Molybdenum Sulfide

Molybdenum Disulfide

CAS 1317-33-5
Linear Formula: MoS2
MDL Number: MFCD00003470
EC No.: 215-263-9

Request Quote

PRODUCT PRODUCT CODE REQUEST A QUOTE SAFETY DATA TECHNICAL DATA
(2N) 99% Molybdenum Sulfide
MO-S-02 Pricing
(2N5) 99.5% Molybdenum Sulfide
MO-S-025 Pricing
(3N) 99.9% Molybdenum Sulfide
MO-S-03 Pricing
(3N5) 99.95% Molybdenum Sulfide
MO-S-035 Pricing
(4N) 99.99% Molybdenum Sulfide
MO-S-04 Pricing
(5N) 99.999% Molybdenum Sulfide
MO-S-05 Pricing

Properties

Compound Formula MoS2
Molecular Weight 160.07
Appearance black solid
Melting Point 1,185° C (2,165° F)
Boiling Point N/A
Density 5.06 g/cm3
Monoisotopic Mass 161.849549
Exact Mass 161.849549

Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes N/A
Safety Statements N/A
Transport Information N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 07/29/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Molybdenum Sulfide

Product Number: All applicable American Elements product codes, e.g. MO-S-02, MO-S-025, MO-S-03, MO-S-035, MO-S-04, MO-S-05

CAS #: 1317-33-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36/37/38: Irritating to eyes, respiratory system and skin.
Information concerning particular hazards for human and environment:
Not applicable
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word
Warning
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/
national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1

1
Health (acute effects) = 1
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
1317-33-5 Molybdenum(IV) sulfide
Identification number(s):
EC number:
215-263-9


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Sulfur oxides (SOx)
Metal oxide fume
Hydrogen sulfide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1317-33-5 Molybdenum(IV) sulfide (100.0%)
TLV (USA) Long-term value: 10* 3** mg/m³
as Mo; *inhalable fracti
on ** respirable fraction
EL (Canada) Long-term value: 3* 10** mg/m³
as Mo; *respirable **inhalable
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid in various forms
Color: Black
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 1185 °C (2165 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Sulfur oxides (SOx)
Metal oxide fume
Hydrogen sulfide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Causes skin irritation.
Eye irritation or corrosion:
Causes serious eye damage.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Sulfide IonMolybdenum Sulfide or Molybdenum Disulfide is a moderately water and acid soluble Molybdenum source for uses compatible with sulfates. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells. Molybdenum Sulfide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Molybdenum(IV) sulfide, Molybdenite, Molykote, hydrogen sulfide; molybdenum, Molybdenum disulphide, Molykote, bis(sulfanylidene)molybdenum, Molysulfide, Nichimoly C, Sumipowder PA, Molykote Z, disulfanylidene molybdenum, dithioxomolybdenum

Chemical Identifiers

Linear Formula MoS2
CAS 1317-33-5
Pubchem CID 14823
MDL Number MFCD00003470
EC No. 215-263-9
Beilstein Registry No. N/A
IUPAC Name bis(sulfanylidene)molybdenum
SMILES [Mo].S
InchI Identifier InChI=1S/Mo. H2S/h;1H2
InchI Key QYSJWHFJGCFRDE-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

Recent Research

Recovery of molybdenum, nickel and cobalt by precipitation from the acidic leachate of a mineral sludge., Vemic, M, Bordas F, Comte S, Guibaud G, Lens P N. L., and van Hullebusch E D. , Environ Technol, 2016 Sep, Volume 37, Issue 17, p.2231-42, (2016)

Effect of molybdenum on structure, microstructure and mechanical properties of biomedical Ti-20Zr-Mo alloys., Kuroda, Pedro Akira Baza, Buzalaf Marília Afonso Rab, and Grandini Carlos Roberto , Mater Sci Eng C Mater Biol Appl, 2016 Oct 1, Volume 67, p.511-5, (2016)

Giant magnetic anisotropy in doped single layer molybdenum disulfide and fluorographene., Sivek, J, Sahin H, Partoens B, and Peeters F M. , J Phys Condens Matter, 2016 May 18, Volume 28, Issue 19, p.195301, (2016)

High-Performance Silver Window Electrodes for Top-Illuminated Organic Photovoltaics Using an Organo-molybdenum Oxide Bronze Interlayer., Tyler, Martin S., Walker Marc, and Hatton Ross A. , ACS Appl Mater Interfaces, 2016 May 18, Volume 8, Issue 19, p.12316-23, (2016)

Tetrathiomolybdate Complexes of Rhodium(I) with Molybdenum-Rhodium Interactions., Xamonaki, Nikoletta, Asimakopoulos Anastasios, Balafas Anastasios, Dasenaki Marilena, Choinopoulos Ioannis, Coco Silverio, Simandiras Emmanuel, and Koinis Spyros , Inorg Chem, 2016 May 16, Volume 55, Issue 10, p.4771-81, (2016)

Moisture effects on the electrochemical reaction and resistance switching at Ag/molybdenum oxide interfaces., Yang, Chuan-Sen, Shang Da-Shan, Chai Yi-Sheng, Yan Li-Qin, Shen Bao-Gen, and Sun Young , Phys Chem Chem Phys, 2016 May 14, Volume 18, Issue 18, p.12466-75, (2016)

Molybdate uptake by Agrobacterium tumefaciens correlates with the cellular molybdenum cofactor status., Hoffmann, Marie-Christine, Ali Koral, Sonnenschein Marleen, Robrahn Laura, Strauss Daria, Narberhaus Franz, and Masepohl Bernd , Mol Microbiol, 2016 May 14, (2016)

Mechanism for doping induced p type C60 using thermally evaporated molybdenum trioxide (MoO3) as a dopant., Yang, Jin-Peng, Wang Wen-Qing, Cheng Li-Wen, Li Yan-Qing, Tang Jian-Xin, Kera Satoshi, Ueno Nobuo, and Zeng Xiang-Hua , J Phys Condens Matter, 2016 May 11, Volume 28, Issue 18, p.185502, (2016)

Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite., Souilem, Amira, and Zid Mohamed Faouzi , Acta Crystallogr E Crystallogr Commun, 2016 May 1, Volume 72, Issue Pt 5, p.737-40, (2016)

Solar Hydrogen Production from Zinc Telluride Photocathode Modified with Carbon and Molybdenum Sulfide., Jang, Youn Jeong, Lee Jaehyuk, Lee Jinwoo, and Lee Jae Sung , ACS Appl Mater Interfaces, 2016 Mar 30, Volume 8, Issue 12, p.7748-55, (2016)

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