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Cadmium

 

Cadmium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Cadmium is a component of some of the lowest melting alloys; it is used in bearing alloys with low coefficients of friction and great resistance to fatigue. Cadmium is used extensively in electroplating, which accounts for about 60% of its use. It is also used in many types of solder, for standard E.M.F. cells, for nickel-cadmium batteries, and as a barrier to control nuclear fission. Cadmium compounds are used in black and white television phosphors and in blue and green phosphors for color television tubes and CRT monitors. Cadmium in glass and ceramic glazes creates a distinctive cadmium yellow. It forms a number of compounds, of which the sulfate is most common; the sulfide is used as a yellow pigment. Cadmium is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Cadmium is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity).  Cadmium is also used in various metal alloys (See AE Alloys).

Cadmium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Cadmium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Cadmium is a Block D, Group 12, Period 5 element. The electronic configuration is [Kr] 4d10 5s2. In its elemental form cadmium's CAS number is 7440-43-9. The cadmium atom has a radius of 148.9.pm and it's Van der Waals radius is 158.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Cadmium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Cadmium was first discovered by Fredrich Stromeyer in 1817.

French Cadmium German Cadmium Italian Cadmio Portuguese Cádmio Spanish Cadmio Swedish Kadmium <

Abundance. The following table shows the abundance of cadmium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Cd-106
105.906458
1.25
Cd-108
107.904183
0.89
Cd-110
109.903006
12.49
Cd-111
110.904182
12.80
Cd-112
111.902757
24.13
Cd-113
112.904401
12.22
Cd-114
113.903358
28.73
Cd-116
115.904755
7.49

Safety Data. The safety data for cadmium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for cadmium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
867.78 kJ mol-1
2nd Ionization Energy
1631.42 kJ mol-1
3rd Ionization Energy
3616.30 kJ mol-1

Conductivity. As to cadmium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 6.83 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.69. The thermal conductivity of cadmium is 96.8 W m-1 K-1.

Thermal Properties. The melting point and boiling point for cadmium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
6.11 kJ mol-1
Heat of Vaporization
100 kJ mol-1
Heat of Atomization
112.05 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Cd 48 112.4 g.mol -1 1.7 8.7 g.cm-3 at 20 °C 321 °C 767 °C 158.pm 0.097 nm (+2) 867.78 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Cadmium

  • A Human Stem Cell Based Model For Identifying Adverse Effects Of Organic And Inorganic Chemicals On The Developing Nervous System. Buzanska L, Sypecka J, Molteni SN, Compagnoni A, Hogberg HT, Del Torchio R, Domanska-Janik K, Zimmer J, Coecke S. Stem Cells. 2009 Jul 16. [Epub ahead of print] PMID: 19609937 [PubMed - as supplied by publisher]

  • Cadmium Stimulates the Expression of Vascular Cell Adhesion Molecule-1 (VCAM-1) via p38 Mitogen-Activated Protein Kinase (MAPK) and JNK Activation in Cerebrovascular Endothelial Cells. Park SL, Kim YM, Ahn JH, Lee SH, Baik EJ, Moon CH, Jung YS. J Pharmacol Sci. 2009 Jul;110(3):405-9. PMID: 19609071 [PubMed - in process]

  • Fixed-bed column study for the removal of cadmium (II) and nickel (II) ions from aqueous solutions using peat and mollusk shells. Li C, Champagne P. J Hazard Mater. 2009 Jun 23. [Epub ahead of print] PMID: 19608338 [PubMed - as supplied by publisher]

  • Chelating agent-assisted electrokinetic removal of cadmium, lead and copper from contaminated soils. Giannis A, Nikolaou A, Pentari D, Gidarakos E. Environ Pollut. 2009 Jul 14. [Epub ahead of print] PMID: 19608313 [PubMed - as supplied by publisher]

  • Induction of micronuclei and sister chromatid exchange in bone-marrow cells and abnormalities in sperm of Algerian mice (Mus spretus) exposed to cadmium, lead and zinc. Tapisso JT, Marques CC, Mathias MD, Ramalhinho MD. Mutat Res. 2009 Jul 13. [Epub ahead of print] PMID: 19607932 [PubMed - as supplied by publisher]

  • A Model Predicting Waterborne Cadmium Bioaccumulation in Gammarus pulex: The Effects of Dissolved Organic Ligands, Calcium, and Temperature. Pellet BJ, Geffard O, Lacour C, Kermoal T, Gourlay-Francé C, Tusseau-Vuillemin MH. Environ Toxicol Chem. 2009 Jul 16:1. [Epub ahead of print] PMID: 19606912 [PubMed - as supplied by publisher]

