American Elements
   



Products
Amorphous Silicon Powder
Ammonium Silicofluoride
Calcium-Silicon Alloy
Chromium-Silicon Alloy
Ferrosilicon
Polycrystalline Silicon Powder
Silicon
Silicon Arsenide
Silicon Bars
Silicon Carbide
Silicon Coins
Silicon Phosphide
Silicon Telluride
Single Crystal Silicon Ingot
Silicon Dioxide, Alumina Doped
3-Aminopropyl Functionalized Silica Nanoparticles, Dispersion
Silicon
Silicon information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Silicon is one of man's most useful elements. It makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, being exceeded only by oxygen. The Czochralski process is commonly used to produce single crystals of silicon used for solid-state or semiconductor devices. Silica, as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Silicon is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Ultra high purity silicon can be doped with boron, gallium, phosphorus , or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics and space-age industries. Hydrogenated amorphous silicon has shown promise in producing economical cells for converting solar energy into electricity. Silcones are important products of silicon. They range from liquids to hard, glasslike solids with many useful properties. Thin film deposition of Silicon Nanoparticle quantum dots on the polycrystalline silicon substrate of a photovoltaic (solar) cell increases voltage output as much as 60% by fluorescing the incoming light prior to capture.

Silicon facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Silicon is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Silicon is a Block D, Group 14, Period 3 element. The electronic configuration is [Ne] 3s2 3p2. In its elemental form silicon's CAS number is 7440-21-3. The silicon atom has a radius of 117.6.pm and it's Van der Waals radius is 210.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Silicon compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Silicon was first discovered by Jons Berzelius in 1823.

French Silicium German Silicium Italian Silicio Portuguese Silício Spanish Silicio Swedish Kisel

Abundance. The following table shows the abundance of silicon and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Si-28
27.976926533
92.23
Si-29
28.97649472
4.67
Si-30
29.97377022
3.10

Safety Data. The safety data for silicon metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for silicon (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
786.52 kJ mol-1
2nd Ionization Energy
1577.15 kJ mol-1
3rd Ionization Energy
3231.61 kJ mol-1

Conductivity. As to silicon's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 10 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.9. The thermal conductivity of silicon is 148 W m-1 K-1.

Thermal Properties. The melting point and boiling point for silicon are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
39.6 kJ mol-1
Heat of Vaporization
383.3 kJ mol-1
Heat of Atomization
451.29 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Si 14 28.0855 g.mol -1 1.8 2.33 g.cm-3 at 20 °C 1410 °C 3265 °C 0.132 nm 0.271 nm (-4) ; 0.041 (+4) 786.3 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
© 2001-2009. American Elements is a U.S. Registered Trademark. All rights reserved.
This website, the Periodic Table of the Elements information, Element and Materials
Science presentations and all pages, designs, concepts, logos, and color schemes herein
are the copyrighted proprietary rights and intellectual property of American Elements.

 

Recent Research & Development for Silicon

  • Size Effects in Mechanical Deformation and Fracture of Cantilevered Silicon Nanowires. Gordon MJ, Baron T, Dhalluin F, Gentile P, Ferret P. Nano Lett. 2009 Jan 21. [Epub ahead of print] PMID: 19159318 [PubMed - as supplied by publisher]

  • Metal-Catalyst-Free Growth of Single-Walled Carbon Nanotubes on Substrates. Huang S, Cai Q, Chen J, Qian Y, Zhang L. J Am Chem Soc. 2009 Jan 21. [Epub ahead of print] PMID: 19159295 [PubMed - as supplied by publisher]

  • Catalyst-free Growth of Single-Crystal Silicon and Germanium Nanowires. Kim BS, Koo TW, Lee JH, Kim DS, Jung YC, Hwang SW, Choi BL, Lee EK, Kim JM, Whang D. Nano Lett. 2009 Jan 21. [Epub ahead of print] PMID: 19159250 [PubMed - as supplied by publisher]

  • Silicon (100) Electrodes Resistant to Oxidation in Aqueous Solutions: An Unexpected Benefit of Surface Acetylene Moieties. Ciampi S, Eggers PK, Le Saux G, James M, Harper JB, Gooding JJ. Langmuir. 2009 Jan 21. [Epub ahead of print] PMID: 19159188 [PubMed - as supplied by publisher]

  • Biosensors based on cantilevers. Alvarez M, Carrascosa LG, Zinoviev K, Plaza JA, Lechuga LM. Methods Mol Biol. 2009;504:51-71. PMID: 19159090 [PubMed - in process]

