element name originates from the Latin word 'Gallia', the old name of France and the word 'Gallus' meaning rooster.
 Gallium |
 Gallium |
 Gallio |
 Gálio |
 Galio |
 Gallium |
Abundance. The following table shows the abundance of gallium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
| Isotope |
Atomic Mass |
% Abundance on Earth |
| Ga-69 |
68.925581 |
60.11 |
| Ga-71 |
70.924705 |
39.89 |
The following table shows the abundance of Gallium present in the human body and in the universe scaled to parts per billion (ppb) by weight and by atom:
| |
Typical Human Body |
Universe |
| by Weight |
no data |
10 ppb |
| by Atom |
no data |
0.2 ppb |
Safety Data and Biological Role. The safety data for gallium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin. Gallium compounds have no biological role.
Ionization Energy. The ionization energy for gallium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
| 1st Ionization Energy |
578.85 kJ mol-1 |
| 2nd Ionization Energy |
1979.33 kJ mol-1 |
| 3rd Ionization Energy |
2963.09 kJ mol-1 |
Conductivity. As to gallium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 şC is 17.4 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.81. The thermal conductivity of gallium is 40.6 W m-1 K-1.
Thermal Properties. The melting point and boiling point for gallium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
| Heat of Fusion |
5.59 kJ mol-1 |
| Heat of Vaporization |
270.3 kJ mol-1 |
| Heat of Atomization |
276 kJ mol-1 |
Recent Research & Development for GalliumSynthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride.
Pascual S, Bour C, de Mendoza P, Echavarren AM.
Beilstein J Org Chem. 2011;7:1520-5. Epub 2011 Nov 14.
PMID:
22238527
[PubMed - in process]
Radioguided surgery in neuroendocrine tumors using ga-68-labeled somatostatin analogs: a pilot study.
Kaemmerer D, Prasad V, Daffner W, Haugvik SP, Senftleben S, Baum RP, Hommann M.
Clin Nucl Med. 2012 Feb;37(2):142-7.
PMID:
22228336
[PubMed - in process]
Complexation of Metal Ions with TRAP (1,4,7-Triazacyclononane Phosphinic Acid) Ligands and 1,4,7-Triazacyclononane-1,4,7-triacetic Acid: Phosphinate-Containing Ligands as Unique Chelators for Trivalent Gallium.
Simecek J, Schulz M, Notni J, Plutnar J, Kubícek V, Havlícková J, Hermann P.
Inorg Chem. 2012 Jan 2;51(1):577-90. Epub 2011 Dec 20.
PMID:
22221285
[PubMed - in process]
A Sterically Demanding Iminopyridine Ligand Affords Redox-Active Complexes of Aluminum(III) and Gallium(III).
Myers TW, Berben LA.
Inorg Chem. 2012 Jan 5. [Epub ahead of print]
PMID:
22220939
[PubMed - as supplied by publisher]
Report from the 1(st )World Congress on Gallium-68 and Peptide Receptor Radio Nuclide Therapy (PRRNT), Bad Berka (Germany), June 23-26, 2011.
Jurgilewicz D.
Nucl Med Rev Cent East Eur. 2011;14(2):125-6. No abstract available.
PMID:
22219158
[PubMed - in process]
Molecular effects of gallium on osteoclastic differentiation of mouse and human monocytes.
Verron E, Loubat A, Carle GF, Vignes-Colombeix C, Strazic I, Guicheux J, Rochet N, Bouler JM, Scimeca JC.
Biochem Pharmacol. 2011 Dec 19. [Epub ahead of print]
PMID:
22202439
[PubMed - as supplied by publisher]
The ARRONAX Project.
Haddad F, Barbet J, Chatal JF.
Curr Radiopharm. 2011 Jul 1;4(3):186-96.
PMID:
22201708
[PubMed - in process]
Differential Cytostatic and Cytotoxic Action of Metallocorroles against Human Cancer Cells: Potential Platforms for Anticancer Drug Development.
Lim P, Mahammed A, Okun Z, Saltsman I, Gross Z, Gray HB, Termini J.
