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Lithium Chromate Hydrate

CAS #:

Linear Formula:

Li2CrO4 • xH2O

MDL Number:

MFCD00167314

EC No.:

238-244-7

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lithium Chromate Hydrate
LI-CRAT-02-C.XHYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Lithium Chromate Hydrate
LI-CRAT-03-C.XHYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Lithium Chromate Hydrate
LI-CRAT-04-C.XHYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Lithium Chromate Hydrate
LI-CRAT-05-C.XHYD
Pricing > SDS > Data Sheet >

Lithium Chromate Hydrate Properties (Theoretical)

Compound Formula H2CrLi2O5
Molecular Weight 147.89
Appearance Powder
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 147.96274
Monoisotopic Mass 147.96274

Lithium Chromate Hydrate Health & Safety Information

Signal Word Danger
Hazard Statements H317-H350
Hazard Codes Xn
Precautionary Statements P201-P261-P280-P363-P405-P501
Risk Codes N/A
Safety Statements N/A
Harmonized Tariff Code 2841.50
Transport Information UN3077 9/PG III
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 05/25/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lithium Chromate Hydrate

Product Number: All applicable American Elements product codes, e.g. LI-CRAT-02-C.XHYD , LI-CRAT-03-C.XHYD , LI-CRAT-04-C.XHYD , LI-CRAT-05-C.XHYD

CAS #: 7789-01-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS) GHS08 Health hazard Carc. 1B H350 May cause cancer. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. Hazards not otherwise classified No information known. Label elements GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms
Exclamation Mark - GHS07 Health Hazard - GHS08
GHS07 GHS08 Signal word Danger Hazard statements H317 May cause an allergic skin reaction. H350 May cause cancer. Precautionary statements P201 Obtain special instructions before use. P261 Avoid breathing dust/fume/gas/mist/vapors/spray P280 Wear protective gloves/protective clothing/eye protection/face protection. P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. WHMIS classification D2A - Very toxic material causing other toxic effects Classification system HMIS ratings (scale 0-4) (Hazardous Materials Identification System) Health (acute effects) = 2 Flammability = 0 Physical Hazard = 1 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances CAS# Description: 7789-01-7 Lithium chromate hydrate Identification number(s): EC number: 238-244-7

SECTION 4. FIRST AID MEASURES

Description of first aid measures After inhalation Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice. After skin contact Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice. After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing Seek medical treatment. Information for doctor Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. May cause cancer. Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire. Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Toxic metal oxide fume Lithium oxide Advice for firefighters Protective equipment: Wear self-contained respirator. Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions: Do not allow product to reach sewage system or any water course. Methods and material for containment and cleaning up: Dispose of contaminated material as waste according to section 13. Ensure adequate ventilation. Prevention of secondary hazards: No special measures required. Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: Substance is not listed. PAC-2: Substance is not listed. PAC-3: Substance is not listed.

SECTION 7. HANDLING AND STORAGE

Handling Precautions for safe handling Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace. Open and handle container with care. Information about protection against explosions and fires: The product is not flammable Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Specific end use(s) No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: No data Exposure controls Personal protective equipment General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks and at the end of work. Store protective clothing separately. Maintain an ergonomically appropriate working environment. Breathing equipment: Use suitable respirator when high concentrations are present. Protection of hands: Impervious gloves Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Penetration time of glove material (in minutes) Not determined Eye protection: Safety glasses with side shields / NIOSH (US) or EN 166(EU) Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties General Information Appearance: Form: Powder Odor: Not determined Odor threshold: Not determined. pH-value: Not applicable. Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined Sublimation temperature / start: Not determined Flammability (solid, gaseous) Not determined. Ignition temperature: Not determined Decomposition temperature: Not determined Auto igniting: Not determined. Danger of explosion: Not determined. Explosion limits: Lower: Not determined Upper: Not determined Vapor pressure: Not applicable. Density: Not determined Relative density Not determined. Vapor density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: Not determined Partition coefficient (n-octanol/water): Not determined. Viscosity: dynamic: Not applicable. kinematic: Not applicable. Other information No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

