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About Oxygen

Oxygen Bohr

One might think that the ubiquity and vital importance of oxygen would facilitate its early and easy discovery, but this was not the case. True, for many centuries of human history, the necessity of some aspect of air to the processes of combustion and respiration was intuited and articulated by scholars, yet until the late eighteenth century, a full theoretical understanding of the underlying chemistry of these processes remained elusive.

A significant barrier to this understanding was phlogiston theory, an early chemical theory that claimed all combustible materials contained phlogiston, and during burning this substance was released. The observation that air contained components that both supported and failed to support combustion had been made, but phlogiston theory dictated that this was due to a limited capacity of air to absorb phlogiston. Both Carl Wilhelm Scheele and Joseph Priestley isolated a component of air that supported both combustion and respiration for longer than ordinary air, with the former referring to it as “fire air” and the latter “dephlogisticated air”, both assuming that what they had found was the substance that combined with phlogiston during combustion. This gas, of course, was oxygen, and Priestley is typically given credit for its discovery; though Scheele isolated his “fire air” first, in 1771, Priestley was first to publish his method of synthesis, which he did in 1774. It took a third chemist, Antoine Lavoisier, to recognize that the newly discovered gas was in fact a new element; he published the first correct explanation of combustion in 1777. Though correct in his dismissal of phlogiston, Lavoisier developed his own mistaken theory stating that all acids contained this new element, and therefore named the element from the Greek roots oxys, acid, and genes, producer. By the time this belief was proven incorrect, the name oxygen had stuck.

It is understandable that early chemists were baffled by oxygen, as they had little experience with elements that came in such an astounding array of forms. A strong oxidizing agent greedy for electrons, oxygen will react with nearly any element given sufficiently high temperatures. Oxygen is found in water and most organic compounds, and its ability to form both single and double bonds, its presence in many polyatomic ions, and its tendency to form complexes with transition metals such as iron all serve to further expand the list of oxygen-containing substances. Major ores of iron, zinc, and aluminum are all oxides, as is the quicklime used in mortar and concrete, the carbon dioxide produced by aerobic respiration, and common silica sand.

In its compound forms, the uses of oxygen are nearly limitless, but even in the form of the pure element, it has many applications. The most stable and common allotrope of oxygen is the O2 we breathe. Pure oxygen gas is traditionally extracted from liquefied air through the fractional distillation; it is left behind in liquid form after nitrogen has evaporated. Additionally, various molecular sieves including activated carbon, zeolites, and silica gel can be used to separate clean dry air, exploiting the differing affinities of nitrogen and oxygen for the filter material at varying pressures. This second method is often used for portable oxygen concentrators used by patients with respiratory ailments. Concentrated oxygen is additionally used for life support in aerospace and diving contexts. Pure oxygen finds use as rocket fuel, as a reagent in the chemical industry, and in metallurgy. In steel smelting, injecting pure oxygen removes sulfur impurities and excess carbon as oxides, while in oxy-fuel welding and metal welding, pure oxygen is used to produce an exceptionally hot flame.

Though common oxygen gas (O2) is known as an oxidizing agent, another form of oxygen is much more potent in this regard. Ozone, a molecule composed of three oxygen atoms, is also an extremely potent oxidizing agent. Ozone is produced in small amounts from molecular oxygen through a variety of processes, most commonly from the action of ultraviolet radiation on fossil fuel byproducts in the air, and from the electrolysis of air--ozone is responsible for the distinctive smell associated with lightning strikes. Ozone’s reactivity makes it toxic, but it decays to harmless oxygen, making it particularly useful for disinfection in contexts where any toxic residue would be unacceptable. It is regularly used to kill insects in grain, spores in food processing plants, and bacteria on food and surfaces. Increasingly, it is used as a replacement for chlorine bleach in producing fabrics and processing wood pulp to paper, usually in conjunction with another strong oxidizing agent, hydrogen peroxide. It also reacts with many water contaminants including metals, sulfides, nitrites, and complex organics, and can be used in water treatment plants to both kill biological agents and neutralize chemical toxins. Ozone’s instability requires that it be produced on site, rather than mass produced and transported. This is typically accomplished using high-voltage electrolysis of air, or through the use of ultraviolet ozone generators.

