Single-Site Osmium Catalysts on MgO: Reactivity and Catalysis of CO Oxidation.

Title Single-Site Osmium Catalysts on MgO: Reactivity and Catalysis of CO Oxidation.
Authors D. Yang; S. Zhang; P. Xu; N.D. Browning; D.A. Dixon; B.C. Gates
Journal Chemistry
DOI 10.1002/chem.201605131
Abstract

MgO-supported osmium dioxo species, described as Os(=O)2 {-Osupport }1?or?2 (the brackets denote O atoms of the MgO surface), formed from Os3 (CO)12 via supported Os(CO)2 , and characterized by spectroscopy, microscopy, and theory, react with ethylene at 298?K to form osmium glycol species or with CO to give osmium mono- and di-carbonyls. Os(=O)2 {-Osupport }1?or?2 is the precursor of a CO oxidation catalyst characterized by a turnover frequency of 4.0×10(-3) (molecules of CO)/(Os atom×s) at 473?K; the active species are inferred to be osmium monocarbonyls. The structures and frequencies calculated at the level of density functional theory with the B3LYP functional bolster the experimental results and facilitate structural assignments. The lowest-energy structures have various osmium oxidation and spin states. The results demonstrate not only new chemistry of the supported single-site catalysts but also their complexity and the value of complementary techniques used in concert to unravel the chemistry.

Citation D. Yang; S. Zhang; P. Xu; N.D. Browning; D.A. Dixon; B.C. Gates.Single-Site Osmium Catalysts on MgO: Reactivity and Catalysis of CO Oxidation.. Chemistry. 2017;23(11):25322536. doi:10.1002/chem.201605131

Related Elements

Osmium

See more Osmium products. Osmium (atomic symbol: Os, atomic number: 76) is a Block D, Group 8, Period 6 element with an atomic weight of 190.23. Osmium Bohr ModelThe number of electrons in each of osmium's shells is [2, 8, 18, 32, 14, 2] and its electron configuration is [Xe] 4f14 5d6 6s2. The osmium atom has a radius of 135 pm and a Van der Waals radius of 216 pm. Osmium was discovered and first isolated by Smithson Tennant in 1803. Elemental OsmiumIn its elemental form, osmium has a silvery blue cast apperance. Osmium has the highest melting point and the lowest vapor pressure of any of the platinum group of metals it is also the densest naturally ocurring element. Osmium is the least abundant stable element in the earth's crust. It is found in the alloys osmiridium and iridiosmium and as a free element. The origin of the name Osmium comes from the Greek word osme, meaning a smell or odor.

Magnesium

Magnesium Bohr ModelSee more Magnesium products. Magnesium (atomic symbol: Mg, atomic number: 12) is a Block S, Group 2, Period 3 element with an atomic mass of 24.3050. The number of electrons in each of Magnesium's shells is [2, 8, 2] and its electron configuration is [Ne] 3s2. The magnesium atom has a radius of 160 pm and a Van der Waals radius of 173 pm. Magnesium was discovered by Joseph Black in 1775 and first isolated by Sir Humphrey Davy in 1808. Magnesium is the eighth most abundant element in the earth's crust and the fourth most common element in the earth as a whole. Elemental MagnesiumIn its elemental form, magnesium has a shiny grey metallic appearance and is an extremely reactive. It is can be found in minerals such as brucite, carnallite, dolomite, magnesite, olivine and talc. Commercially, magnesium is primarily used in the creation of strong and lightweight aluminum-magnesium alloys, which have numerous advantages in industrial applications. The name "Magnesium" originates from a Greek district in Thessaly called Magnesia.

Related Forms & Applications