Chem Res Toxicol. 2012 Jan 10. [Epub ahead of print]
PMID:
22185566
[PubMed - as supplied by publisher]
Autonomic Restoration of Electrical Conductivity.
Blaiszik BJ, Kramer SL, Grady ME, McIlroy DA, Moore JS, Sottos NR, White SR.
Adv Mater. 2011 Dec 20. doi: 10.1002/adma.201102888. [Epub ahead of print]
PMID:
22183927
[PubMed - as supplied by publisher]
Dependence of the Redshifted and Blueshifted Photoluminescence Spectra of Single In_{x}Ga_{1-x}As/GaAs Quantum Dots on the Applied Uniaxial Stress.
Jöns KD, Hafenbrak R, Singh R, Ding F, Plumhof JD, Rastelli A, Schmidt OG, Bester G, Michler P.
Phys Rev Lett. 2011 Nov 18;107(21):217402. Epub 2011 Nov 15.
PMID:
22181923
[PubMed - in process]
Second line salvage chemotherapy for transplant-eligible patients with Hodgkin lymphoma resistant to platinum-containing first-line salvage chemotherapy.
Villa D, Seshadri T, Puig N, Massey C, Tsang R, Keating A, Crump M, Kuruvilla J.
Haematologica. 2011 Dec 16. [Epub ahead of print]
PMID:
22180434
[PubMed - as supplied by publisher]
Hole spin relaxation in Ge-Si core-shell nanowire qubits.
Hu Y, Kuemmeth F, Lieber CM, Marcus CM.
Nat Nanotechnol. 2011 Dec 18;7(1):47-50. doi: 10.1038/nnano.2011.234.
PMID:
22179569
[PubMed - in process]
Synthesis, radiometal labeling and in vitro evaluation of a targeted PPIX derivative.
Behnam Azad B, Cho CF, Lewis JD, Luyt LG.
Appl Radiat Isot. 2012 Mar;70(3):505-11. Epub 2011 Dec 6.
PMID:
22178308
[PubMed - in process]
Leukemia, thyroiditis and gallium-67 scan.
Wiwanitkit V.
Indian J Med Paediatr Oncol. 2011 Apr;32(2):122. No abstract available.
PMID:
22174505
[PubMed - in process]
Unusual presentation of mycosis fungoides as a lump in the scalp.
Imran MB, Othman S, Shahid A.
Singapore Med J. 2011 Nov;52(11):e226-8.
PMID:
22173261
[PubMed - in process]
(68)Ga-labeling and in vivo evaluation of a uPAR binding DOTA- and NODAGA-conjugated peptide for PET imaging of invasive cancers.
Persson M, Madsen J, Ostergaard S, Ploug M, Kjaer A.
Nucl Med Biol. 2011 Dec 13. [Epub ahead of print]
PMID:
22172391
[PubMed - as supplied by publisher]
Cathodoluminescence spectra of gallium nitride nanorods.
Tsai CC, Li GH, Lin YT, Chang CW, Wadekar P, Chen QY, Rigutti L, Tchernycheva M, Julien FH, Tu LW.
Nanoscale Res Lett. 2011 Dec 14;6(1):631. [Epub ahead of print]
PMID:
22168896
[PubMed - as supplied by publisher]
Design of neutral lewis superacids of group 13 elements.
Mück LA, Timoshkin AY, Frenking G.
Inorg Chem. 2012 Jan 2;51(1):640-6. Epub 2011 Dec 14.
PMID:
22168307
[PubMed - in process]
Role of Gallium-67 scintigraphy in the evaluation of occult sepsis in the medical ICU.
Chen WC, Tsai KD, Chen CH, Lin MS, Chen CM, Shih CM, Chen W.
Intern Emerg Med. 2011 Dec 14. [Epub ahead of print]
PMID:
22167445
[PubMed - as supplied by publisher]
Susceptibility of Candida albicans to photodynamic therapy using methylene blue and toluidine blue as photosensitizing dyes.
Pupo YM, Gomes GM, Santos EB, Chaves L, Michel MD, Kozlowski VA Jr, Gomes OM, Gomes JC.
Acta Odontol Latinoam. 2011;24(2):188-92.
PMID:
22165318
[PubMed - in process] |
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