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Arsenic
Arsenic information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenide. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Arsenic facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Arsenic is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Arsenic is a Block P, Group 15, Period 4 element. The electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3. The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Arsenic compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Arsenic was first discovered by Early Man.

French Arsenic German Arsen Italian Arsenico Portuguese Arsênic Spanish Arsénico Swedish Arsenik

Abundance. The following table shows the abundance of arsenic and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
As-75
74.921596
100

Safety Data. The safety data for arsenic metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for arsenic (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
944.46 kJ mol-1
2nd Ionization Energy
1797.82 kJ mol-1
3rd Ionization Energy
2735.48 kJ mol-1

Conductivity. As to arsenic's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 33.3 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.18. The thermal conductivity of arsenic is 50 W m-1 K-1.

Thermal Properties. The melting point and boiling point for arsenic are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.7 kJ mol-1
Heat of Vaporization
31.9 kJ mol-1
Heat of Atomization
301.42 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
As 33 74.9216 g.mol -1 2.0 5.7 g.cm-3 at 20 °C 814 °C 615 °C 185.pm 0.222 nm (-2) ; 0.047 (+5) ; 0.058 (+3) 944.46 7 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Arsenic

  • Arsenic accumulation in Scutellaria baicalensis Georgi and its effects on plant growth and pharmaceutical components. Cao H, Jiang Y, Chen J, Zhang H, Huang W, Li L, Zhang W. J Hazard Mater. 2009 Jun 16. [Epub ahead of print] PMID: 19577841 [PubMed - as supplied by publisher]

  • A comparison of arsenic tolerance, uptake and accumulation between arsenic hyperaccumulator, Pteris vittata L. and non-accumulator, P. semipinnata L.-A hydroponic study. Lou LQ, Ye ZH, Wong MH. J Hazard Mater. 2009 Jun 12. [Epub ahead of print] PMID: 19577839 [PubMed - as supplied by publisher]

  • Preparation and evaluation of iron-chitosan composites for removal of As(III) and As(V) from arsenic contaminated real life groundwater. Gupta A, Chauhan VS, Sankararamakrishnan N. Water Res. 2009 Jun 6. [Epub ahead of print] PMID: 19577786 [PubMed - as supplied by publisher]

  • Sodium arsenite-induced DAPK promoter hypermethylation and autophagy via ERK1/2 phosphorylation in human uroepithelial cells. Huang YC, Hung WC, Chen WT, Yu HS, Chai CY. Chem Biol Interact. 2009 Jul 2. [Epub ahead of print] PMID: 19577553 [PubMed - as supplied by publisher]

  • Carcinogenic effect of arsenate in C57BL/6J/Han mice and its modulation by different dietary selenium status. Stepnik M, Stetkiewicz J, Krajnow A, Domeradzka K, Gradecka-Meesters D, Arkusz J, Stanczyk M, Palus J, Dziubaltowska E, Sobala W, Gromadzinska J, Wasowicz W, Rydzynski K. Ecotoxicol Environ Saf. 2009 Jul 2. [Epub ahead of print] PMID: 19577296 [PubMed - as supplied by publisher]

  • Effects of Arsenic on Maternal and Fetal Health. Vahter M. Annu Rev Nutr. 2009 Jun 12. [Epub ahead of print] PMID: 19575603 [PubMed - as supplied by publisher]

  • Characterization of glutathione reductase and catalase in the fronds of two Pteris ferns upon arsenic exposure. Kertulis-Tartar GM, Rathinasabapathi B, Ma LQ. Plant Physiol Biochem. 2009 Jun 12. [Epub ahead of print] PMID: 19574057 [PubMed - as supplied by publisher]

  • Arsenic trioxide-induced apoptosis of Hep-2 cell line through modulating intracellular glutathione (GSH) level. Cheng B, Yang X, An L, Gao B, Liu X. Auris Nasus Larynx. 2009 Jun 30. [Epub ahead of print] PMID: 19574005 [PubMed - as supplied by publisher]

  • Removal of arsenic from water: Effects of competing anions on As(III) removal in KMnO(4)-Fe(II) process. Guan X, Dong H, Ma J, Jiang L. Water Res. 2009 Jun 11. [Epub ahead of print] PMID: 19573891 [PubMed - as supplied by publisher]

