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Boron
Boron information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate glasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. The hydrides are easily oxidized with considerable energy liberation, and have been studied for use as rocket fuels. Demand is increasing for boron filaments, a high-strength, lightweight material chiefly employed for advanced aerospace structures Boron is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Boron is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).

Boron facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Boron is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Boron is a Block P, Group 13, Period 2 element. The electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Boron compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808.

French Bore German Bor Italian Boro Portuguese Boro Spanish Boro Swedish Bor

Abundance. The following table shows the abundance of boron and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
B-10
10.0129370
19.9
B-11
11.0093055
80.1

Safety Data. The safety data for boron metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for boron (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
800.64 kJ mol-1
2nd Ionization Energy
2427.09 kJ mol-1
3rd Ionization Energy
3659.78 kJ mol-1

Conductivity. As to boron's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 1.8E+12 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.04. The thermal conductivity of boron is 27 W m-1 K-1.

Thermal Properties. The melting point and boiling point for boron are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
22.2 kJ mol-1
Heat of Vaporization
504.5 kJ mol-1
Heat of Atomization
557.64 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
B 5 10.81 g.mol -1 2.0 2.3 g.cm-3 at 20 °C 2076 °C 3927 °C 200.pm 0.027 nm 800.64 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Boron



  • Decay resistance of wood treated with boric acid and tall oil derivates. Bioresour Technol. 2008 May;99(7):2102-2106. Epub 2007 Oct 10.

  • Hexagonal boron nitride as a tablet lubricant and a comparison with conventional lubricants. Int J Pharm. 2008 Apr 2;353(1-2):45-51. Epub 2007 Nov 17.

  • Boron removal from aqueous solutions by ion-exchange resin: Column sorption-elution studies. J Hazard Mater. 2008 Apr 1;152(2):744-9. Epub 2007 Jul 20.

  • Synthesis of aluminium borate-boron oxide and binary titanium-boron and zirconium-boron oxides from metal alkoxides and (MeO)(3)B(3)O(3) in non-aqueous solvents. Dalton Trans. 2008 Mar 21;(11):1503-6. Epub 2008 Feb 12.

  • Influence of the solvent and R groups on the structure of (carboranyl)R(2)PI(2) compounds in solution. Crystal structure of the first iodophosphonium salt incorporating the anion [7,8-nido-C(2)B(9)H(10)](-). Dalton Trans. 2008 Mar 21;(11):1471-80. Epub 2008 Feb 14.

  • Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid. J Hazard Mater. 2008 Mar 21;152(1):415-22. Epub 2007 Jul 7.

  • Aggregation Behavior of Nucleoside-Boron Cluster Conjugates in Aqueous Solutions. Langmuir. 2008 Mar 18;24(6):2625-2630. Epub 2008 Feb 8.

  • Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah. Sci Total Environ. 2008 Mar 15;392(1):1-11. Epub 2007 Dec 18.

  • Direct electrochemistry of glucose oxidase and biosensing for glucose based on boron-doped carbon nanotubes modified electrode. Biosens Bioelectron. 2008 Mar 14;23(8):1272-7. Epub 2007 Nov 28.

  • Topochemical 3D Polymerization of C(60) under High Pressure at Elevated Temperatures. J Am Chem Soc. 2008 Mar 11; [Epub ahead of print]

  • Separate vaporisation of boric acid and inorganic boron from tungsten sample cuvette-tungsten boat furnace followed by the detection of boron species by inductively coupled plasma mass spectrometry and atomic emission spectrometry (ICP-MS and ICP-AES). Anal Chim Acta. 2008 Mar 10;610(2):179-85. Epub 2008 Jan 25.

  • Lithium aminoborohydrides 16. Synthesis and reactions of monomeric and dimeric aminoboranes. J Org Chem. 2008 Mar 7;73(5):1898-905. Epub 2008 Jan 24.

  • The Diamond/Aqueous Electrolyte Interface: an Impedance Investigation. Langmuir. 2008 Mar 7; [Epub ahead of print]

  • Label-Free Sequence-Specific DNA Sensing Using Copper-Enhanced Anodic Stripping of Purine Bases at Boron-Doped Diamond Electrodes. Anal Chem. 2008 Mar 6; [Epub ahead of print]

  • Development of general catalytic allylation of acylhydrazones with pinacolyl allylboronate using an indium(i) catalyst. Org Lett. 2008 Mar 6;10(5):737-40. Epub 2008 Feb 7.

  • Mild synthesis of organophosphorus compounds: reaction of phosphorus-containing carbenoids with organoboranes. Org Lett. 2008 Mar 6;10(5):977-80. Epub 2008 Feb 6.

  • Boron-Substituted Difluorocyclopropanes: New Building Blocks of gem-Difluorocyclopropanes. Org Lett. 2008 Mar 6;10(5):769-72. Epub 2008 Jan 29.

  • Fine-Tuning of Boron Complexes with Cage-Shaped Ligand Geometry: Rational Design of Triphenolic Ligand as a Template for Structure Control. Org Lett. 2008 Mar 6;10(5):929-932. Epub 2008 Jan 26.

  • Chemical state and environment of boron dopant in B,N-codoped anatase TiO2 nanoparticles: an avenue for probing diamagnetic dopants in TiO2 by electron paramagnetic resonance spectroscopy. J Am Chem Soc. 2008 Mar 5;130(9):2760-1. Epub 2008 Feb 7.

  • Boron Trihalide Mediated Alkyne-Aldehyde Coupling Reactions: A Mechanistic Investigation. J Org Chem. 2008 Mar 5; [Epub ahead of print]

 

 

 

 

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