About Tungstates

Tungstate Ion

Tungstates are mixed oxides containing tungsten or compounds that contain an oxoanion of tungsten. Most useful tungsten ores, including scheelite, the naturally occurring form of calcium tungstate, belong to this class of compounds. Alkali metal tungstates are typically water soluble and may be used for their properties in solution. Sodium tungstate is used as a source of tungsten in chemical synthesis and as a catalyst in organic synthesis, while lithium tungstate is used to produce high-density aqueous solutions used in the separation of minerals.

Most other metal tungstates have minimal solubility in water, and are used in various solid forms, including bulk single crystals, thin films, nanostructures, and powders. Cadmium tungstate is one such material, generally used as a scintillation crystal for the detection of gamma rays or x-rays, lending it to use in compact radiation detectors and in computed tomography (CT scan) devices. Other insoluble tungstates, such as barium tungstate, are used widely in the production of advanced ceramic materials.

Recent Research & Development for Tungstates

Ultrathin bismuth tungstate nanosheets as an effective photo-assisted support for electrocatalytic methanol oxidation., Hu, Sujuan, Wang Baoling, Ma Yinhai, Li Mengyuan, Zhang Liting, and Huang Zixuan , J Colloid Interface Sci, 2019 Sep 15, Volume 552, p.179-185, (2019)

Structural Insights on 2D Gadolinium Tungstate Nanoflake: A Promising Electrocatalyst for Sensor and Photocatalyst for the Degradation of Postharvest Fungicide (Carbendazim)., Periyasamy, Sundaresan, Kumar Jeyaraj Vinoth, Chen Shen-Ming, Annamalai Yamuna, Karthik Raj, and Rajagounder Nagarajan Erumaipatt , ACS Appl Mater Interfaces, 2019 Oct 09, Volume 11, Issue 40, p.37172-37183, (2019)

Facile in situ generation of bismuth tungstate nanosheet-multiwalled carbon nanotube composite as unconventional affinity material for quartz crystal microbalance detection of antibiotics., Munawar, Anam, Schirhagl Romana, Rehman Abdul, Shaheen Ayesha, Taj Ayesha, Bano Khizra, Bassous Nicole J., Webster Thomas J., Khan Waheed S., and Bajwa Sadia Z. , J Hazard Mater, 2019 Mar 18, Volume 373, p.50-59, (2019)

Sonochemical versus hydrothermal synthesis of bismuth tungstate nanostructures: Photocatalytic, sonocatalytic and sonophotocatalytic activities., Zargazi, Mahboobeh, and Entezari Mohammad H. , Ultrason Sonochem, 2019 Mar, Volume 51, p.1-11, (2019)

Non-Noble Cobalt Tungstate Catalyst for Effective Electrocatalytic Oxidation of Borohydride., Tiwari, Aarti, Singh Vikram, and Nagaiah Tharamani C. , ACS Appl Mater Interfaces, 2019 Jun 19, Volume 11, Issue 24, p.21465-21472, (2019)

Simple sonochemical synthesis of lanthanum tungstate (La(WO)) nanoparticles as an enhanced electrocatalyst for the selective electrochemical determination of anti-scald-inhibitor diphenylamine., Sundaresan, Periyasamy, Gnanaprakasam Periyasami, Chen Shen-Ming, Mangalaraja Ramalinga Viswanatha, Lei Wu, and Hao Qingli , Ultrason Sonochem, 2019 Jun 18, Volume 58, p.104647, (2019)

Synthesis, functionalization and properties of uniform europium-doped sodium lanthanum tungstate and molybdate (NaLa(XO), X = Mo,W) probes for luminescent and X-ray computed tomography bioimaging., Laguna, Mariano, Nuñez Nuria O., Becerro Ana I., Lozano Gabriel, Moros Maria, de la Fuente Jesús M., Corral Ariadna, Balcerzyk Marcin, and Ocaña Manuel , J Colloid Interface Sci, 2019 Jul 13, Volume 554, p.520-530, (2019)

Boosting charge transfer via molybdenum doping and electric-field effect in bismuth tungstate: Density function theory calculation and potential applications., Bian, Yuan, Zeng Weixuan, He Meng, Ma Yongjin, Liu Yi, Kong Yi, and Pan Jun , J Colloid Interface Sci, 2019 Jan 15, Volume 534, p.20-30, (2019)

Synthesis, characterization and catalytic epoxidation properties of a new tellurotungstate(iv)-supported rhenium carbonyl derivative., Lu, Jingkun, Ma Xinyi, Wang Ping, Feng Junwei, Ma Pengtao, Niu Jingyang, and Wang Jingping , Dalton Trans, 2019 Jan 02, Volume 48, Issue 2, p.628-634, (2019)

Tumor microenvironment-manipulated radiocatalytic sensitizer based on bismuth heteropolytungstate for radiotherapy enhancement., Zhou, Ruyi, Wang Huamei, Yang Yufei, Zhang Chenyang, Dong Xinghua, Du Jiangfeng, Yan Liang, Zhang Guangjin, Gu Zhanjun, and Zhao Yuliang , Biomaterials, 2019 Jan, Volume 189, p.11-22, (2019)

Rare-Earth and Antimony-Oxo Clusters Simultaneously Connecting Antimonotungstates Comprising Divacant and Tetravacant Keggin Fragments., Xu, Xin, Chen Yanhong, Zhang Yan, Liu Yifan, Chen Lijuan, and Zhao Junwei , Inorg Chem, 2019 Aug 15, (2019)

Antiviral effects of a niobium-substituted heteropolytungstate on hepatitis B virus-transgenic mice., Li, Qingmei, Zhang Hong, Qi Yanfei, Wang Juan, Li Juan, and Niu Junqi , Drug Dev Res, 2019 Aug 09, (2019)

Solution growth of 1D zinc tungstate (ZnWO) nanowires; design, morphology, and electrochemical sensor fabrication for selective detection of chloramphenicol., Shad, Naveed A., Bajwa Sadia Z., Amin Nasir, Taj Ayesha, Hameed Sadaf, Khan Yaqoob, Dai Zhifei, Cao Chuanbao, and Khan Waheed S. , J Hazard Mater, 2019 Apr 05, Volume 367, p.205-214, (2019)

Tungstate removal from aqueous solution by nanocrystalline iowaite: An iron-bearing layered double hydroxide., Cao, Yaowu, Guo Qinghai, Shu Zhu, Jiao Cong, Luo Li, Guo Wei, Zhao Qian, and Yin Zuowei , Environ Pollut, 2019 Apr, Volume 247, p.118-127, (2019)

High doses of sodium tungstate can promote mitochondrial dysfunction and oxidative stress in isolated mitochondria., Cheraghi, Ghazale, Hajiabedi Elnaz, Niaghi Behnaz, Nazari Firouzeh, Naserzadeh Parvaneh, and Hosseini Mir-Jamal , J Biochem Mol Toxicol, 2019 Apr, Volume 33, Issue 4, p.e22266, (2019)