Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes.

Title Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes.
Authors T.P. Latendresse; V. Vieru; B.O. Wilkins; N.S. Bhuvanesh; L.F. Chibotaru; M. Nippe
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201804075
Abstract

A rare example of an organometallic terbium single-ion magnet is reported. A Tb -[1]ferrocenophane complex displays a larger barrier to magnetization reversal than its isostructural Dy analogue, which is reminiscent of trends observed for lanthanide-bis-phthalocyanine complexes. Detailed ab?initio calculations support the experimental observations and suggest a significantly larger ground-state stabilization for the non-Kramers ion Tb in the Tb complex than for the Kramers-ion Dy in the Dy complex.

Citation T.P. Latendresse; V. Vieru; B.O. Wilkins; N.S. Bhuvanesh; L.F. Chibotaru; M. Nippe.Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes.. Angew Chem Int Ed Engl. 2018;57(27):81648169. doi:10.1002/anie.201804075

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