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Boron
Boron information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate glasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. The hydrides are easily oxidized with considerable energy liberation, and have been studied for use as rocket fuels. Demand is increasing for boron filaments, a high-strength, lightweight material chiefly employed for advanced aerospace structures Boron is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Boron is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).

Boron facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Boron is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Boron is a Block P, Group 13, Period 2 element. The electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Boron compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808.

French Bore German Bor Italian Boro Portuguese Boro Spanish Boro Swedish Bor

Abundance. The following table shows the abundance of boron and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
B-10
10.0129370
19.9
B-11
11.0093055
80.1

Safety Data. The safety data for boron metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for boron (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
800.64 kJ mol-1
2nd Ionization Energy
2427.09 kJ mol-1
3rd Ionization Energy
3659.78 kJ mol-1

Conductivity. As to boron's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 1.8E+12 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.04. The thermal conductivity of boron is 27 W m-1 K-1.

Thermal Properties. The melting point and boiling point for boron are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
22.2 kJ mol-1
Heat of Vaporization
504.5 kJ mol-1
Heat of Atomization
557.64 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
B 5 10.81 g.mol -1 2.0 2.3 g.cm-3 at 20 °C 2076 °C 3927 °C 200.pm 0.027 nm 800.64 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Boron

  • Aggregation and deposition behavior of boron nanoparticles in porous media. J Colloid Interface Sci. 2008 Oct 17. [Epub ahead of print]

  • Hydrogen-Mediated Metal-Carbon to Metal-Boron Bond Conversion in Metal-Carboranyl Complexes. J Am Chem Soc. 2008 Oct 31. [Epub ahead of print]

  • [Study of the elements determination method in animal fur by microwave digestion ICP-AES] Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Aug;28(8):1933-7. Chinese.

  • Enhanced Thermoelectric Figure-of-Merit in Nanostructured p-type Silicon Germanium Bulk Alloys. Nano Lett. 2008 Oct 31. [Epub ahead of print]

  • Simultaneous determination of ascorbic acid, uric acid and neurotransmitters with a carbon ceramic electrode prepared by sol-gel technique. Talanta. 2006 Nov 15;70(4):823-32. Epub 2006 Mar 24.

  • Electroanalytical applications of boron-doped diamond microelectrode arrays. Talanta. 2006 Jun 15;69(4):829-34. Epub 2005 Dec 9.

  • Electroanalysis of sulfonamides by flow injection system/high-performance liquid chromatography coupled with amperometric detection using boron-doped diamond electrode. Talanta. 2006 Feb 28;68(5):1726-31. Epub 2005 Sep 23.

  • Amperometric detection of ultra trace amounts of Hg(I) at the surface boron doped diamond electrode modified with iridium oxide. Talanta. 2006 Feb 28;68(5):1610-6. Epub 2005 Sep 22.

  • Use of nickel implanted boron-doped diamond thin film electrode coupled to HPLC system for the determination of tetracyclines. Talanta. 2006 Feb 15;68(4):1329-35. Epub 2005 Aug 25.

  • Separation of molecular constituents from a humic acid by solid-phase extraction following a transesterification reaction. Talanta. 2006 Feb 15;68(4):1135-42. Epub 2005 Aug 18.

  • Statistical evaluation of an analytical GC/MS method for the determination of long chain fatty acids. Talanta. 2006 Jan 15;68(3):888-94. Epub 2005 Jul 20.

  • On-line generation and hydrolysis of methyl borate for the spectrophotometric determination of boron in soil and plants with azomethine-H. Talanta. 2005 Dec 15;68(2):374-81. Epub 2005 Oct 3.

  • Classification of aniseed drinks by means of cluster, linear discriminant analysis and soft independent modelling of class analogy based on their Zn, B, Fe, Mg, Ca, Na and Si content. Talanta. 2005 Jun 15;66(5):1350-4. Epub 2005 Feb 19.

  • Spectrophotometric determination of iron and boron in soil extracts using a multi-syringe flow injection system. Talanta. 2005 Apr 30;66(3):703-11. Epub 2005 Jan 6.

  • Synthesis of cross-linked chitosan possessing N-methyl-d-glucamine moiety (CCTS-NMDG) for adsorption/concentration of boron in water samples and its accurate measurement by ICP-MS and ICP-AES. Talanta. 2005 Mar 31;66(1):136-44. Epub 2004 Dec 8.

  • 1-(2,3,4-Trihydroxybenzylideneamino)-8-hydroxynaphthalene-3,6-disulfonic acid as reagent for spectrophotometric determination of boron in plants. Talanta. 2005 Mar 15;65(5):1307-12.

  • Detection of catechin based on its electrochemical autoxidation. Talanta. 2005 Jan 30;65(2):511-7.

  • Manganese detection in marine sediments: anodic vs. cathodic stripping voltammetry. Talanta. 2005 Jan 30;65(2):423-9.

  • Reduction of hexavalent chromium at solid electrodes in acidic media: reaction mechanism and analytical applications. Talanta. 2005 Jan 15;65(1):74-80.

  • Flow-injection determination of iodide ion in nuclear emergency tablets, using boron-doped diamond thin film electrode. Talanta. 2004 Dec 15;64(5):1253-8.

 

 

 

 

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