SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 4)
Skin irritation (Category 2)
Serious eye damage (Category 1)

Signal word: Danger
Hazard statement(s):
Combustible liquid.
Causes skin irritation.
Causes serious eye damage.

Precautionary statement(s):
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wash skin thoroughly after handling.
Wear protective gloves/ eye protection/ face protection.
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
If skin irritation occurs: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
Store in a well-ventilated place. Keep cool.
Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) or not covered by GHS - none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Synonyms : 3-(Trimethoxysilyl)propylamine
Formula : C6H17NO3Si
Molecular weight : 179.29 g/mol
CAS-No. : 13822-56-5
EC-No. : 237-511-5

Hazardous components
Flammable Liquid: 4
Skin Irritation: 2
Eye Damage: 1

SECTION 4. FIRST AID MEASURES

General advice:
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact:
Wash off with soap and plenty of water. Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed:
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed:
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed:
No data available

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture:
Carbon oxides, Nitrogen oxides (NOx), silicon oxides

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.

Further information:
Use water spray to cool unopened containers.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.

Environmental precautions:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up:
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling:
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Storage class (TRGS 510): Combustible liquids

Specific end use(s):
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters:
Contains no substances with occupational exposure limit values.

Exposure controls
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Form: liquid
Colour: colourless
Odour: No data available
Odour Threshold: No data available
pH: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: 91 - 92 °C (196 - 198 °F) at 20 hPa (15 mmHg) - lit.
Flash point: 90 °C (194 °F) - closed cup
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Vapour pressure: No data available
Vapour density: No data available
Relative density: 1.027 g/cm3 at 25 °C (77 °F)
Water solubility: soluble
Partition coefficient: noctanol/water: No data available
Auto-ignition temperature: 295 °C (563 °F)
Decomposition temperature: No data available
Viscosity: No data available
Explosive properties: No data available
Oxidizing properties: No data available

Other safety information:
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity:
No data available

Chemical stability:
May decompose on exposure to moist air or water.
Stable under recommended storage conditions.

Possibility of hazardous reactions:
No data available

Conditions to avoid:
Heat, flames and sparks.

Incompatible materials:
Strong acids, Strong oxidizing agents, Water, Bases, Alcohols, Peroxides

Hazardous decomposition products:
Other decomposition products - No data available
In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity:
LD50 Oral - Rat - 2,970 mg/kg
Inhalation: No data available
LD50 Dermal - Rat - 11,300 mg/kg
(OECD Test Guideline 402)
No data available

Skin corrosion/irritation:
Skin - Rabbit
Result: Skin irritation
(OECD Test Guideline 404)

Serious eye damage/eye irritation:
No data available

Respiratory or skin sensitisation:
No data available

Germ cell mutagenicity:
No data available

Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

Reproductive toxicity:
No data available

Specific target organ toxicity - single exposure:
No data available
Specific target organ toxicity - repeated exposure:
No data available

Aspiration hazard:
No data available

Additional Information:
RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity:
No data available

Persistence and degradability:
No data available

Bioaccumulative potential:
No data available

Mobility in soil:
No data available

Results of PBT and vPvB assessment:
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects:
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Product:
This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging:
Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
NA-Number: 1993 Class: NONE Packing group: III
Proper shipping name: Combustible liquid, n.o.s. (3-(Trimethoxysilyl)propylamine)
Reportable Quantity (RQ):
Poison Inhalation Hazard: No

IMDG
Not dangerous goods

IATA
Not dangerous goods

SECTION 15. REGULATORY INFORMATION

SARA 302 Components:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards:
Fire Hazard, Acute Health Hazard

Massachusetts Right To Know Components:
No components are subject to the Massachusetts Right to Know Act

Pennsylvania Right To Know Components:
3-(Trimethoxysilyl)propylamine
CAS-No.
13822-56-5

New Jersey Right To Know Components:
3-(Trimethoxysilyl)propylamine
CAS-No.
13822-56-5

California Prop. 65 Components:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.