Preparation and reactivity of a square-planar PNP cobalt(ii)-hydrido complex: isolation of the first {Co-NO}8-hydride.

Title Preparation and reactivity of a square-planar PNP cobalt(ii)-hydrido complex: isolation of the first {Co-NO}8-hydride.
Authors M. Krishnan; H.D. Arman; Z.J. Tonzetich
Journal Dalton Trans
DOI 10.1039/c7dt04339b
Abstract

The synthesis of a square-planar cobalt(ii) hydrido complex supported by a pyrrole-based PNP ligand has been reinvestigated and its reactivity with various small molecules examined. Preparation of the complex was accomplished by treatment of the corresponding chloride complex, [CoCl(tBuPNP)] (tBuPNP = anion of 2,5-bis((di-tert-butylphosphino)methyl)pyrrole), with di-iso-butylaluminum hydride (DIBAL). Reaction of [CoCl(tBuPNP)] with other hydride sources such as NaEt3BH and LiAlH4 resulted in mixtures of the desired Co(ii) hydride along with the reduced Co(i) species, [Co(N2)(tBuPNP)], as the primary product. The hydride complex exhibits facile migratory insertion chemistry with CO2 producing the corresponding Co(ii) formate complex. When the Co-H complex is reacted with nitric oxide, the first example of a cobalt nitrosyl hydride complex is produced.

Citation M. Krishnan; H.D. Arman; Z.J. Tonzetich.Preparation and reactivity of a square-planar PNP cobalt(ii)-hydrido complex: isolation of the first {Co-NO}8-hydride.. Dalton Trans. 2017. doi:10.1039/c7dt04339b

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

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