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About Gallium

Gallium Bohr

Just four years after Dmitri Mendeleev published his 1871 periodic table that predicted element 31 and gave it the tentative name eka-aluminum, spectroscopic evidence for the existence of the element was detected in a sphalerite sample by Paul Emile Lecoq de Boisbaudran. Lecoq later went on to discover more elements, but he named gallium, his first, from the Latin for Gaul, the area occupied by his native France. For the following eighty-five years, it was primarily a curiosity--a metal that is solid around room temperature, but liquefies when held in the hand--but did find some use in the preparation of metal alloys with special properties such as low-melting points, in high-temperature thermometers, and as the reflective compound in mirrors.

Gallium use changed forever in the 1960’s, when gallium arsenide was developed as a semiconductor with somewhat different electrical properties than the more common silicon, and that is more suited than silicon to some applications. Notably, gallium arsenide is a direct band gap semiconductor, which means that it can both absorb and emit light with high efficiency. This lends it to use in LEDs and lasers. Additionally, extremely thin layers of gallium arsenide can effectively absorb all the photons from incident sunlight, as opposed to the thick layers of silicon required for the same task. This allows for the creation of one type of thin-film solar cell. Gallium arsenide semiconductor devices also exhibit less noise than those produced from silicon, and are thus favored in many telecommunications applications.

In addition to being a component of gallium arsenide, gallium can be used to make several other semiconducting compounds. The gallium semiconductors are used in many applications, including light-emitting devices such as LEDs and lasers, photovoltaic and thermophotovoltaic cells, and integrated circuits. Gallium also finds use in a few highly specialized technical applications, including in neutrino-detecting telescopes, notable for the sheer volume of gallium they can require--the Gallium-Germanium Neutrino Telescope used by the SAGE experiment at the Baksan Neutrino Observatory in Russia used at least 55 tons of the liquid metal. It can also serve as a liquid metal ion source for focused ion devices. Gadolinium gallium garnets are used to fabricate optical components and as a substrate material for magneto-optical films and high-temperature superconductors. Finally, gallium phosphate is a piezoelectric material that can function at high temperatures unlike alternatives such as quartz, which makes it useful for pressure and force sensors in high-temperature applications.

Gallium is not a compound naturally involved in human biology, but because it is generally considered non-toxic at low doses and mimics some of the properties of iron in the body, it is useful in some medical applications. Gallium tends to concentrate in areas of high levels of inflammation and cell growth, and therefore radioactive isotopes of the element are used in scans for tracking the spread of some cancers and disorders of the immune system. Additionally, gallium salts are used to treat hypercalcemia that results from cancers metastasizing to the bones, and are under investigation as treatment for certain types of cancers. Gallium compounds are also known to be toxic to some disease-causing microorganisms, and organometallic gallium compounds have shown some promise as potential malaria treatments.

The few minerals which contain substantial percentages of gallium are too rare to serve as a commercially viable source of the element. Gallium is found in small amounts in the aluminum ore bauxite and the zinc ore sphalerite, and is therefore extracted from waste materials from the processing of these metals.

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Semiconductor & Optical

High Purity (99.999%) Gallium (Ga) Sputtering TargetSummary. Gallium has received much attention in relation to its application in the production of semiconducting compounds. Of these, the most important are the compounds of gallium with antimony, arsenic or phosphor. Gallium arsenide (GaAs) is used in the production of diodes and transistors for voltage rectification and signal amplification. Other gallium arsenide applications include semiconductor "lasing" and microwave generation. Gallium is also used in sensors to measure temperature, light or magnetic field. High Purity (99.999%) Gallium Oxide (Ga2O3) Powder Elemental or metallic forms of gallium include pellets for evaporation source material purposes. Gallium oxide is available in forms including powders and dense pellets for use as optical coating and thin film applications.Oxides tend to be insoluble. Gallium fluoride is another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Gallium is available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.

