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Arsenic
Arsenic information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenide. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Arsenic facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Arsenic is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Arsenic is a Block P, Group 15, Period 4 element. The electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3. The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Arsenic compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Arsenic was first discovered by Early Man.<

French Arsenic German Arsen Italian Arsenico Portuguese Arsênic Spanish Arsénico Swedish Arsenik

Abundance. The following table shows the abundance of arsenic and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
As-75
74.921596
100

Safety Data. The safety data for arsenic metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for arsenic (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
944.46 kJ mol-1
2nd Ionization Energy
1797.82 kJ mol-1
3rd Ionization Energy
2735.48 kJ mol-1

Conductivity. As to arsenic's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 33.3 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.18. The thermal conductivity of arsenic is 50 W m-1 K-1.

Thermal Properties. The melting point and boiling point for arsenic are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.7 kJ mol-1
Heat of Vaporization
31.9 kJ mol-1
Heat of Atomization
301.42 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
As 33 74.9216 g.mol -1 2.0 5.7 g.cm-3 at 20 °C 814 °C 615 °C 185.pm 0.222 nm (-2) ; 0.047 (+5) ; 0.058 (+3) 944.46 7 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Arsenic

  • Arsenic abundance and variation in golf course lakes. Sci Total Environ. 2008 Feb 29; [Epub ahead of print]

  • A reinvestigation of the synthesis of arsonolipids (2,3-diacyloxypropylarsonic acids). Chem Phys Lipids. 2008 Feb 12; [Epub ahead of print]

  • Element Composition of Tea Leaves and Tea Infusions and Its Impact on Health. Bull Environ Contam Toxicol. 2008 Feb 29; [Epub ahead of print]

  • Chemical states of trace elements in sewage sludge incineration ash by using x-ray absorption fine structure. Water Sci Technol. 2008;57(3):411-7.

  • A dominant suppressor mutation of the met30 cell cycle defect suggests regulation of the S. cerevisiae Met4 CBF1 transcription complex by Met32. J Biol Chem. 2008 Feb 28; [Epub ahead of print]

  • Clinical Manifestations and Arsenic Methylation after a Rare Subacute Arsenic Poisoning Accident. Toxicol Sci. 2008 Feb 27; [Epub ahead of print]

  • Redox processes and water quality of selected principal aquifer systems. Ground Water. 2008 Mar-Apr;46(2):259-71.

  • Arsenic-Containing Long-Chain Fatty Acids in Cod-Liver Oil: A Result of Biosynthetic Infidelity? Angew Chem Int Ed Engl. 2008 Feb 27; [Epub ahead of print] No abstract available.

  • Membrane fatty acids adaptive profile in the simultaneous presence of arsenic and toluene in Bacillus sp. ORAs2 and Pseudomonas sp. ORAs5 strains. Extremophiles. 2008 Feb 28; [Epub ahead of print]

  • Arsenic-induced mitochondrial instability leading to programmed cell death in the exposed individuals. Toxicology. 2008 Jan 12; [Epub ahead of print]

  • Measurement of quenching cross sections for laser-induced fluorescence of atomic arsenic. Appl Opt. 1998 Oct 20;37(30):7132-6.

  • Hyperleukocytosis from arsenic trioxide. Pediatr Blood Cancer. 2008 Feb 25; [Epub ahead of print]

  • Bhattacharya P., Mukherjee A. B., Bundschuh J., Zevenhoven R., and Loeppert R.H. (ed): Arsenic in Soil and Groundwater Environment. Biochemical Interactions, Health Effects and Remediation; Volume 9: Trace Metals in the Environment. Series edited by J. Nriagu : Elsevier, Amsterdam, 2007, 653 pp, GBP 68.99/USD 120/EUR 99.95, ISBN 978-444-51820-0. Environ Geochem Health. 2008 Feb 26; [Epub ahead of print] No abstract available.

  • Arsenic, cadmium, and lead in california cropland soils: role of phosphate and micronutrient fertilizers. J Environ Qual. 2008 Feb 20;37(3):689-95. Print 2008 May-Jun.

  • Acute promyelocytic leukemia: from highly fatal to highly curable. Blood. 2008 Mar 1;111(5):2505-15.

  • Regulation of arsenic trioxide-induced cellular responses by Mnk1 and Mnk2. J Biol Chem. 2008 Feb 25; [Epub ahead of print]

  • Sample pre-treatment to eliminate cationic methylated arsenic for determining arsenite on an anion-exchange column by high performance liquid chromatography-inductively coupled plasma mass spectrometry. Anal Chim Acta. 2008 Mar 17;611(1):48-55. Epub 2008 Feb 2.

  • Arsenic trioxide: safety issues and their management. Acta Pharmacol Sin. 2008 Mar;29(3):296-304.

  • Characterization of the activity of heavy metal-responsive promoters in the cyanobacterium Synechocystis PCC 6803. Acta Biol Hung. 2007;58 Suppl:11-22.

  • Inhibition of mitochondrial protein translation sensitizes melanoma cells to arsenic trioxide cytotoxicity via a reactive oxygen species dependent mechanism. Cancer Chemother Pharmacol. 2008 Feb 23; [Epub ahead of print]

 

 

 

 

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