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Oxygen Properties

Oxygen Element SymbolOxygen is a Block P, Group 16, Period 2 element. Its electron configuration is [He]2s22p4 . The oxygen atom has a covalent radius of 66±2 pm and its Van der Waals radius is 152 pm. In its elemental form, CAS 7782-44-7, oxygen is colorless gas or a pale blue liquid. The name oxygen is derived from the Greek word oxys, meaning acid because, at the time of its naming, it was thought that acids required oxygen in their composition.

Oxygen information, including technical data, safety data and its high purity properties, research, applications and other useful facts are specified below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Symbol: O
Atomic Number: 8
Atomic Weight: 16
Element Category: nonmetal, chalcogen
Group, Period, Block: 16 (chalcogens), 2, p
Color: colourless as a gas, liquid is pale blue
Other Names: Ossigeno, Oxigênio, Syre
Melting Point: -218.79°C, -361.822°F, 54.36 K
Boiling Point: -182.962°C, -297.332°F
Density: (0 °C, 101.325 kPa) 1.429 g/L
Liquid Density @ Melting Point: 1.141 g·cm3
Density @ 20°C: 0.001429 g/cm3
Density of Solid: 1495 kg·m3
Specific Heat: N/A
Superconductivity Temperature: N/A
Triple Point: 54.361 K, 0.1463 kPa
Critical Point: 154.581 K, 5.043 MPa
Heat of Fusion (kJ·mol-1): 0.444
Heat of Vaporization (kJ·mol-1): 6.82
Heat of Atomization (kJ·mol-1): 246.785
Thermal Conductivity: 26.58x10-3  W·m-1·K-1
Thermal Expansion: N/A
Electrical Resistivity: N/A
Tensile Strength: N/A
Molar Heat Capacity: 29.378 J·mol-1·K-1
Young's Modulus: N/A
Shear Modulus: N/A
Bulk Modulus: N/A
Poisson Ratio: N/A
Mohs Hardness: N/A
Vickers Hardness: N/A
Brinell Hardness: N/A
Speed of Sound: (gas, 27 °C) 330 m·s-1
Pauling Electronegativity: 3.44
Sanderson Electronegativity: 3.65
Allred Rochow Electronegativity: 3.5
Mulliken-Jaffe Electronegativity: 3.41 (16.7% s orbital)
Allen Electronegativity: 3.61
Pauling Electropositivity: 0.56
Reflectivity (%): N/A
Refractive Index: 1.000271 (gas; liquid 1.221)
Electrons: 8
Protons: 8
Neutrons: 8
Electron Configuration: [He]2s22p4
Atomic Radius: N/A
Atomic Radius,
non-bonded (Å):
1.52
Covalent Radius: 66±2 pm
Covalent Radius (Å): 0.64
Van der Waals Radius: 152 pm
Oxidation States: 2, 1, 1, 2
Phase: Gas
Crystal Structure: cubic
Magnetic Ordering: paramagnetic
Electron Affinity (kJ·mol-1) 140.926
1st Ionization Energy: 1313.9 kJ·mol-1
2nd Ionization Energy: 3388.3 kJ·mol-1
3rd Ionization Energy: 5300.5 kJ·mol-1
CAS Number: 7782-44-7
EC Number: 231-956-9
MDL Number: MFCD00011434
Beilstein Number: N/A
SMILES Identifier: O
InChI Identifier: InChI=1S/O
InChI Key: QVGXLLKOCUKJST-UHFFFAOYSA-N
PubChem CID: 977
ChemSpider ID: 140526
Earth - Total: 30.12%
Mercury - Total: 14.44%
Venus - Total: 30.90%
Earth - Seawater (Oceans), ppb by weight: 8.57E+08
Earth - Seawater (Oceans), ppb by atoms: 3.31E+08
Earth -  Crust (Crustal Rocks), ppb by weight: 4.6E+08
Earth -  Crust (Crustal Rocks), ppb by atoms: 6E+08
Sun - Total, ppb by weight: 9000000
Sun - Total, ppb by atoms: 700000
Stream, ppb by weight: 8.8E+08
Stream, ppb by atoms: 55000000
Meterorite (Carbonaceous), ppb by weight: 4.1E+08
Meterorite (Carbonaceous), ppb by atoms: 4.8E+08
Typical Human Body, ppb by weight: N/A
Typical Human Body, ppb by atom: N/A
Universe, ppb by weight: N/A
Universe, ppb by atom: N/A
Discovered By: Carl Wilhelm Scheele
Discovery Date: 1772
First Isolation: N/A

Health, Safety & Transportation Information for Oxygen

Pure oxygen is highly reactive, and can react violently with common materials such as oil or grease. Almost all materials will burn vigorously in pure oxygen, including textiles, rubber, and metals, once a fire has been started. Some materials may catch fire spontaneously in an oxygen enriched environment. Care should be taken in oxygen-enriched environments to avoid producing sparks, and materials that may ignite spontaneously must be avoided. Materials for tanks, hoses, gaskets, and pressure regulators used with compressed oxygen must be certified as safe for this use.

