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Boron
Boron information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate glasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. The hydrides are easily oxidized with considerable energy liberation, and have been studied for use as rocket fuels. Demand is increasing for boron filaments, a high-strength, lightweight material chiefly employed for advanced aerospace structures Boron is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Boron is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).

Boron facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Boron is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Boron is a Block P, Group 13, Period 2 element. The electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Boron compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808.

French Bore German Bor Italian Boro Portuguese Boro Spanish Boro Swedish Bor

Abundance. The following table shows the abundance of boron and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
B-10
10.0129370
19.9
B-11
11.0093055
80.1

Safety Data. The safety data for boron metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for boron (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
800.64 kJ mol-1
2nd Ionization Energy
2427.09 kJ mol-1
3rd Ionization Energy
3659.78 kJ mol-1

Conductivity. As to boron's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 1.8E+12 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.04. The thermal conductivity of boron is 27 W m-1 K-1.

Thermal Properties. The melting point and boiling point for boron are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
22.2 kJ mol-1
Heat of Vaporization
504.5 kJ mol-1
Heat of Atomization
557.64 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
B 5 10.81 g.mol -1 2.0 2.3 g.cm-3 at 20 °C 2076 °C 3927 °C 200.pm 0.027 nm 800.64 kJ.mol-1

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Recent Research & Development for Boron

  • N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical. Ueng SH, Solovyev A, Yuan X, Geib SJ, Fensterbank L, Laco^te E, Malacria M, Newcomb M, Walton JC, Curran DP. J Am Chem Soc. 2009 Jul 16. [Epub ahead of print] PMID: 19606860 [PubMed - as supplied by publisher]

  • Boron nitride nanotubes functionalized by a series of carbenes. Cao F, Ren W, Xu X, Ji YM, Zhao C. Phys Chem Chem Phys. 2009 Aug 7;11(29):6256-62. Epub 2009 May 15. PMID: 19606337 [PubMed - in process]

  • EORTC trial 11001: distribution of two (10)B-compounds in patients with squamous cell carcinoma of head and neck, a translational research/phase 1 trial. Wittig A, Collette L, Appelman K, Bührmann S, Jäckel MC, Jöckel KH, Schmid KW, Ortmann U, Moss R, Sauerwein WA. J Cell Mol Med. 2009 Jul 10. [Epub ahead of print] PMID: 19602035 [PubMed - as supplied by publisher]

  • Benzo- and Naphthoborepins: Blue-Emitting Boron Analogues of Higher Acenes. Mercier LG, Piers WE, Parvez M. Angew Chem Int Ed Engl. 2009 Jul 13. [Epub ahead of print] No abstract available. PMID: 19598197 [PubMed - as supplied by publisher]

  • A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate. Guo SP, Guo GC, Wang MS, Zou JP, Zeng HY, Cai LZ, Huang JS. Chem Commun (Camb). 2009 Aug 7;(29):4366-8. Epub 2009 Jun 19. PMID: 19597594 [PubMed - in process]

  • Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes. Zhu X, Ni J, Lai P. Water Res. 2009 Jun 23. [Epub ahead of print] PMID: 19595422 [PubMed - as supplied by publisher]

  • Influence of elastic strains on the adsorption process in porous materials: an experimental approach. Grosman A, Ortega C. Langmuir. 2009 Jul 21;25(14):8083-93. PMID: 19594184 [PubMed - in process]

  • sp(2)-sp(3) Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed beta-Boration of alpha,beta-Unsaturated Conjugated Compounds. Gao M, Thorpe SB, Santos WL. Org Lett. 2009 Jul 13. [Epub ahead of print] PMID: 19594167 [PubMed - as supplied by publisher]

  • Clustering and nearest neighbour distances in atom-probe tomography. Philippe T, De Geuser F, Duguay S, Lefebvre W, Cojocaru-Mirédin O, Da Costa G, Blavette D. Ultramicroscopy. 2009 Jun 21. [Epub ahead of print] PMID: 19592168 [PubMed - as supplied by publisher]

