Boron information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Boron in its elemental form is not toxic. Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate glasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. The hydrides are easily oxidized with considerable energy liberation, and have been studied for use as rocket fuels. Demand is increasing for boron filaments, a high-strength, lightweight material chiefly employed for advanced aerospace structures Boron is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Boron is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).
Boron facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Boron is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Boron is a Block P, Group 13, Period 2 element. The number of electrons in each of Boron's shells is 2, 3 and its electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm.
All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, thin fillm deposition using sputtering targets and evaporation materials, metallurgy and optical materials and other high technology applications. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Boron compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808.
The name Boron originates from a combination of carbon and the Arabic word 'buraqu meaning borax.
Bore |
Bor |
Boro |
Boro |
Boro |
Bor |
Abundance. The following table shows the abundance of boron and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
| Isotope |
Atomic Mass |
% Abundance on Earth |
| B-10 |
10.0129370 |
19.9 |
| B-11 |
11.0093055 |
80.1 |
The following table shows the abundance of Boron present in the human body and in the universe scaled to parts per billion (ppb) by weight and by atom:
| |
Typical Human Body |
Universe |
| by Weight |
700 ppb |
1 ppb |
| by Atom |
410 ppb |
0.1 ppb |
Safety Data and Biological Role. The safety data for boron metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin. Boron compounds are required by green algae and higher plants.
Ionization Energy. The ionization energy for boron (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
| 1st Ionization Energy |
800.64 kJ mol-1 |
| 2nd Ionization Energy |
2427.09 kJ mol-1 |
| 3rd Ionization Energy |
3659.78 kJ mol-1 |
Conductivity. As to boron's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 1.8E+12 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.04. The thermal conductivity of boron is 27 W m-1 K-1.
Thermal Properties. The melting point and boiling point for boron are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
| Heat of Fusion |
22.2 kJ mol-1 |
| Heat of Vaporization |
504.5 kJ mol-1 |
| Heat of Atomization |
557.64 kJ mol-1 |
Recent Research & Development for BoronExpression of the Arabidopsis Borate Efflux Transporter Gene, AtBOR4, in Rice Affects the Xylem Loading of Boron and Tolerance to Excess Boron.
Kajikawa M, Fujibe T, Uraguchi S, Miwa K, Fujiwara T.
Biosci Biotechnol Biochem. 2011 Dec 7. [Epub ahead of print]
PMID:
22146734
[PubMed - as supplied by publisher]
Cl-BODIPYs: a BODIPY class enabling facile B-substitution.
Lundrigan T, Crawford SM, Cameron TS, Thompson A.
Chem Commun (Camb). 2011 Dec 6. [Epub ahead of print]
PMID:
22146671
[PubMed - as supplied by publisher]
Size-Dependent Electrocatalytic Activity of Gold Nanoparticles on HOPG and Highly Boron-Doped Diamond Surfaces.
Brülle T, Ju W, Niedermayr P, Denisenko A, Paschos O, Schneider O, Stimming U.
Molecules. 2011 Dec 6;16(12):10059-77.
PMID:
22146369
[PubMed - in process]
[Investigation of antiviral activity of adamantan boron derivaties on pandemic influenza virus models].
[No authors listed]
Antibiot Khimioter. 2011;56(5-6):3-6. Russian.
PMID:
22145224
[PubMed - in process]
Surface glycosylation of polysulfone membrane towards a novel complexing membrane for boron removal.
Meng J, Yuan J, Kang Y, Zhang Y, Du Q.
J Colloid Interface Sci. 2011 Nov 22. [Epub ahead of print]
PMID:
22142998
[PubMed - as supplied by publisher]
Comparison of neutron spectrum measurement methods used for the epithermal beam of the LVR-15 research reactor.
Viererbl L, Klupák V, Lahodová Z, Marek M.
Appl Radiat Isot. 2011 Nov 25. [Epub ahead of print]
PMID:
22138025
[PubMed - as supplied by publisher]
Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation.
Kliman LT, Mlynarski SN, Ferris GE, Morken JP.
