About Chromates

Chromate Ion

Chromate salts contain the anion CrO42-, while dichromate salts contain the dichromate anion, Cr2O72-. Both classes of compounds contain chromium in the oxidation state +6--hexavalent chromium--and act as strong oxidizing agents. Water soluble chromates are frequently used in chrome electroplating processes used to protect underlying metals from corrosion or improve paint adhesion. Chromate conversion coating, a process which uses oxidants to passivate certain metal alloy surfaces, may utilize chromate derived from chromic acid. Non-soluble chromates have strong colors and have been used as pigments. Because hexavalent chromium is now known to be toxic, chromate waste disposal is regulated and chromate usage is declining in areas where there are suitable substitutes. In particular, chromium pigments such as chrome yellow, widely recognized as the color of American school buses, have largely fallen out of use in favor of safer pigment compounds.

Recent Research & Development for Chromates

Chromate exposure induces DNA hypermethylation of the mismatch repair gene MLH1 in lung cancer., Tsuboi, Mitsuhiro, Kondo Kazuya, Soejima Shiho, Kajiura Koichiro, Kawakita Naoya, Toba Hiroaki, Kawakami Yukikiyo, Yoshida Mitsuteru, Takizawa Hiromitsu, and Tangoku Akira , Mol Carcinog, 2019 Oct 03, (2019)

Insights into the mode of flavin mononucleotide binding and catalytic mechanism of bacterial chromate reductases: A molecular dynamics simulation study., Pradhan, Sukanta Kumar, Singh Nihar Ranjan, Dehury Budheswar, Panda Debashis, Modi Mahendra Kumar, and Thatoi Hrudayanath , J Cell Biochem, 2019 May 26, (2019)

Structural characteristics of cake layer in membrane bioreactor with chromate exposure., Zhou, Lijie, Ye Biao, and Xia Siqing , Ecotoxicol Environ Saf, 2019 Mar, Volume 169, p.583-589, (2019)

Steering wheel and gearstick dermatitis caused by chromate., Tewari, Angela, Khan Imran, and Ostlere Lucy , Contact Dermatitis, 2019 Jun 19, (2019)

Insights into chromate resistance of LDS1., Lemaire, Olivier N., Honoré Flora A., Tempel Sébastien, Fortier Emma M., Leimkühler Silke, Méjean Vincent, and Iobbi-Nivol Chantal , Appl Environ Microbiol, 2019 Jul 12, (2019)

Anaerobic methane oxidation coupled to chromate reduction in a methane-based membrane biofilm batch reactor., Dong, Qiu-Yi, Wang Zhen, Shi Ling-Dong, Lai Chun-Yu, and Zhao He-Ping , Environ Sci Pollut Res Int, 2019 Jul 08, (2019)

Putting the Squeeze on Lead Chromate Nanorods., Yuan, Hongsheng, Rodriguez-Hernandez Placida, Muñoz Alfonso, and Errandonea Daniel , J Phys Chem Lett, 2019 Aug 15, Volume 10, Issue 16, p.4744-4751, (2019)

Persistence of chromate in vadose zone and aquifer sediments in Hanford, Washington., Szecsody, Jim E., Truex Mike J., Qafoku Nikolla P., McKinley James P., Ivarson Kristine A., and Di Pietro Silvina , Sci Total Environ, 2019 Aug 01, Volume 676, p.482-492, (2019)

Association of blood chromium and rare earth elements with the risk of DNA damage in chromate exposed population., Bai, Yi, Long Changmao, Hu Guiping, Zhou Di, Gao Xiaoying, Chen Zhangjian, Wang Tiancheng, Yu Shanfa, Han Youli, and Yan Lailai , Environ Toxicol Pharmacol, 2019 Aug 01, Volume 72, p.103237, (2019)

[Early effects of low-level long-term occupational chromate exposure on workers'health]., Liu, J X., Hu G P., Zhao L, Zhang Y M., Wang L, Jia G, Liu R X., Feng H M., and Xu H D. , Beijing Da Xue Xue Bao Yi Xue Ban, 2019 Apr 18, Volume 51, Issue 2, p.307-314, (2019)

Adsorption mechanisms of chromate and phosphate on hydrotalcite: A combination of macroscopic and spectroscopic studies., Hsu, Liang-Ching, Tzou Yu-Min, Chiang Po-Neng, Fu Wei-Min, Wang Ming-Kuang, Teah Heng Yi, and Liu Yu-Ting , Environ Pollut, 2019 Apr, Volume 247, p.180-187, (2019)

A Unified Surface Complexation Modeling Approach for Chromate Adsorption on Iron Oxides., Bompoti, Nefeli Maria, Chrysochoou Maria, and Machesky Michael L. , Environ Sci Technol, 2019 06 04, Volume 53, Issue 11, p.6352-6361, (2019)

Chromate resistance mechanisms in ., Sturm, Gunnar, Brunner Stefanie, Suvorova Elena, Dempwolff Felix, Reiner Johannes, Graumann Peter, Bernier-Latmani Rizlan, Majzlan Juraj, and Gescher Johannes , Appl Environ Microbiol, 2018 Sep 28, (2018)

Highly Performing Chromate-Based Ceramic Anodes (YCaCrCu O) for Low-Temperature Solid Oxide Fuel Cells., A Hussain, Mohammed, Pan Ke-Ji, Huang Yi-Lin, Robinson Ian A., Gore Colin, and Wachsman Eric D. , ACS Appl Mater Interfaces, 2018 Oct 24, Volume 10, Issue 42, p.36075-36081, (2018)

Using chromate to investigate the impact of mineral-organic contact time on the surface reactivity of goethite., Hales-Messenger, Stacey, and Swindle Andrew , Environ Sci Process Impacts, 2018 Oct 17, Volume 20, Issue 10, p.1469-1478, (2018)