SECTION 2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin Corrosion/irritation:
Category 2
Serious Eye Damage/Eye Irritation:
Category 2
Specific target organ toxicity (single exposure):
Category 3
Target Organs:
Respiratory system.
Label Elements
Signal Word: Warning
Pictogram
GHS07
Hazard Statements:
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Precautionary Statements
Prevention:
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Inhalation:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin:
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Storage:
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal:
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC):
None identified
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component:
Copper(I) hexafluoro-2,4-pentanedionate
1,5-cyclooctadiene complex
CAS-No:
86233-74-1
Weight:
< 100%
SECTION 4. FIRST AID MEASURES
General Advice:
If symptoms persist, call a physician.
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation:
Move to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Notes to Physician:
Treat symptomatically
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Most important symptoms and effects:
None reasonably foreseeable.
SECTION 5. FIREFIGHTING MEASURES
Unsuitable Extinguishing Media: No information available
Flash Point: No information available
Method: No information available
Autoignition Temperature: No information available
Explosion Limits
Upper: No data available
Lower: No data available
Sensitivity to Mechanical Impact: No information available
Sensitivity to Static Discharge: No information available
Specific Hazards Arising from the Chemical:
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products:
None known
Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health: 2
Flammability: 1
Instability: 0
Physical Hazards: -
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation.
Environmental Precautions:
Should not be released into the environment. See Section 12 for additional ecological information.
Methods for Containment and Clean Up:
Keep in suitable, closed containers for disposal. Sweep up or vacuum up spillage and collect in suitable container for disposal.
SECTION 7. HANDLING AND STORAGE
Handling:
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.
Storage:
Keep containers tightly closed in a dry, cool and well-ventilated place.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.
Engineering Measures:
Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection:
Long sleeved clothing.
Respiratory Protection:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Appearance: Yellow
Odor: Odorless
Odor Threshold: No information available
pH: No information available
Melting Point/Range: 93 - 100 °C / 199.4 - 212 °F
Boiling Point/Range: 60 °C / 140 °F
Flash Point: No information available
Evaporation Rate: Not applicable
Flammability (solid,gas): No information available
Flammability or explosive limits
Upper: No data available
Lower: No data available
Vapor Pressure: No information available
Vapor Density: Not applicable
Specific Gravity: No information available
Solubility: No information available
Partition coefficient; n-octanol/water: No data available
Autoignition Temperature: No information available
Decomposition Temperature: No information available
Viscosity: Not applicable
SECTION 10. STABILITY AND REACTIVITY
Reactive Hazard:
None known, based on information available
Stability:
Stable under normal conditions.
Conditions to Avoid:
Incompatible products.
Incompatible Materials:
Strong oxidizing agents
Hazardous Decomposition Products:
None under normal use conditions
Hazardous Polymerization:
Hazardous polymerization does not occur.
Hazardous Reactions:
None under normal processing.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information:
Component Information:
Toxicologically Synergistic: No information available
Products:
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation: No information available
Sensitization: No information available
Carcinogenicity:
Component: Copper(I) hexafluoro-2,4-pentanedionate 1,5-cyclooctadiene complex
CAS-No: 86233-74-1
IARC: Not listed
NTP: Not listed
ACGIH: Not listed
OSHA: Not listed
Mexico: Not listed
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
STOT - single exposure: Respiratory system
STOT - repeated exposure: None known
Aspiration hazard: No information available
Symptoms / effects,both acute and delayed: No information available
Endocrine Disruptor Information: No information available
Other Adverse Effects: The toxicological properties have not been fully investigated.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Do not empty into drains.
Persistence and Degradability: Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its volatility.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
SECTION 14. TRANSPORT INFORMATION
DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
SECTION 15. REGULATORY INFORMATION
All of the components in the product are on the following Inventory lists:
X = listed
International Inventories
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b): Not applicable
SARA 313: Not applicable
SARA 311/312: Hazard Categories See section 2 for more information
CWA (Clean Water Act): Not applicable
Clean Air Act: Not applicable
OSHA: Not applicable
CERCLA: Not applicable
California Proposition 65: This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations: Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant: N
DOT Severe Marine Pollutant: N
U.S. Department of Homeland Security:
This product does not contain any DHS chemicals
Other International Regulations:
Mexico - Grade No information available