Reactivity No information known. Chemical stability Stable under recommended storage conditions. Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications. Possibility of hazardous reactions Reacts with strong oxidizing agents Conditions to avoid No further relevant information available. Incompatible materials: Oxidizing agents Hazardous decomposition products: Toxic metal oxide fume Lithium oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects Acute toxicity: No effects known. LD/LC50 values that are relevant for classification: No data Skin irritation or corrosion: May cause irritation Eye irritation or corrosion: May cause irritation Sensitization: May cause an allergic skin reaction. Germ cell mutagenicity: No effects known. Carcinogenicity: May cause cancer. EPA-A: human carcinogen: sufficient evidence from epidemiologic studies to support a causal association between exposure and cancer. IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity. ACGIH A1: Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemiologic studies of, or convincing clinical evidence in, exposed humans. NTP-K: Known to be carcinogenic: sufficient evidence from human studies. Reproductive toxicity: No effects known. Specific target organ system toxicity - repeated exposure: No effects known. Specific target organ system toxicity - single exposure: No effects known. Aspiration hazard: No effects known. Subacute to chronic toxicity: No effects known. Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Very toxic for aquatic organisms Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. May cause long lasting harmful effects to aquatic life. Avoid transfer into the environment. Very toxic for aquatic organisms Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods Recommendation Consult state, local or national regulations to ensure proper disposal. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number DOT, IMDG, IATA UN3077 UN proper shipping name DOT Environmentally hazardous substances, solid, n.o.s. (Lithium chromate) ADR 3077 Environmentally hazardous substances, solid, n.o.s. (Lithium chromate) IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lithium chromate) Transport hazard class(es) DOT, IMDG Class 9 Miscellaneous dangerous substances and articles Label 9 ADR Class 9 (M7) Miscellaneous dangerous substances and articles Label 9 IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT, ADR, IMDG, IATA III Environmental hazards: Special marking (ADR): Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles EMS Number: F-A,S-F Stowage Category A Stowage Code SW23 When transported in BK3 bulk container, see 7.6.2.12 and 7.7.3.9. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: No limit On cargo aircraft only: No limit Marine Pollutant (DOT): No IMDG Limited quantities (LQ) 5 kg Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g UN "Model Regulation": UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.(LITHIUM CHROMATE), 9, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms GHS07 GHS08 Signal word Danger Hazard statements H317 May cause an allergic skin reaction. H350 May cause cancer. Precautionary statements P201 Obtain special instructions before use. P261 Avoid breathing dust/fume/gas/mist/vapors/spray P280 Wear protective gloves/protective clothing/eye protection/face protection. P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory. All components of this product are listed on the Canadian Domestic Substances List (DSL). SARA Section 313 (specific toxic chemical listings) 7789-01-7 Lithium chromate dihydrate California Proposition 65 Prop 65 - Chemicals known to cause cancer 7789-01-7 Lithium chromate dihydrate Prop 65 - Developmental toxicity 7789-01-7 Lithium chromate dihydrate Prop 65 - Developmental toxicity, female 7789-01-7 Lithium chromate dihydrate Prop 65 - Developmental toxicity, male 7789-01-7 Lithium chromate dihydrate Information about limitation of use: For use only by technically qualified individuals. This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372. Other regulations, limitations and prohibitive regulations Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed. The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed. Substance is not listed. Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lithium Chromate Hydrate

Chromate IonLithium Chromate Hydrate is generally immediately available in most volumes. Hydrate or anhydrous forms may be purchased. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lithium Chromate Hydrate Synonyms

Lithium chromate(VI) hydrate; Dilithium chromate hydrate; Lithium dioxido(dioxo)chromium hydrate (2:1:1); Lithium chromate dihydrate

Chemical Identifiers

Linear Formula Li2CrO4 • xH2O
MDL Number MFCD00167314
EC No. 238-244-7
Beilstein Registry No. N/A
Pubchem CID 16212570
IUPAC Name dilithium dioxido(dioxo)chromium hydrate
SMILES [Li+].[Li+].[O-][Cr]([O-])(=O)=O.O
InchI Identifier InChI=1S/Cr.2Li.H2O.4O/h;;;1H2;;;;/q;2*+1;;;;2*-1
InchI Key BPHMTHBOSQWANY-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Chromium products. Chromium (atomic symbol: Cr, atomic number: 24) is a Block D, Group 6, Period 4 element with an atomic weight of 51.9961. Chromium Bohr ModelThe number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electron configuration is [Ar] 3d5 4s1. Chromium was first discovered by Louis Nicolas Vauquelin in 1797. It was first isolated in 1798, also by Louis Nicolas Vauquelin. The chromium atom has a radius of 128 pm and a Van der Waals radius of 189 pm. In its elemental form, chromium has a lustrous steel-gray appearance. Elemental ChromiumChromium is the hardest metal element in the periodic table and the only element that exhibits antiferromagnetic ordering at room temperature, above which it tranforms into a paramagnetic solid. The most common source of chromium is chromite ore (FeCr2O4). Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color.

Lithium Bohr ModelSee more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.

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May 25, 2019
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