  • Cadmium tolerance in seven Daphnia magna clones is associated with reduced hsp70 baseline levels and induction. Haap T, Köhler HR. Aquat Toxicol. 2009 Jun 17. [Epub ahead of print] PMID: 19604586 [PubMed - as supplied by publisher]

  • Temporal variation of heavy metal contamination in fish of the river lot in southern France. Shinn C, Dauba F, Grenouillet G, Guenard G, Lek S. Ecotoxicol Environ Saf. 2009 Jul 13. [Epub ahead of print] PMID: 19604580 [PubMed - as supplied by publisher]

  • High Arctic Ponds Receiving Bio-Transported Nutrients from a Nearby Seabird Colony are also subject to Potentially Toxic Loadings of Arsenic, Cadmium, and Zinc. Brimble SK, Foster KL, Mallory ML, Macdonald RW, Smol JP, Blais JM. Environ Toxicol Chem. 2009 Jul 15:1. [Epub ahead of print] PMID: 19604032 [PubMed - as supplied by publisher]

  • Removal of nickel and cadmium from aqueous solutions by sewage sludge ash: study in single and binary systems. Elouear Z, Bouzid J, Boujelben N. Environ Technol. 2009 May;30(6):561-70. PMID: 19603703 [PubMed - in process]

  • Alterations of valve closing behavior in juvenile Catarina scallops (Argopecten ventricosus Sowerby, 1842) exposed to toxic metals. Sobrino-Figueroa A, Cáceres-Martínez C. Ecotoxicology. 2009 Jul 15. [Epub ahead of print] PMID: 19603269 [PubMed - as supplied by publisher]

  • Biochemical endpoints on juvenile Solea senegalensis exposed to estuarine sediments: the effect of contaminant mixtures on metallothionein and CYP1A induction. Costa PM, Caeiro S, Diniz MS, Lobo J, Martins M, Ferreira AM, Caetano M, Vale C, Delvalls TA, Costa MH. Ecotoxicology. 2009 Jul 15. [Epub ahead of print] PMID: 19603267 [PubMed - as supplied by publisher]

  • Biomonitoring the environmental impact of atmospheric emissions from the Avonmouth zinc smelter, United Kingdom. Sims I, Crane M, Johnson I, Credland P. Ecotoxicology. 2009 Jul 15. [Epub ahead of print] PMID: 19603266 [PubMed - as supplied by publisher]

  • Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia. Markovic M, Cupac S, Durovic R, Milinovic J, Kljajic P. Arch Environ Contam Toxicol. 2009 Jul 15. [Epub ahead of print] PMID: 19603130 [PubMed - as supplied by publisher]

  • Heavy metals and noise exposure: Health effects. Prasher D. Noise Health. 2009 Jul-Sep;11(44):141-4. PMID: 19602766 [PubMed - in process]

  • CzcP is a novel efflux system contributing to transition metal resistance in Cupriavidus metallidurans CH34. Scherer J, Nies DH. Mol Microbiol. 2009 Jul 7. [Epub ahead of print] PMID: 19602147 [PubMed - as supplied by publisher]

  • Phytoextraction of Pb and Cd by the Mediterranean saltbush (Atriplex halimus L.): metal uptake in relation to salinity. Manousaki E, Kalogerakis N. Environ Sci Pollut Res Int. 2009 Jul 14. [Epub ahead of print] PMID: 19597858 [PubMed - as supplied by publisher]

  • Content of Lead and Cadmium in Barred Hogfish, Bodianus scrofa, Island Grouper, Mycteroperca fusca, and Portuguese Dogfish, Centroscymnus coelolepis, from Canary Islands, Spain. Lozano G, Brito A, Hardisson A, Gutiérrez A, González-Weller D, Lozano IJ. Bull Environ Contam Toxicol. 2009 Jul 14. [Epub ahead of print] PMID: 19597713 [PubMed - as supplied by publisher]

  • Monolithic aerogels of silver modified cadmium sulfide colloids. Gill SK, Hope-Weeks LJ. Chem Commun (Camb). 2009 Aug 7;(29):4384-6. Epub 2009 Jun 11. PMID: 19597600 [PubMed - in process]

  • Molecular cloning and characterization of an ATP binding cassette (ABC) transmembrane transporter from the white shrimp Litopenaeus vannamei. Zhou J, He WY, Wang WN, Yang CW, Wang L, Xinl Y, Wu J, Cai DX, Liu Y, Wang AL. Comp Biochem Physiol C Toxicol Pharmacol. 2009 Jul 9. [Epub ahead of print] PMID: 19595789 [PubMed - as supplied by publisher]

 

 

 

 

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