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Gallium (By Crystallization)
Gallium Antimonide (By Crystallization)
Gallium Arsenide (By Crystallization)
Gallium Chloride
Gallium Fluoride
Gallium Indium Antimonide (By Crystallization)
Gallium Indium Arsenide (By Crystallization)
Gallium Nitrate
Gallium Phosphide (By Crystallization)
Gallium Selenide Single Crystal
Gallium Selenide
Gallium(II) Selenide
Gallium Selenide Sputtering Target
Gallium Sulfate
Gallium Telluride
Gallium(III) Telluride (By Crystallization)
Gallium Tube
Gallium
Gallium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Gallium is one of three elements that naturally occur as a liquid at room temperature. The other two are mercury and cesium. The application of gallium that has received the most attention is the production of semiconducting compounds. Of these, the most important are the compounds of gallium with antimony, arsenic or phosphor . Nowadays gallium arsenide (Ga-As) is undoubtedly the most used. This compound is used in the production of several electronic parts such as diodes and transistors, made for voltage rectification, signal amplification, etc. Other gallium arsenide applications are the semiconductor "lasing" and microwave generation and also in sensors to measure temperature, light or magnetic field. Gallium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Gallium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Gallium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Gallium is a Block P, Group 13, Period 4 element. The electronic configuration is [Ar] 3d10 4s2 4p1. In its elemental form gallium's CAS number is 7440-55-3. The gallium atom has a radius of 122.1.pm and it's Van der Waals radius is 187.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Gallium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Gallium was first discovered by Hans Christian Oersted in 1825.

French Gallium German Gallium Italian Gallio Portuguese Gálio Spanish Galio Swedish Gallium

Abundance. The following table shows the abundance of gallium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ga-69
68.925581
60.11
Ga-71
70.924705
39.89

Safety Data. The safety data for gallium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for gallium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
578.85 kJ mol-1
2nd Ionization Energy
1979.33 kJ mol-1
3rd Ionization Energy
2963.09 kJ mol-1

Conductivity. As to gallium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 17.4 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.81. The thermal conductivity of gallium is 40.6 W m-1 K-1.

Thermal Properties. The melting point and boiling point for gallium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
5.59 kJ mol-1
Heat of Vaporization
270.3 kJ mol-1
Heat of Atomization
276 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ga 31 69.72 g.mol -1 unknown 5.1 g.cm-3 at 20 °C 29.8 °C 2204 °C 187.pm 0.083 nm (+3) 578.85 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Gallium

  • Simultaneous dual-band ultra-high resolution full-field optical coherence tomography. Sacchet D, Moreau J, Georges P, Dubois A. Opt Express. 2008 Nov 24;16(24):19434-46. PMID: 19030031 [PubMed - in process]

  • Twinning superlattices in indium phosphide nanowires. Algra RE, Verheijen MA, Borgström MT, Feiner LF, Immink G, van Enckevort WJ, Vlieg E, Bakkers EP. Nature. 2008 Nov 20;456(7220):369-372. PMID: 19020617 [PubMed - as supplied by publisher]

  • Management and prevention of diabetic foot ulcers and infections: a health economic review. Chow I, Lemos EV, Einarson TR. Pharmacoeconomics. 2008;26(12):1019-35. doi: 10.2165/0019053-200826120-00005. PMID: 19014203 [PubMed - in process]

  • Clinical, morphological, and ultrastructural aspects with the use of Er:YAG and Er,Cr:YSGG lasers in restorative dentistry. Iaria G. Gen Dent. 2008 Nov-Dec;56(7):636-9. PMID: 19014022 [PubMed - in process]

  • Influence of etching with erbium, chromium:yttrium-scandium-gallium-garnet laser on microleakage of class V restoration. Marotti J, Geraldo-Martins VR, Bello-Silva MS, de Paula Eduardo C, Apel C, Gutknecht N. Lasers Med Sci. 2008 Nov 15. [Epub ahead of print] PMID: 19011950 [PubMed - as supplied by publisher]

  • Effect of low-level laser therapy after implantation of poly-L: -lactic/polyglycolic acid in the femurs of rats. Freddo AL, Rodrigo SM, Massotti FP, Etges A, de Oliveira MG. Lasers Med Sci. 2008 Nov 15. [Epub ahead of print] PMID: 19011949 [PubMed - as supplied by publisher]

  • cis/trans Isomerism of Hydroalumination and Hydrogallation Products-Reflections on Stability and Rearrangement Mechanism. Uhl W, Bock HR, Claesener M, Layh M, Tiesmeyer I, Würthwein EU. Chemistry. 2008 Nov 13. [Epub ahead of print] PMID: 19009572 [PubMed - as supplied by publisher]