Gallium Properties

Gallium (Ga) atomic and molecular weight, atomic number and elemental symbolGallium is a Block P, Group 13, Period 4 element. The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d10 4s2 4p1. The gallium atom has a radius of 122.1.pm and it's Van der Waals radius is 187.pm. In its elemental form, CAS 7440-55-3, gallium has a silvery appearance. Gallium Bohr ModelGallium is one of three elements that occur naturally as a liquid at room temperature. Elemental GalliumThe other two are mercury and cesium. Gallium does not exist by itself in nature and is sourced commercially from bauxite and sphalerite. Gallium was first discovered by Hans Christian Oersted in 1825. The element name originates from the Latin word 'Gallia', the old name of France and the word 'Gallus' meaning rooster. Gallium information, including technical data, safety data, high purity properties, and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on earth, conductivity and thermal properties are also included.

Symbol: Ga
Atomic Number: 31
Atomic Weight: 69.723
Element Category: post-transition metal
Group, Period, Block: 13, 4, p
Color: silvery white/ silvery-blue
Other Names: N/A
Melting Point: 29.765°C, 85.576°F, 302.915 K
Boiling Point: 2229°C, 4044.2°F, 2502.15 K
Density: 5.91 g·cm3
Liquid Density @ Melting Point: 6.095 g·cm3
Density @ 20°C: 5.907 g/cm3
Density of Solid: 5904 kg·m3
Specific Heat: 0.372 @20°C J/g mol
Superconductivity Temperature: 1.083 [or -272.067 °C (-457.72 °F)] K
Triple Point: N/A
Critical Point: N/A
Heat of Fusion (kJ·mol-1): 5.59
Heat of Vaporization (kJ·mol-1): 270.3
Heat of Atomization (kJ·mol-1): 276
Thermal Conductivity: 40.6 W·m-1·K-1
Thermal Expansion: (25 °C) 18 µm·mol-1·K-1
Electrical Resistivity: (20 °C) 270 nΩ·m
Tensile Strength: N/A
Molar Heat Capacity: 25.86 J·mol-1·K-1
Young's Modulus: 9.8 GPa
Shear Modulus: N/A
Bulk Modulus: N/A
Poisson Ratio: 0.47
Mohs Hardness: 1.5
Vickers Hardness: N/A
Brinell Hardness: 60 MPa
Speed of Sound: (20 °C) 2740 m·s-1
Pauling Electronegativity: 1.81
Sanderson Electronegativity: 2.42
Allred Rochow Electronegativity: 1.82
Mulliken-Jaffe Electronegativity: 2.01 (sp2 orbital)
Allen Electronegativity: 1.756
Pauling Electropositivity: 2.19
Reflectivity (%): N/A
Refractive Index: N/A
Electrons: 31
Protons: 31
Neutrons: 39
Electron Configuration: [Ar] 3d10 4s2 4p1
Atomic Radius: 135 pm
Atomic Radius,
non-bonded (Å):
1.87
Covalent Radius: 122±3 pm
Covalent Radius (Å): 1.23
Van der Waals Radius: 187 pm
Oxidation States: 3, 2, 1 (amphoteric oxide)
Phase: Solid
Crystal Structure: orthorhombic
Magnetic Ordering: diamagnetic
Electron Affinity (kJ·mol-1) 41.474
1st Ionization Energy: 578.85 kJ·mol-1
2nd Ionization Energy: 1979.33 kJ·mol-1
3rd Ionization Energy: 2963.09 kJ·mol-1
CAS Number: 7440-55-3
EC Number: 231-163-8
MDL Number: MFCD00134045
Beilstein Number: N/A
SMILES Identifier: [Ga]
InChI Identifier: InChI=1S/Ga
InChI Key: GYHNNYVSQQEPJS-UHFFFAOYSA-N
PubChem CID: 23981
ChemSpider ID: 4514603
Earth - Total: 3.1 ppm 
Mercury - Total: 0.50 ppm
Venus - Total: 3.4 ppm 
Earth - Seawater (Oceans), ppb by weight: 0.03
Earth - Seawater (Oceans), ppb by atoms: 0.0027
Earth -  Crust (Crustal Rocks), ppb by weight: 19000
Earth -  Crust (Crustal Rocks), ppb by atoms: 5500
Sun - Total, ppb by weight: 40
Sun - Total, ppb by atoms: 0.6
Stream, ppb by weight: 0.15
Stream, ppb by atoms: 0.002
Meterorite (Carbonaceous), ppb by weight: 7800
Meterorite (Carbonaceous), ppb by atoms: 2000
Typical Human Body, ppb by weight: N/A
Typical Human Body, ppb by atom: N/A
Universe, ppb by weight: 10
Universe, ppb by atom: 0.2
Discovered By: Lecoq de Boisbaudran
Discovery Date: 1875
First Isolation: Lecoq de Boisbaudran (1875)