Angew Chem Int Ed Engl. 2011 Dec 1. doi: 10.1002/anie.201105716. [Epub ahead of print]
PMID:
22135105
[PubMed - as supplied by publisher]
Graphene substrate-mediated catalytic performance enhancement of Ru nanoparticles: a first-principles study.
Liu X, Yao KX, Meng C, Han Y.
Dalton Trans. 2011 Dec 1. [Epub ahead of print]
PMID:
22134739
[PubMed - as supplied by publisher]
C7H122+: A Prototype Hexacoordinate Carbonium Ion.
Rasul G, Olah GA, Prakash GK.
J Phys Chem A. 2011 Nov 30. [Epub ahead of print]
PMID:
22129100
[PubMed - as supplied by publisher]
Measurements of beam current density and proton fraction of a permanent-magnet microwave ion source.
Waldmann O, Ludewigt B.
Rev Sci Instrum. 2011 Nov;82(11):113505.
PMID:
22128974
[PubMed - in process]
Hydrogenation of fragment cations produced by femtosecond laser ablation of boron nitride.
Kobayashi T, Matsuo Y.
J Chem Phys. 2011 Nov 28;135(20):204504.
PMID:
22128940
[PubMed - in process]
Spectroscopic and structural characterization of the CyNHC adduct of B2pin2 in solution and in the solid state.
Kleeberg C, Crawford AG, Batsanov AS, Hodgkinson P, Apperley DC, Cheung MS, Lin Z, Marder TB.
J Org Chem. 2011 Nov 29. [Epub ahead of print]
PMID:
22126312
[PubMed - as supplied by publisher]
Novel retinoic Acid receptor alpha agonists for treatment of kidney disease.
Zhong Y, Wu Y, Liu R, Li Z, Chen Y, Evans T, Chuang P, Das B, He JC.
PLoS One. 2011;6(11):e27945. Epub 2011 Nov 18.
PMID:
22125642
[PubMed - in process]
Structure, bonding, vibration and ideal strength of primitive-centered tetragonal boron nitride.
Li Z, Gao F.
Phys Chem Chem Phys. 2011 Nov 29. [Epub ahead of print]
PMID:
22124285
[PubMed - as supplied by publisher]
Evaluation of the ions release / incorporation of the prototype S-PRG filler-containing endodontic sealer.
Han L, Okiji T.
Dent Mater J. 2011 Nov 25. [Epub ahead of print]
PMID:
22123015
[PubMed - as supplied by publisher]
Kinetic Monte Carlo study on the suppression of boron transient enhanced diffusion with carbon pre-implant.
Park SY, Sung KS, Won T.
J Nanosci Nanotechnol. 2011 Jul;11(7):6594-8.
PMID:
22121763
[PubMed - in process]
Synthesis of B4C nanobelts in porous SiC bodies.
Jung IC, Kwon YD, Lee J, Min BK.
J Nanosci Nanotechnol. 2011 Jul;11(7):6555-8.
PMID:
22121755
[PubMed - in process]
Theoretical investigation of Ti-adsorbed graphene for hydrogen storage using the ab-initio method.
Park HL, Yoo DS, Yi SC, Chung YC.
J Nanosci Nanotechnol. 2011 Jul;11(7):6131-5.
PMID:
22121672
[PubMed - in process]
Improvement of heavy dopant doped Ni-silicide using ytterbium interlayer for nano-scale MOSFETS with an ultra shallow junction.
Shin HS, Oh SK, Kang MH, Li SG, Lee GW, Lee HD.
J Nanosci Nanotechnol. 2011 Jul;11(7):5628-32.
PMID:
22121582
[PubMed - in process]
A novel fluorescent probe for Au(iii)/Au(i) ions based on an intramolecular hydroamination of a Bodipy derivative and its application to bioimaging.
Wang JB, Wu QQ, Min YZ, Liu YZ, Song QH.
Chem Commun (Camb). 2011 Nov 28. [Epub ahead of print]
PMID:
22121504
[PubMed - as supplied by publisher] |