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Tin
Tin information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Tin compounds sprayed onto glass are used to produce electrically conductive coatings. These have been used for panel lighting and for frost-free windshields. Most window glass is now made by floating molten glass on molten tin (float glass) to produce a flat surface. Crystalline tin-niobium alloy is superconductive at very low temperatures. This promises to be important in the construction of superconductive magnets that generate enormous field strengths but use practically no power. Tin is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. An important tin compound is the chloride, which is used as a reducing agent and as a mordant in calico printing.  Tin is also used in various metal alloys (See AE Alloys).

Tin facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Tin is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Tin is a Block P, Group 14, Period 5 element. The electronic configuration is [Kr] 4d10 5s2 5p2. In its elemental form tin's CAS number is 7440-31-5. The tin atom has a radius of 140.5.pm and it's Van der Waals radius is 217.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Tin compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Tin was first discovered by Early Man..

French Étain German Zinn Italian Stagno Portuguese Estanho Spanish Estaño Swedish Tenn

Abundance. The following table shows the abundance of tin and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Sn-112
111.904821
0.97
Sn-114
113.902782
0.65
Sn-115
114.903346
0.34
Sn-116
115.901744
14.53
Sn-117
116.902954
7.68
Sn-118
117.901606
24.23
Sn-119
118.903309
8.59
Sn-120
119.902197
32.59
Sn-122
121.903440
4.63
Sn-124
123.905275
5.79

Safety Data. The safety data for tin metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for tin (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
708.58 kJ mol-1
2nd Ionization Energy
1411.81 kJ mol-1
3rd Ionization Energy
2943.07 kJ mol-1

Conductivity. As to tin's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 11 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.96. The thermal conductivity of tin is 66.6 W m-1 K-1.

Thermal Properties. The melting point and boiling point for tin are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
7.2 kJ mol-1
Heat of Vaporization
296.2 kJ mol-1
Heat of Atomization
302 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Sn 50 118.69 g.mol -1 1.8 5.77 g.cm-3 at 20 °C 232 °C 2270 °C 217.pm 0.112 nm (+2) ; 0.070 (+4) 708.58 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Tin

  • Study on optical constants of ITO:Ag nanocompsite films. Sun ZQ, Xiao L, Cao CB, Cai Q, Song XP. Appl Opt. 2009 Oct 20;48(30):5759-63. doi: 10.1364/AO.48.005759. PMID: 19844312 [PubMed - in process]

  • Mozart in my practice. Carelli F. Br J Gen Pract. 2009 Oct;59(567):780. No abstract available. PMID: 19843427 [PubMed - in process]

  • High-Performance Single-Crystalline Arsenic-Doped Indium Oxide Nanowires for Transparent Thin-Film Transistors and Active Matrix Organic Light-Emitting Diode Displays. Chen PC, Shen G, Chen H, Ha YG, Wu C, Sukcharoenchoke S, Fu Y, Liu J, Facchetti A, Marks TJ, Thompson ME, Zhou C. ACS Nano. 2009 Oct 20. [Epub ahead of print] PMID: 19842677 [PubMed - as supplied by publisher]

  • Exercises for paretic upper limb after stroke: A combined virtual-reality and telemedicine approach. Piron L, Turolla A, Agostini M, Zucconi C, Cortese F, Zampolini M, Zannini M, Dam M, Ventura L, Battauz M, Tonin P. J Rehabil Med. 2009 Nov;41(12):1016-102. PMID: 19841835 [PubMed - in process]

  • Contralateral testicular biopsy in testis cancer: current concepts and controversies. Heidenreich A. BJU Int. 2009 Nov;104(9 Pt B):1346-50. PMID: 19840011 [PubMed - in process]

  • Solution-deposited sodium beta-alumina gate dielectrics for low-voltage and transparent field-effect transistors. Pal BN, Dhar BM, See KC, Katz HE. Nat Mater. 2009 Oct 18. [Epub ahead of print] PMID: 19838183 [PubMed - as supplied by publisher]

  • Enzyme-mediated amperometric biosensors prepared via successive surface-initiated atom-transfer radical polymerization. Zhang ZB, Yuan SJ, Zhu XL, Neoh KG, Kang ET. Biosens Bioelectron. 2009 Oct 1. [Epub ahead of print] PMID: 19837578 [PubMed - as supplied by publisher]