Safety Data
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H270-H280
Hazard Codes 0
Risk Codes 8
Safety Precautions N/A
RTECS Number RS2060000
Transport Information UN 1072 2.2
WGK Germany nwg
Globally Harmonized System of
Classification and Labelling (GHS)
Oxidizing Liquid - Oxidizing Gas Gas Cylinder - Gases Under Pressure

Oxygen Isotopes

Oxygen has three stable isotopes: 16O, 17O and 18O.

Nuclide Isotopic Mass Half-Life Mode of Decay Nuclear Spin Magnetic Moment Binding Energy (MeV) Natural Abundance
(% by atom)
12O 12.034405(20) 580(30)E-24 s [0.40(25) ] 2p to 10C; p to 11N 0+ N/A 56.29 -
13O 13.024812(10) 8.58(5) ms β+ to 13N; β+ + p to 12C (3/2-) N/A 73.69 -
14O 14.00859625(12) 70.598(18) s EC to 14N 0+ N/A 96.67 -
15O 15.0030656(5) 122.24(16) s EC to 15N 1/2- 0.719 109.41 -
16O 15.99491461956(16) STABLE - 0+ 0 125.87 99.757
17O 16.99913170(12) STABLE - 5/2+ -1.8938 129.29 0.038
18O 17.9991610(7) STABLE - 0+ 0 137.37 0.205
19O 19.003580(3) 26.464(9) s β- to 19F 5/2+ N/A 141.72 -
20O 20.0040767(12) 13.51(5) s β- to 20F 0+ N/A 148.87 -
21O 21.008656(13) 3.42(10) s β- to 21F (1/2,3/2,5/2)+ N/A 153.22 -
22O 22.00997(6) 2.25(15) s β- to 22F; β- + n to 21F 0+ N/A 160.37 -
23O 23.01569(13) 82(37) ms β- + n to 22F; β- to 23F 1/2+# N/A 162.86 -
24O 24.02047(25) 65(5) ms β- + n to 23F; β- to 24F 0+ N/A 166.28 -
25O 25.02946(28)# <50 ns Unknown (3/2+)# N/A 165.97 -
26O 26.03834(28)# <40 ns β- to 26F; n to 25O 0+ N/A 165.67 -
27O 27.04826(54)# <260 ns Unknown 3/2+# N/A 164.43 -
28O 28.05781(64)# <100 ns Unknown 0+ N/A 164.12 -
Oxygen Elemental Symbol

