CAS No. 12031-82-2

Chemical Identifiers

Linear Formula Li2TiO3
Pubchem CID 6093646
MDL Number MFCD00016181
EC No. 234-759-6
IUPAC Name dilithium; dioxido(oxo) titanium
Beilstein/Reaxys No. N/A
SMILES [Li+].[Li+].[O-][Ti]([O-])=O
InchI Identifier InChI=1S/2Li.3O.Ti/q2*+1;;2*-1;
InchI Key GLUCAHCCJMJHGV-UHFFFAOYSA-N

Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #12031-82-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
The substance is not classified according to the Globally Harmonized System (GHS).
Hazards not otherwise classified No data available
GHS label elements N/A
Hazard pictograms N/A
Signal word N/A
Hazard statements N/A
WHMIS classification Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1


Health (acute effects) = 1
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
12031-82-2 Lithium titanium oxide
Identification number(s):
EC number: 234-759-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released:
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup: Pick up mechanically.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Off-white
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 1520-1564 °C (2768-2847 °F)
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: N/A
Flammability (solid, gas) Product is not flammable.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density: No data available
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: No effects known.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Titanium and titanium compounds are considered physiologically inert. There are no reported cases in the literature where titanium as such has caused human
intoxication.
Large amounts of lithium compounds may cause vomiting, diarrhea, ataxia, intestinal irritation, kidney injury, central nervous system depression and a drop in blood
pressure. Central nervous system effects may include slurred speech, blurred vision, dizziness, sensory loss, convulsions and stupor. Chronic intake may cause
neuromuscular effects such as tremor, ataxia, weakness, clonus and hyperactive reflexes. Lithium can cause kidney damage, gastrointestinal disturbances, fatigue,
dehydration, weight loss, dermatological effects and thyroid damage. Lithium ion has shown teratogenic effects in rats and mice.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

13 Disposal considerations
Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

Not a hazardous material for transportation.
UN-Number
DOT, IMDG, IATA None
UN proper shipping name
DOT, IMDG, IATA None
Transport hazard class(es)
DOT, ADR, IMDG, IATA
Class None
Packing group
DOT, IMDG, IATA None
Environmental hazards: N/A
Special precautions for user N/A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information: Not dangerous according to the above specifications.
DOT
Marine Pollutant (DOT): No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements N/A
Hazard pictograms N/A
Signal word N/A
Hazard statements N/A
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Niobium doped lithium titanate as a high rate anode material for Li-ion batteries. Tian B, Xiang H, Zhang L, Li Z, Wang H. Electrochimica Acta. 2010 Jul 30;55(19):5453-8.
  • Thermogravimetric study of the kinetics of lithium titanate reduction by hydrogen. Sagar Sonak, R. Rakesh, Uttam Jain, Abhishek Mukherjee, Nagaiyar Krishnamurthy. Fusion Engineering and Design, Volume 89, Issue 11, November 2014, Pages 2738-2742.
  • Self-supporting lithium titanate nanorod/carbon nanotube/reduced graphene oxide flexible electrode for high performance hybrid lithium-ion capacitor. Xing Li, Yao Tang, Junhua Song, Mingshan Wang, Jianming Zheng. Journal of Alloys and Compounds, Volume 790, 25 June 2019, Pages 1157-1166.
  • Crystal growth and structure refinement of monoclinic Li2TiO3. Kataoka K, Takahashi Y, Kijima N, Nagai H, Akimoto J, Idemoto Y, Ohshima KI. Materials Research Bulletin. 2009 Jan 8;44(1):168-72.
  • Electrical conductivity of Li2TiO3 ceramics. Fehr T, Schmidbauer E. Solid State Ionics. 2007 Jan 31;178(1-2):35-41.
  • Single step synthesis of Li2TiO3 powder. Sinha A, Nair SR, Sinha PK. Journal of Nuclear Materials. 2010 Apr 30;399(2-3):162-6.
  • Sol–gel synthesis and sintering of nano-size Li2TiO3 powder. Wu X, Wen Z, Lin B, Xu X. Materials Letters. 2008 Mar 15;62(6-7):837-9.
  • Point defects and non-stoichiometry in Li2TiO3. Murphy ST, Hine ND. Chemistry of Materials. 2014 Feb 3;26(4):1629-38.
  • Chemical compatibility between ARAA alloy and lithium meta-titanate breeder material. Seungyon Cho, Yi-Hyun Park, Young-Bum Chun, Kyung-Mi Min, Youngmin Lee. Fusion Engineering and Design, Volume 124, November 2017, Pages 1052-1058.