Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties.

Title Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties.
Authors M. Ma; C. Li; D. Shu; C. Wang; P. Xi
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.09.009
Abstract

A photoluminescent terbium (Tb) complex involving a novel benzoic-acid compound with a unique coordinated structure, namely 1,4-bis(carbonylmethyl)terephthalate (BCMT), has been designed and synthesized. The new coordinate structure and energy-transfer mechanism between the ligand and Tb(III) ions were investigated in detail. The results demonstrated that the BCMT-Tb(III) complex shows strong fluorescence intensity (4×106a.u.) and long fluorescence lifetime (1.302ms), owing to the favorable degree of energy matching between the triplet excited level of the ligand and the resonant level of Tb(III) ions. Based on the analysis of three-dimensional luminescence spectra, the as-prepared Tb(III) complex can be effectively excited in the range of 250-310nm, and it shows high color purity, with a bright green appearance.

Citation M. Ma; C. Li; D. Shu; C. Wang; P. Xi.Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate: Structure and luminescence properties.. Spectrochim Acta A Mol Biomol Spectrosc. 2018;190:6875. doi:10.1016/j.saa.2017.09.009

Related Elements

Terbium

See more Terbium products. Terbium (atomic symbol: Tb, atomic number: 65) is a Block F, Group 3, Period 6 element with an atomic radius of 158.92535.Terbium Bohr Model The number of electrons in each of Terbium's shells is [2, 8, 18, 27, 8, 2] and its electron configuration is [Xe]4f9 6s2. The terbium atom has a radius of 177 pm and a Van der Waals radius of 221 pm.Terbium was discovered and first isolated by Carl Gustaf Mosander in 1842. In its elemental form, terbium is a silvery-white soft metal. Terbium is found in cerite, gadolinite, and monazite. It is not found in nature as a free element. Elemental TerbiumTerbium compounds are brightly fluorescent, and a majority of the world's terbium supply is used for creating green phosphors that enable trichromatic lighting technology. It is also frequently used as a dopant for crystalline solid-state devices and fuel cell materials. It is named after Ytterby, the town in Sweden where it was discovered.

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