Health, Safety & Transportation Information for Gallium

Gallium is not toxic in its elemental form; however, safety data for Gallium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific Gallium material or compound referenced in the “Gallium Products” tab.

Safety Data
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H314
Hazard Codes C
Risk Codes 34
Safety Precautions 26-36/37/39-45
RTECS Number LW8600000
Transport Information UN 2803 8/PG 3
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Corrosion-Corrosive to metals

Gallium Isotopes

Gallium (Ga) has two stable isotopes: gallium-69 and gallium-71.

Nuclide Isotopic Mass Half-Life Mode of Decay Nuclear Spin Magnetic Moment Binding Energy (MeV) Natural Abundance
(% by atom)
56Ga 55.99491(28)# N/A p to 55Zn 3+# N/A 423.21 -
57Ga 56.98293(28)# N/A p to 56Zn 1/2-# N/A 442.47 -
58Ga 57.97425(23)# N/A p to 57Zn 2+# N/A 458 -
59Ga 58.96337(18)# N/A p to 58Zn 3/2-# N/A 476.33 -
60Ga 59.95706(12)# 70(10) ms β+ to 60Zn (2+) N/A 490 -
61Ga 60.94945(6) 168(3) ms β+ to 61Zn 3/2- N/A 505.53 -
62Ga 61.944175(30) 116.18(4) ms β+ to 62Zn 0+ N/A 518.27 -
63Ga 62.9392942(14) 32.4(5) s β+ to 63Zn (3/2-) N/A 531 -
64Ga 63.9368387(22) 2.627(12) min EC to 64Zn 0(+#) N/A 541.88 -
65Ga 64.9327348(9) 15.2(2) min EC to 65Zn 3/2- N/A 553.68 -
66Ga 65.931589(3) 9.49(7) h EC to 66Zn 0+ N/A 562.69 -
67Ga 66.9282017(14) 3.2612(6) d EC to 67Zn 3/2- 1.8507 573.57 -
68Ga 67.9279801(16) 67.71(9) min EC to 68Zn 1+ 0.01175 582.58 -
69Ga 68.9255736(13) STABLE - 3/2- 2.01659 592.52 60.108
70Ga 69.9260220(13) 21.14(3) min EC to 70Zn; β- to 70Ge 1+ N/A 599.67 -
71Ga 70.9247013(11) STABLE - 3/2- 2.56227 609.61 39.892
72Ga 71.9263663(11) 14.095(3) h β- to 72Ge 3- -0.13224 615.82 -
73Ga 72.9251747(18) 4.86(3) h β- to 73Ge 3/2- N/A 624.83 -
74Ga 73.926946(4) 8.12(12) min β- to 74Ge (3-) N/A 631.98 -
75Ga 74.9265002(26) 126(2) s β- to 75Ge (3/2)- N/A 640.06 -
76Ga 75.9288276(21) 32.6(6) s β- to 76Ge (2+,3+) N/A 646.28 -
77Ga 76.9291543(26) 13.2(2) s β- to 77Ge (3/2-) N/A 653.42 -
78Ga 77.9316082(26) 5.09(5) s β- to 78Ge (3+) N/A 659.64 -
79Ga 78.93289(11) 2.847(3) s β- to 79Ge; β- + n to 78Ge (3/2-)# N/A 666.78 -
80Ga 79.93652(13) 1.697(11) s β- to 80Ge; β- + n to 79Ge -3 N/A 671.14 -
81Ga 80.93775(21) 1.217(5) s β- to 81Ge; β- + n to 80Ge (5/2-) N/A 678.28 -
82Ga 81.94299(32)# 0.599(2) s β- to 82Ge; β- + n to 81Ge (1,2,3) N/A 681.7 -
83Ga 82.94698(32)# 308(1) ms β- to 83Ge; β- + n to 82Ge 3/2-# N/A 686.06 -
84Ga 83.95265(43)# 0.085(10) s β- + n to 73Ge; β- to 84Ge N/A N/A 688.55 -
85Ga 84.95700(54)# 50# ms [>300 ns] Unknown 3/2-# N/A 691.97 -
86Ga 85.96312(86)# 30# ms [>300 ns] Unknown N/A N/A 694.46 -
Gallium (Ga) Elemental Symbol

