About Sulfides

Sulfide Ion

Sulfides are compounds derived from the sulfide anion, S2-. As sulfur is a member of group 16 on the periodic table, it is considered a chalcogen, and sulfide compounds belong to a class of compounds known as chalcogenides.

The bonding in transition metal sulfides is highly covalent, a property that is intimately related to their ability to function as semiconductors and pigments . These are the sulfides most often used directly as functional materials; they are found as pigments, catalysts, optical materials, phase change materials, solid electrolytes, or semiconductors. One particularly familiar sulfide is the bright yellow species CdS or "cadmium yellow". This is the color used for school buses in the United States, though the color is now replicated with alternate pigments due to the toxicity of cadmium.

Another familiar transition-metal sulfide is the black tarnish formed on sterling silver: silver sulfide. Cadmium sulfide is an essential component of cadmium telluride (CdTe) solar cells. Calcium polysulfide ("lime sulfur") is a traditional fungicide in gardening. Lead sulfide is used in infra-red sensors. Molybdenum disulfide, found naturally as the mineral molybdenite, is used as a petrochemical catalyst to remove sulfur from fossil fuels and as a solid lubricant for high temperature and high pressure applications. Zinc sulfide is used for lenses and other optical devices in the infrared part of the spectrum. Zinc sulfide with a trace of copper is used for photoluminescent strips for emergency lighting and luminous watch dials. Research into properties of semiconducting sulfides in the form of nanostructured materials such as quantum dots has grown in recent years, and such materials are now coming into use in optoelectronic applications.

Alkali metal and alkaline earth chalcogenides, including the sulfides, have bonds with more ionic character than those found in transition metal sulfides. They are typically colorless, water-soluble compounds, and are used more as chemical reagents than as functional materials. For instance, sodium sulfide is an important industrial chemical, used in paper manufacturing, dyes, leather tanning, crude petroleum processing, treatment of heavy metal pollution, and others.

Recent Research & Development for Sulfides

Fast response near-infrared fluorescent probe for hydrogen sulfide in natural waters., Jin, Yonglei, Liu Rui, Zhan Zixuan, and Lv Yi , Talanta, 2019 Sep 01, Volume 202, p.159-164, (2019)

Fabrication of Cobalt Sulfide/Graphene Sheets Nanocomposite Harvesting Improved Anode Performance for Lithium-Ion Battery., Zhu, Jia, Jin Menghan, and Tang Sheng , J Nanosci Nanotechnol, 2019 Sep 01, Volume 19, Issue 9, p.5921-5927, (2019)

Sustained Release of Hydrogen Sulfide (HS) from Poly(Lactic Acid) Functionalized 4-Hydroxythiobenzamide Microparticles to Protect Against Oxidative Damage., Do, Anh-Vu, Smith Rasheid, Tobias Phillip, Carlsen Daniel, Pham Erica, Bowden Ned B., and Salem Aliasger K. , Ann Biomed Eng, 2019 May 28, (2019)

Using the high-temperature phase transition of iron sulfide minerals as an indicator of fault slip temperature., Chen, Yan-Hong, Chen Yen-Hua, Hsu Wen-Dung, Chang Yin-Chia, Sheu Hwo-Shuenn, Lee Jey-Jau, and Lin Shih-Kang , Sci Rep, 2019 May 28, Volume 9, Issue 1, p.7950, (2019)

Highly selective circular dichroism sensor based on d-penicillamine/cysteamine‑cadmium sulfide quantum dots for copper (II) ion detection., Ngamdee, Kessarin, Chaiendoo Kanokwan, Saiyasombat Chatree, Busayaporn Wutthikrai, Ittisanronnachai Somlak, Promarak Vinich, and Ngeontae Wittaya , Spectrochim Acta A Mol Biomol Spectrosc, 2019 Mar 15, Volume 211, p.313-321, (2019)

Current and future envision on developing biosensors aided by 2D molybdenum disulfide (MoS) productions., N R, Dalila, Arshad M K. Md, Gopinath Subash C. B., Norhaimi W M. W., and Fathil M F. M. , Biosens Bioelectron, 2019 Mar 06, Volume 132, p.248-264, (2019)

Influence of doping ion, capping agent and pH on the fluorescence properties of zinc sulfide quantum dots: Sensing of Cu and Hg ions and their biocompatibility with cancer and fungal cells., Desai, Mittal L., Deshmukh Balaji, Lenka Nibedita, Haran Varun, Jha Sanjay, Basu Hirakendu, Singhal Rakesh Kumar, Sharma P K., Kailasa Suresh Kumar, and Kim Ki-Hyun , Spectrochim Acta A Mol Biomol Spectrosc, 2019 Mar 05, Volume 210, p.212-221, (2019)

Performance of Cu(In, Ga)Se2 Solar Cells on Zinc Sulfide Buffer Layers for Various Power Values of an Intense Pulsed Light System., Cao, Vu Minh Han, Hwang Soohyun, Lin Jian, and Lee Jaehyeong , J Nanosci Nanotechnol, 2019 Mar 01, Volume 19, Issue 3, p.1635-1639, (2019)

Effect of Hydrogen Sulfide on Kidney Injury in Rat Model of Crush Syndrome., Tekşen, Yasemin, Kadıoğlu Emine, Koçak Cengiz, and Koçak Havva , J Surg Res, 2019 Mar, Volume 235, p.470-478, (2019)

Quaternized chitosan-stabilized copper sulfide nanoparticles for cancer therapy., Huang, Xiujie, Xu Changliang, Li Yichen, Cheng Haibo, Wang Xiaoying, and Sun Runcang , Mater Sci Eng C Mater Biol Appl, 2019 Mar, Volume 96, p.129-137, (2019)

Facile one-pot sonochemical synthesis of Ni doped bismuth sulphide for the electrochemical determination of promethazine hydrochloride., Sakthivel, Rajalakshmi, Kubendhiran Subbiramaniyan, and Chen Shen-Ming , Ultrason Sonochem, 2019 Jun, Volume 54, p.68-78, (2019)

Enhanced light absorption and charge recombination control in quantum dot sensitized solar cells using tin doped cadmium sulfide quantum dots., Muthalif, Mohammed Panthakkal, Sunesh Chozhidakath Damodharan, and Choe Youngson , J Colloid Interface Sci, 2019 Jan 15, Volume 534, p.291-300, (2019)

Manganese oxide at cadmium sulfide (MnOx@CdS) shells encapsulated with graphene: A spatially separated photocatalytic system towards superior hydrogen evolution., Tan, Pengfei, Zhu Anquan, Qiao Lulu, Zeng Weixuan, Cui Hao, and Pan Jun , J Colloid Interface Sci, 2019 Jan 01, Volume 533, p.452-462, (2019)

Enhancement in mechanical quality factors of poly phenylene sulfide under high-amplitude ultrasonic vibration through thermal annealing., Wu, Jiang, Mizuno Yosuke, and Nakamura Kentaro , Ultrasonics, 2019 Jan, Volume 91, p.52-61, (2019)

Site-Selective and van der Waals Epitaxial Growth of Rhenium Disulfide on Graphene., Seo, Jihyung, Lee Junghyun, Jeong Gyujeong, and Park Hyesung , Small, 2019 Jan, Volume 15, Issue 2, p.e1804133, (2019)