  • Anisotropic Fermi Couplings Due to Large Unquenched Orbital Angular Momentum: Q-Band (1)H, (14)N, and (11)B ENDOR of Bis(trispyrazolylborate) Cobalt(II). Myers WK, Scholes CP, Tierney DL. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591466 [PubMed - as supplied by publisher]

  • Synthesis of chromones and 4-hydroxyquinolines based on uncatalyzed condensations of 1-methoxy-1,3-bis(trimethylsilyloxy)-1,3-butadiene with 2-alkoxy- and 2-nitrobenzoyl chlorides and related reactions. Rahn T, Appel B, Baumann W, Jiao H, Börner A, Fischer C, Langer P. Org Biomol Chem. 2009 May 7;7(9):1931-8. Epub 2009 Mar 20. PMID: 19590790 [PubMed - in process]

  • Convection enhanced delivery of boronated EGF as a molecular targeting agent for neutron capture therapy of brain tumors. Yang W, Barth RF, Wu G, Huo T, Tjarks W, Ciesielski M, Fenstermaker RA, Ross BD, Wikstrand CJ, Riley KJ, Binns PJ. J Neurooncol. 2009 Jul 9. [Epub ahead of print] PMID: 19588228 [PubMed - as supplied by publisher]

  • Boron-enriched star-shaped molecule via cycloaddition reaction. Prasanna Dash B, Satapathy R, Maguire JA, Hosmane NS. Chem Commun (Camb). 2009 Jun 14;(22):3267-9. Epub 2009 May 6. PMID: 19587935 [PubMed - in process]

  • Nanoenergetic materials: boron nanoparticles from the pyrolysis of decaborane and their functionalisation. Bellott BJ, Noh W, Nuzzo RG, Girolami GS. Chem Commun (Camb). 2009 Jun 14;(22):3214-5. Epub 2009 May 7. PMID: 19587917 [PubMed - in process]

  • Ionic high-pressure form of elemental boron. Oganov AR, Chen J, Gatti C, Ma Y, Ma Y, Glass CW, Liu Z, Yu T, Kurakevych OO, Solozhenko VL. Nature. 2009 Jul 9;460(7252):292. No abstract available. PMID: 19587770 [PubMed - in process]

  • Theoretical investigation of the divacancies in boron nitride nanotubes: properties and surface reactivity toward various adsorbates. Zhao JX, Ding YH. J Chem Phys. 2009 Jul 7;131(1):014706. PMID: 19586116 [PubMed - in process]

  • Molecules with All Triple Bonds: OCBBCO, N(2)BBN(2), and [OBBBBO](2-) (dagger). Ducati LC, Takagi N, Frenking G. J Phys Chem A. 2009 Jul 8. [Epub ahead of print] PMID: 19586003 [PubMed - as supplied by publisher]

  • Facile Cyclometalation Reactions of Cp-Zirconium Complexes with Weakly Lewis Acidic Pendent Boron Functionalities. Emmert M, Kehr G, Fröhlich R, Erker G. Chemistry. 2009 Jul 8. [Epub ahead of print] No abstract available. PMID: 19585643 [PubMed - as supplied by publisher]

  • Acquisition-weighted MRSI for Detection and Quantification of BNCT (10)B-carrier L-p-boronophenylalanine-fructose Complex, a Phantom Study. Timonen M, Kankaanranta L, Lundbom N, Kortesniemi M, Seppälä T, Kouri M, Savolainen S, Heikkinen S. J Radiat Res (Tokyo). 2009 Jul 8. [Epub ahead of print] PMID: 19584572 [PubMed - as supplied by publisher]

  • Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes. Spokoyny AM, Reuter MG, Stern CL, Ratner MA, Seideman T, Mirkin CA. J Am Chem Soc. 2009 Jul 15;131(27):9482-3. PMID: 19583431 [PubMed - in process]

 

 

 

 

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