SECTION 2. HAZARDS IDENTIFICATION

Hazards description

Emergency Overview
OSHA Hazards: Toxic, Harmful
Information pertaining to particular dangers for mans and environment
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 43 May cause sensitization by skin contact
R 45 May cause cancer.
HMIS Classification: Health: 1; Flammability: 1; Reactivity: 1
NFPA Ratings: Health: 1; Flammability: 1; Reactivity: 1
Route of Exposure: Skin, Inhalation
Potential Health Effects
May cause cancer. Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Possible teratogen. Neurological hazard.
Target Organs: Respiratory system

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Description: Nickel(II) 1-dimethylamino-2-methyl-2-butoxide
Molecular Formula: C14H32N2O2Ni

SECTION 4. FIRST AID MEASURES

Eyes: In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
Skin: In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media:
Suitable: Carbon dioxide, dry chemical powder, or appropriate foam.
Products of Combustion: CO, CO2, NOx, Nickel/Nickel oxide
Special Protective Equipment for Fire-Fighters: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Flash Point: Not available
Flammable Limits: Not available
Auto-Ignition Temperature: Not available.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Spill: Evacuate area.
Personal Precautions: Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.

SECTION 7. HANDLING AND STORAGE

Handling
Do not breathe dust. Avoid all contact. Avoid prolonged or repeated exposure.
Storage
Keep container tightly closed in a dry and well-ventilated place. Store in cool place.
Special Requirements
Hygroscopic.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls
Safety shower and eye bath. Use only in a chemical fume hood.
Personal Protective Equipment
Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
General Hygiene Measures
Wash thoroughly after handling. Discard contaminated clothing and shoes.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Dark green liquid
Molecular Weight: 319.13 g/mol
Melting Point: Not available
Boiling Point: 148℃ (298.4℉) at 3.32 torr
Flash Point: Not available
Volatility: Not available
Liquid Density: Not available
Vapor Pressure: 0.1 torr at 80℃
Solubility in water: React
Vapor Density: Not available
n-octanol/water Partition Coefficient: Not available
pH (1% soln/water): N/A

SECTION 10. STABILITY AND REACTIVITY

Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Moisture
Materials to Avoid: Strong oxidizing agents. Hazardous Decomposition Products: CO, CO2, NOx, Nickel/Nickel oxides
Hazardous Polymerization: Has not been reported.

SECTION 11. TOXICOLOGICAL INFORMATION

Route of Exposure
Skin Contact: Irritation
Eye Contact: Irritation
Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity: No information available.
Bioaccumulation: No information available.
Biodegredation: No information available.
Environmental Stability: No information available

SECTION 13. DISPOSAL CONSIDERATIONS

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accuate classification.

SECTION 14. TRANSPORT INFORMATION

UN No: 3398
CLASS: 4.3
Packing Group: Packing Group II
Proper Shipping Name: Organometallic substance, liquid, water-reactive
(Nickel(II) 1-dimethylamino-2-methyl-2-butoxide)

SECTION 15. REGULATORY INFORMATION

OSHA Hazards
Toxic
Product related hazard information:
Hazard symbols:
T Toxic
Risk phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 42/43 May cause sensitization by inhalation and skin contact.
R 45 May cause cancer.
Safety phrases:
S 24 Avoid contact with the skin.
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).