  • Nanopipes in Gallium Nitride Nanowires and Rods. Jacobs BW, Crimp MA, McElroy K, Ayres VM. Nano Lett. 2008 Nov 14. [Epub ahead of print] PMID: 19007288 [PubMed - as supplied by publisher]

  • A quinazoline-derivative DOTA-type gallium(III) complex for targeting epidermal growth factor receptors: synthesis, characterisation and biological studies. Garcia R, Fousková P, Gano L, Paulo A, Campello P, Tóth E, Santos I. J Biol Inorg Chem. 2008 Nov 13. [Epub ahead of print] PMID: 19005706 [PubMed - as supplied by publisher]

  • Macroscopic signature of protected spins in a dense frustrated magnet. Ghosh S, Rosenbaum TF, Aeppli G. Phys Rev Lett. 2008 Oct 10;101(15):157205. Epub 2008 Oct 10. PMID: 18999636 [PubMed - in process]

  • When Arsine Makes the Difference: Chelating Phosphino and Bridging Arsinoarylthiolato Gallium Complexes. Va?lean AM, Go´mez-Ruiz S, Lo¨nnecke P, Silaghi-Dumitrescu I, Silaghi-Dumitrescu L, Hey-Hawkins E. Inorg Chem. 2008 Nov 6. [Epub ahead of print] PMID: 18986138 [PubMed - as supplied by publisher]

  • Helium ion microscopy and its application to nanotechnology and nanometrology. Postek MT, Vladár AE. Scanning. 2008 Nov 4. [Epub ahead of print] PMID: 18985698 [PubMed - as supplied by publisher]

  • CSi(2)Ga (2): a neutral planar tetracoordinate carbon (ptC) building block. Yang LM, Li XP, Ding YH, Sun CC. J Mol Model. 2009 Jan;15(1):97-104. Epub 2008 Nov 5. PMID: 18985395 [PubMed - in process]

  • Synthesis, characterisation and structures of thio-, seleno- and telluro-ether complexes of gallium(iii). Gurnani C, Levason W, Ratnani R, Reid G, Webster M. Dalton Trans. 2008 Nov 28;(44):6274-82. Epub 2008 Oct 2. PMID: 18985261 [PubMed - in process]

  • Disruption of Murine Cardiac Allograft Acceptance by Latent Cytomegalovirus. Cook CH, Bickerstaff AA, Wang JJ, Zimmerman PD, Forster MR, Nadasdy T, Colvin RB, Hadley GA, Orosz CG. Am J Transplant. 2008 Oct 31. [Epub ahead of print] PMID: 18976295 [PubMed - as supplied by publisher]

  • Cationic Terminal Gallylene Complexes by Halide Abstraction: Coordination Chemistry of a Valence Isoelectronic Analogue of CO and N2. Coombs ND, Vidovic D, Day JK, Thompson AL, Pevelen DD, Stasch A, Clegg W, Russo L, Male L, Hursthouse MB, Willock DJ, Aldridge S. J Am Chem Soc. 2008 Nov 1. [Epub ahead of print] PMID: 18975947 [PubMed - as supplied by publisher]

  • 2,2,6,6-Tetramethylpiperidinogallium as a Terminal and Bridging Ligand in Homo- and Heteroleptic Chromium, Nickel, and Cobalt Complexes. Seifert A, Linti G. Inorg Chem. 2008 Nov 1. [Epub ahead of print] PMID: 18975940 [PubMed - as supplied by publisher] Related Articles 18: Controlled delivery of antimicrobial gallium ions from phosphate-based glasses. Valappil SP, Ready D, Abou Neel EA, Pickup DM, O'Dell LA, Chrzanowski W, Pratten J, Newport RJ, Smith ME, Wilson M, Knowles JC. Acta Biomater. 2008 Oct 10. [Epub ahead of print] PMID: 18974026 [PubMed - as supplied by publisher]

  • An Electrochemical Study of Antineoplastic Gallium, Iron and Ruthenium Complexes with Redox Noninnocent alpha-N-Heterocyclic Chalcogensemicarbazones. Kowol CR, Reisner E, Chiorescu I, Arion VB, Galanski M, Deubel DV, Keppler BK. Inorg Chem. 2008 Oct 31. [Epub ahead of print] PMID: 18973290 [PubMed - as supplied by publisher]

  • Synthesis and characterization of a novel cross-linking complex of beta-cyclodextrin-o-vanillin furfuralhydrazone and highly selective spectrofluorimetric determination of trace gallium. Tang B, Chen ZZ, Zhang N, Zhang J, Wang Y. Talanta. 2006 Jan 15;68(3):575-80. Epub 2005 Jun 6. PMID: 18970359 [PubMed - in process]

 

 

 

 

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