Recent Research & Development for Oxygen

  • Ziwu Liu, Qianqian Shi, Rufan Zhang, Quande Wang, Guojun Kang, Feng Peng, Phosphorus-doped carbon nanotubes supported low Pt loading catalyst for the oxygen reduction reaction in acidic fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Gustav Sievers, Steffen Mueller, Antje Quade, Florian Steffen, Sven Jakubith, Angela Kruth, Volker Brueser, Mesoporous Pt–Co oxygen reduction reaction (ORR) catalysts for low temperature proton exchange membrane fuel cell synthesized by alternating sputtering, Journal of Power Sources, Volume 268, 5 December 2014
  • Lin Lin, Meng Li, Liqing Jiang, Yongfeng Li, Dajun Liu, Xingquan He, Lili Cui, A novel iron (?) polyphthalocyanine catalyst assembled on graphene with significantly enhanced performance for oxygen reduction reaction in alkaline medium, Journal of Power Sources, Volume 268, 5 December 2014
  • Ke Liu, Yang Song, Shaowei Chen, Electrocatalytic activities of alkyne-functionalized copper nanoparticles in oxygen reduction in alkaline media, Journal of Power Sources, Volume 268, 5 December 2014
  • Yiyin Huang, Fang Fu, Peng Wu, Yaobing Wang, Jiannian Yao, A bioinspired approach to protectively decorate platinum–carbon for enhanced activity and durability in oxygen reduction, Journal of Power Sources, Volume 268, 5 December 2014
  • Hui Fan, Michael Keane, Prabhakar Singh, Minfang Han, Electrochemical performance and stability of lanthanum strontium cobalt ferrite oxygen electrode with gadolinia doped ceria barrier layer for reversible solid oxide fuel cell, Journal of Power Sources, Volume 268, 5 December 2014
  • Chien-Liang Lee, Chia-Chen Yang, Chia-Ru Liu, Zhe-Ting Liu, Jyun-Sian Ye, Pt-coated Pd nanocubes as catalysts for alkaline oxygen reduction activity, Journal of Power Sources, Volume 268, 5 December 2014
  • Zaenal Awaludin, Takeyoshi Okajima, Takeo Ohsaka, Preparation of reduced tantalum pentoxide by electrochemical technique for oxygen reduction reaction, Journal of Power Sources, Volume 268, 5 December 2014
  • Jie-Ning Zheng, Li-Li He, Chen Chen, Ai-Jun Wang, Ke-Fu Ma, Jiu-Ju Feng, One-pot synthesis of platinum3cobalt nanoflowers with enhanced oxygen reduction and methanol oxidation, Journal of Power Sources, Volume 268, 5 December 2014
  • R.G. González-Huerta, G. Ramos-Sánchez, P.B. Balbuena, Oxygen evolution in Co-doped RuO2 and IrO2: Experimental and theoretical insights to diminish electrolysis overpotential, Journal of Power Sources, Volume 268, 5 December 2014
  • Juan Wang, Tian Qiu, Xu Chen, Yanluo Lu, Wensheng Yang, Hierarchical hollow urchin-like NiCo2O4 nanomaterial as electrocatalyst for oxygen evolution reaction in alkaline medium, Journal of Power Sources, Volume 268, 5 December 2014
  • Yuan Fang, Xiaodong Yang, Li Wang, Yongning Liu, Microspheres assembled by KMn8O16 nanorods and their catalytic oxygen reduction activity in direct methanol fuel cells, Journal of Power Sources, Volume 267, 1 December 2014
  • Bing Chen, Daojian Cheng, Jiqin Zhu, Synthesis of PtCu nanowires in nonaqueous solvent with enhanced activity and stability for oxygen reduction reaction, Journal of Power Sources, Volume 267, 1 December 2014
  • Hye-Lim Kim, Shin Kim, Kyu-Hyung Lee, Hong-Lim Lee, Ki-Tae Lee, Oxygen ion conduction in barium doped LaInO3 perovskite oxides, Journal of Power Sources, Volume 267, 1 December 2014
  • Antonia Sandoval González, Francisco Paraguay Delgado, Pathiyamattom Joseph Sebastian, Edgar Borja Arco, Microwave synthesis of an electrocatalyst based on CoFeRu for the oxygen reduction reaction in the absence and presence of methanol, Journal of Power Sources, Volume 267, 1 December 2014
  • Z.H. Cui, X.X. Guo, Manganese monoxide nanoparticles adhered to mesoporous nitrogen-doped carbons for nonaqueous lithium–oxygen batteries, Journal of Power Sources, Volume 267, 1 December 2014
  • Zengqiang Wang, Fengting Sang, Yuelong Zhang, Xiaokang Hui, Mingxiu Xu, Peng Zhang, Weili Zhao, Benjie Fang, Liping Duo, Yuqi Jin, An experimental research on the mixing process of supersonic oxygen–iodine parallel streams, Optics & Laser Technology, Volume 64, December 2014
  • Jakub Drnec, David A. Harrington, Oxygen and iodine adsorption on cesium-precovered Pt(111), Surface Science, Volume 630, December 2014
  • T. Paul, A. Ghosh, Structure and vibrational properties of La2-xBixMo2O9 (0.05 ? x ? 0.4) oxygen ion conductors, Journal of Alloys and Compounds, Volume 613, 15 November 2014
  • Xiaoling Yang, Wenjian Zou, Yunhe Su, Yihua Zhu, Hongliang Jiang, Jianhua Shen, Chunzhong Li, Activated nitrogen-doped carbon nanofibers with hierarchical pore as efficient oxygen reduction reaction catalyst for microbial fuel cells, Journal of Power Sources, Volume 266, 15 November 2014