  • Pseudo alopecia triangularis: a very rare aspect of male pattern baldness. D'Ovidio R. G Ital Dermatol Venereol. 2009 Oct;144(5):622-3. No abstract available. PMID: 19834442 [PubMed - in process]

  • Three concentrations of levobupivacaine for ilioinguinal/iliohypogastric nerve block in ambulatory pediatric surgery. Disma N, Tuo P, Pellegrino S, Astuto M. J Clin Anesth. 2009 Sep;21(6):389-93. PMID: 19833270 [PubMed - in process]

  • Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination. Peng Y, Guo JD, Ellis BD, Zhu Z, Fettinger JC, Nagase S, Power PP. J Am Chem Soc. 2009 Oct 16. [Epub ahead of print] PMID: 19831421 [PubMed - as supplied by publisher]

  • Modified Thermodynamics in Ionic Liquids for Controlled Electrocrystallization of Nanocubes, Nanowires, and Crystalline Thin Films of Silver-Tetracyanoquinodimethane. Zhao C, Macfarlane DR, Bond AM. J Am Chem Soc. 2009 Oct 15. [Epub ahead of print] PMID: 19831410 [PubMed - as supplied by publisher]

  • Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable-Temperature Electrical Conductivity. Djukic B, Lemaire MT. Inorg Chem. 2009 Oct 15. [Epub ahead of print] PMID: 19831361 [PubMed - as supplied by publisher]

  • Treatment of gastric emptying delay. Bortolotti M. Minerva Gastroenterol Dietol. 2009 Sep;55(3):345-77. PMID: 19829288 [PubMed - in process]

  • [Metallic elements in 31st updating of 67/548/EEC directive] Apostoli P, Catalani S. G Ital Med Lav Ergon. 2009 Apr-Jun;31(2):177-81. Italian. PMID: 19827279 [PubMed - in process]

  • Solvent-free direct reductive amination by catalytic use of an organotin reagent incorporated on an ionic liquid. Pham PD, Bertus P, Legoupy S. Chem Commun (Camb). 2009 Nov 7;(41):6207-9. Epub 2009 Sep 22. PMID: 19826670 [PubMed - in process]

  • Theoretical Modeling of Laser Ablation of Quaternary Bronze Alloys: Case Studies Comparing Femtosecond and Nanosecond LIBS Experimental Data (dagger). Fornarini L, Fantoni R, Colao F, Santagata A, Teghil R, Elhassan A, Harith MA. J Phys Chem A. 2009 Oct 9. [Epub ahead of print] PMID: 19817368 [PubMed - as supplied by publisher]

  • Facile Synthesis of Macrocellular Mesoporous Foamlike Ce-Sn Mixed Oxides with a Nanocrystalline Framework by Using Triblock Copolymer as the Single Template. Li LL, Xu J, Yuan Q, Li ZX, Song WG, Yan CH. Small. 2009 Oct 8. [Epub ahead of print] PMID: 19816877 [PubMed - as supplied by publisher]

  • Tin Oxide Thin Film with Three-Dimensional Ordered Reticular Morphology as a Lithium Ion Battery Anode. Zhu X, Guo Z, Zhang P, Du G, Zeng R, Chen Z, Liu H. Chemphyschem. 2009 Oct 6. [Epub ahead of print] PMID: 19810085 [PubMed - as supplied by publisher]

  • A randomized study to compare ramp versus burst antitachycardia pacing therapies to treat fast ventricular tachyarrhythmias in patients with implantable cardioverter defibrillators: the PITAGORA ICD trial. Gulizia MM, Piraino L, Scherillo M, Puntrello C, Vasco C, Scianaro MC, Mascia F, Pensabene O, Giglia S, Chiarandà G, Vaccaro I, Mangiameli S, Corrao D, Santi E, Grammatico A; PITAGORA ICD Study Investigators. Circ Arrhythm Electrophysiol. 2009 Apr;2(2):146-53. Epub 2009 Feb 13. PMID: 19808459 [PubMed - in process]

  • Pharmacokinetics and tolerability of single escalating doses of gabapentin enacarbil: a randomized-sequence, double-blind, placebo-controlled crossover study in healthy volunteers. Lal R, Sukbuntherng J, Luo W, Chen D, Vu A, Tovera J, Cundy KC. Clin Ther. 2009 Aug;31(8):1776-86. PMID: 19808136 [PubMed - in process]

 

 

 

 

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