About Hydrides

Hydride Ion Diagram

The hydride ion is the anion of hydrogen, H-. Hydrides are compounds in which one or more hydrogens have nucleophilic/reducing properties, and many are ionic compounds containing the hydride ion. Almost all the elements form binary compounds with hydrogen; these are the simplest hydrides.

Hydrides are divided into three basic types: saline, metallic, and covalent. Saline hydrides, such as sodium hydride and calcium hydride, are often used as portable sources of hydrogen gas. Metallic hydrides, such as titanium hydride, are alloy-like materials that share some properties with metals including luster and electrical conductivity. Covalent hydrides are mostly compounds of hydrogen and nonmetallic elements; they include water, ammonia, hydrogen sulfide, and methane. A fourth group of hydrides, dimeric or polymeric hydrides, give off large amounts of energy when burned and have been investigated for use in rocket fuels.

Hydrides like sodium and potassium hydride are commonly used as reducing agents in chemical synthesis, dessicants or drying agents in laboratory or industrial settings, catalysts, and as chemical means of hydrogen storage, as in nickel-metal hydride battery and hydrogen fuel cell technologies.

Recent Research & Development for Hydrides

Improvement in the Hydrogen-Storage Characteristics of Magnesium Hydride by Grinding with Sodium Alanate and Transition Metals in a Hydrogen Atmosphere., Song, Myoung Youp, Kwak Young Jun, and Lee Seong Ho , J Nanosci Nanotechnol, 2018 Sep 01, Volume 18, Issue 9, p.6047-6054, (2018)

Preparation and characterisation of heterobimetallic copper-tungsten hydride complexes., Hicken, Alexandra, White Andrew J. P., and Crimmin Mark R. , Dalton Trans, 2018 May 22, (2018)

A disguised hydride in a butylmagnesium cation., Banerjee, Sumanta, Andrews Alex, and Venugopal Ajay , Chem Commun (Camb), 2018 May 21, (2018)

Chiral Magnesium Bisphosphate-Catalyzed Asymmetric Double C(sp)-H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process., Mori, Keiji, Isogai Ryo, Kamei Yuto, Yamanaka Masahiro, and Akiyama Takahiko , J Am Chem Soc, 2018 May 11, (2018)

An automated continuous homogeneous microextraction for the determination of selenium and arsenic by hydride generation atomic fluorescence spectrometry., Shishov, Andrey, Wieczorek Marcin, Kościelniak Paweł, Dudek-Adamska Danuta, Telk Anna, Moskvin Leonid, and Bulatov Andrey , Talanta, 2018 May 01, Volume 181, p.359-365, (2018)

Hydrogenation properties of lithium and sodium hydride - closo-borate, [BH] and [BH], composites., Jensen, Steffen R. H., Paskevicius Mark, Hansen Bjarne R. S., Jakobsen Anders S., Møller Kasper T., White James L., Allendorf Mark D., Stavila Vitalie, Skibsted Jørgen, and Jensen Torben R. , Phys Chem Chem Phys, 2018 Jun 13, Volume 20, Issue 23, p.16266-16275, (2018)

Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals., Lu, Zhiyao, Cherepakhin Valeriy, Demianets Ivan, Lauridsen Paul J., and Williams Travis J. , Chem Commun (Camb), 2018 Jun 11, (2018)

Normal and abnormal NHC coordination in cationic hydride iodide complexes of aluminium., Trose, Michael, Burnett Stuart, Bonyhady Simon J., Jones Cameron, Cordes David B., Slawin Alexandra M. Z., and Stasch Andreas , Dalton Trans, 2018 Jul 31, Volume 47, Issue 30, p.10281-10287, (2018)

Substrate-controlled divergent synthesis of polycyclic indoloazepines and indolodiazepines via 1,5-hydride shift/7-cyclization cascades., Liu, Siyuan, Qu Jingping, and Wang Baomin , Chem Commun (Camb), 2018 Jul 12, Volume 54, Issue 57, p.7928-7931, (2018)

Gold(I)-Catalyzed Tandem Cycloisomerization of 1,5-Enyne Ethers via Hydride Transfer., Wong, Henry N. C., Lu Xiao-Lin, Lyu Mao-Yun, and Peng Xiao-Shui , Angew Chem Int Ed Engl, 2018 Jul 10, (2018)

Synthesis of cerium and nickel doped titanium nanofibers for hydrolysis of sodium borohydride., Tamboli, Ashif H., Gosavi S W., Terashima Chiaki, Fujishima Akira, Pawar Atul A., and Kim Hern , Chemosphere, 2018 Jul, Volume 202, p.669-676, (2018)

Synthesis and Stability of Lanthanum Superhydrides., Geballe, Zachary M., Liu Hanyu, Mishra Ajay K., Ahart Muhtar, Somayazulu Maddury, Meng Yue, Baldini Maria, and Hemley Russell J. , Angew Chem Int Ed Engl, 2018 Jan 15, Volume 57, Issue 3, p.688-692, (2018)

Titanium(III)-Oxo Clusters in a Metal-Organic Framework Support Single-Site Co(II)-Hydride Catalysts for Arene Hydrogenation., Ji, Pengfei, Song Yang, Drake Tasha, Veroneau Samuel S., Lin Zekai, Pan Xiandao, and Lin Wenbin , J Am Chem Soc, 2018 Jan 10, Volume 140, Issue 1, p.433-440, (2018)