  • Fast light in silicon ring resonator with resonance-splitting. Li Q, Zhang Z, Wang J, Qiu M, Su Y. Opt Express. 2009 Jan 19;17(2):933-40. PMID: 19158908 [PubMed - in process] Related Articles 7: Modification of the Er3+ radiative lifetime from proximity to silicon nanoclusters in silicon-rich silicon oxide. Horak P, Loh WH, Kenyon AJ. Opt Express. 2009 Jan 19;17(2):906-11. PMID: 19158905 [PubMed - in process]

  • Ambient-stable blue luminescent silicon nanocrystals prepared by nanosecond-pulsed laser ablation in water. Svrcek V, Mariotti D, Kondo M. Opt Express. 2009 Jan 19;17(2):520-7. PMID: 19158863 [PubMed - in process]

  • para-Functionalized Aryl-di-tert-butylfluorosilanes as Potential Labeling Synthons for (18)F Radiopharmaceuticals. Iovkova L, Wängler B, Schirrmacher E, Schirrmacher R, Quandt G, Boening G, Schürmann M, Jurkschat K. Chemistry. 2009 Jan 20. [Epub ahead of print] PMID: 19156812 [PubMed - as supplied by publisher]

  • Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones. Schneider N, Finger M, Haferkemper C, Bellemin-Laponnaz S, Hofmann P, Gade LH. Angew Chem Int Ed Engl. 2009 Jan 20. [Epub ahead of print] No abstract available. PMID: 19156797 [PubMed - as supplied by publisher]

  • Characterization of porous silicon integrated in liquid chromatography chips. Tiggelaar RM, Verdoold V, Eghbali H, Desmet G, Gardeniers JG. Lab Chip. 2009 Mar;9(3):456-63. Epub 2008 Nov 13. PMID: 19156296 [PubMed - in process]

  • Nanostructured biosensing platform-shadow edge lithography for high-throughput nanofabrication. Bai JG, Yeo WH, Chung JH. Lab Chip. 2009 Mar;9(3):449-55. Epub 2008 Nov 11. PMID: 19156295 [PubMed - in process]

  • A conformal nano-adhesive via initiated chemical vapor deposition for microfluidic devices. Im SG, Bong KW, Lee CH, Doyle PS, Gleason KK. Lab Chip. 2009 Mar;9(3):411-6. Epub 2008 Nov 7. PMID: 19156290 [PubMed - in process]

  • Measurements of Subcutaneous Tissue PO(2) Reflect Oxygen Metabolism of the Small Intestinal Mucosa during Hemorrhage and Resuscitation. An Experimental Study in Pigs. Mellström A, Månsson P, Jönsson K, Hartmann M. Eur Surg Res. 2009 Jan 21;42(2):122-129. [Epub ahead of print] PMID: 19155629 [PubMed - as supplied by publisher]

  • Structures of silicon cluster cations in the gas phase. Lyon JT, Gruene P, Fielicke A, Meijer G, Janssens E, Claes P, Lievens P. J Am Chem Soc. 2009 Jan 28;131(3):1115-21. PMID: 19154175 [PubMed - in process]

  • Role of Surfactant in the Stability of Liquid Crystal-Based Nanocolloids. Spillmann CM, Naciri J, Wahl KJ, Garner YH, Chen MS, Ratna BR. Langmuir. 2009 Jan 20. [Epub ahead of print] PMID: 19154135 [PubMed - as supplied by publisher]

  • Potassium tert-Butoxide-Catalyzed Dehydrogenative Si--O Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection. Weickgenannt A, Oestreich M. Chem Asian J. 2009 Jan 19. [Epub ahead of print] PMID: 19153976 [PubMed - as supplied by publisher]

  • Miniaturized and integrated fluorescence detectors for microfluidic capillary electrophoresis devices. Kamei T. Methods Mol Biol. 2009;503:361-74. PMID: 19151952 [PubMed - in process]

  • Multilayer structure for a spectral imaging sensor. Parrein P, Moussy N, Poupinet L, Gidon P. Appl Opt. 2009 Jan 20;48(3):653-7. PMID: 19151837 [PubMed - in process]

  • Removal of Densiron-68 with a 23-gauge transconjunctival vitrectomy system. Romano MR, Groenwald C, Das R, Stappler T, Wong D, Heimann H. Eye. 2009 Jan 16. [Epub ahead of print] PMID: 19151654 [PubMed - as supplied by publisher] Related Articles

 

 

 

 

American Elements Products can also be sourced at these sites:
 
 
 
electronics-ee.com