  • Increased Risk of QT Prolongation Associated with Atherosclerotic Diseases in Arseniasis Endemic Area of Southwestern Coast Taiwan. Wang CH, Chen CL, Hsiao CK, Chiang FT, Hsu LI, Chiou HY, Hsueh YM, Wu MM, Chen CJ. Toxicol Appl Pharmacol. 2009 Jun 29. [Epub ahead of print] PMID: 19573547 [PubMed - as supplied by publisher]

  • ARSENIC BINDING TO IRON(II) MINERALS PRODUCED BY AN IRON(III)-REDUCING AEROMONAS STRAIN ISOLATED FROM PADDY SOIL. Wang XJ, Chen XP, Kappler A, Sun GX, Zhu YG. Environ Toxicol Chem. 2009 Jul 2:1. [Epub ahead of print] PMID: 19572768 [PubMed - as supplied by publisher]

  • Arsenic Trioxide Inhibits Human T Cell-Lymphotropic Virus-1-Induced Syncytiums by Down-Regulating gp46. Nabeshi H, Yoshikawa T, Kamada H, Shibata H, Sugita T, Abe Y, Nagano K, Nomura T, Minowa K, Yamashita T, Itoh N, Yoshioka Y, Tsunoda S, Tsutsumi Y. Biol Pharm Bull. 2009 Jul;32(7):1286-8. PMID: 19571400 [PubMed - in process]

  • Arsenic accumulation by Pseudomonas stutzeri and its response to some thiol chelators. Joshi DN, Patel JS, Flora SJ, Kalia K. Environ Health Prev Med. 2008 Sep;13(5):257-63. Epub 2008 Jul 4. PMID: 19568912 [PubMed - in process]

  • Correlation between the arsenic concentrations in the air and the SMR of lung cancer. Yoshikawa M, Aoki K, Ebine N, Kusunoki M, Okamoto A. Environ Health Prev Med. 2008 Jul;13(4):207-18. Epub 2008 Apr 26. PMID: 19568907 [PubMed - in process]

  • Metallomics study using hair mineral analysis and multiple logistic regression analysis: relationship between cancer and minerals. Yasuda H, Yoshida K, Segawa M, Tokuda R, Tsutsui T, Yasuda Y, Magara S. Environ Health Prev Med. 2009 Jun 26. [Epub ahead of print] PMID: 19568830 [PubMed - as supplied by publisher]

  • Folate-mediated intracellular drug delivery increases the anticancer efficacy of nanoparticulate formulation of arsenic trioxide. Chen H, Ahn R, Van den Bossche J, Thompson DH, O'Halloran TV. Mol Cancer Ther. 2009 Jun 30. [Epub ahead of print] PMID: 19567824 [PubMed - as supplied by publisher]

  • Arsenic in contaminated waters: biogeochemical cycle, microbial metabolism and biotreatment processes. Lièvremont D, Bertin PN, Lett MC. Biochimie. 2009 Jun 27. [Epub ahead of print] PMID: 19567262 [PubMed - as supplied by publisher]

  • Phase II study of darinaparsin in patients with advanced hepatocellular carcinoma. Wu J, Henderson C, Feun L, Van Veldhuizen P, Gold P, Zheng H, Ryan T, Blaszkowsky LS, Chen H, Costa M, Rosenzweig B, Nierodzik M, Hochster H, Muggia F, Abbadessa G, Lewis J, Zhu AX. Invest New Drugs. 2009 Jun 30. [Epub ahead of print] PMID: 19565187 [PubMed - as supplied by publisher]

  • Prevalence of Kidney Dysfunction in Humans - Relationship to Cadmium Dose, Metallothionein, Immunological and Metabolic factors. Nordberg GF, Jin T, Wu X, Lu J, Chen L, Lei L, Hong F, Nordberg M. Biochimie. 2009 Jun 26. [Epub ahead of print] PMID: 19563860 [PubMed - as supplied by publisher]

  • [Arsenic trioxide inhibits cell growth in imatinib-resistant bcr-abl mutant cell lines in vitro] Lu RZ, Qiu L, Wang XD, Li XF, Chen LJ, Wang XL, Zhang BL, Ma J. Zhonghua Xue Ye Xue Za Zhi. 2009 Jan;30(1):13-7. Chinese. PMID: 19563028 [PubMed - in process]

 

 

 

 

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