Recent Research & Development for Gallium

  • P. Zhang, L.W. Shen, J. Ouyang, Y.M. Zhang, S.Q. Wu, Z.M. Sun, Room temperature mushrooming of gallium wires and its growth mechanism, Journal of Alloys and Compounds, Volume 619, 15 January 2015
  • Wei-Sheng Liu, Shen-Yu Wu, Chao-Yu Hung, Ching-Hsuan Tseng, Yu-Lin Chang, Improving the optoelectronic properties of gallium ZnO transparent conductive thin films through titanium doping, Journal of Alloys and Compounds, Volume 616, 15 December 2014
  • Mohamed Bakr Mohamed, M. Yehia, Cation distribution and magnetic properties of nanocrystalline gallium substituted cobalt ferrite, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Erkan Aydin, Mehmet Sankir, Nurdan Demirci Sankir, Conventional and rapid thermal annealing of spray pyrolyzed copper indium gallium sulfide thin films, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Ming-Wei Wu, Pang-Hsin Lai, Chia-Hong Hong, Fang-Cheng Chou, The sintering behavior, microstructure, and electrical properties of gallium-doped zinc oxide ceramic targets, Journal of the European Ceramic Society, Volume 34, Issue 15, December 2014
  • Min-Jia Wang, Hui Yang, Qi-Long Zhang, Zhi-Sheng Lin, Zi-Shan Zhang, Dan Yu, Liang Hu, Microstructure and dielectric properties of BaTiO3 ceramic doped with yttrium, magnesium, gallium and silicon for AC capacitor application, Materials Research Bulletin, Volume 60, December 2014
  • Helge Reinsch, Dirk De Vos, Structures and properties of gallium-MOFs with MIL-53-topology based on aliphatic linker molecules, Microporous and Mesoporous Materials, Volume 200, December 2014
  • V.V. Serikov, N.M. Kleinerman, A.V. Vershinin, N.V. Mushnikov, A.V. Protasov, L.A. Stashkova, O.I. Gorbatov, A.V. Ruban, Yu.N. Gornostyrev, Formation of solid solutions of gallium in Fe–Cr and Fe–Co alloys: Mössbauer studies and first-principles calculations, Journal of Alloys and Compounds, Volume 614, 25 November 2014
  • Jae-Hun Jeong, Dong-Won Jung, Eun-Suok Oh, Lithium storage characteristics of a new promising gallium selenide anodic material, Journal of Alloys and Compounds, Volume 613, 15 November 2014
  • Fahmi Fariq Muhammad, Khaulah Sulaiman, Optical and morphological modifications in post-thermally treated tris(8-hydroxyquinoline) gallium films deposited on quartz substrates, Materials Chemistry and Physics, Volume 148, Issues 1–2, 14 November 2014