Lutetium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.
Lutetium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Lutetium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Lutetium is a Block F, Group 3, Period 6 element. The number of electrons in each of Lutetium's shells is 2, 8, 18, 32, 9, 2 and its electronic configuration is [Xe] 4f15 5d1 6s2. In its elemental form lutetium's CAS number is 7439-94-3. The lutetium atom has a radius of 171.8.pm and it's Van der Waals radius is unknown. Lutetium is not toxic. Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth.
All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, thin fillm deposition using sputtering targets and evaporation materials, metallurgy and optical materials and other high technology applications. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Lutetium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Lutetium was first discovered by George Urbain in 1907.
The name Lutetium originates from the Latin word Lutetia meaning Paris.
lutécium |
Lutetium |
lutezio |
Lutécio |
lutecio |
Lutetium |
Lutetium Abundance. The following table shows the abundance of Lutetium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
| Isotope |
Atomic Mass |
% Abundance on Earth |
| Lu-175 |
174.941 |
97.41 |
| Lu-176 |
175.943 |
2.59 |
The following table shows the abundance of Lutetium present in the human body and in the universe scaled to parts per billion (ppb) by weight and by atom:
| |
Typical Human Body |
Universe |
| by Weight |
no data |
0.1 ppb |
| by Atom |
no data |
0.001 ppb |
Lutetium Safety Data and Biological Role. The safety data for Lutetium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin. Lutetium compounds have no biological role.
Ionization Energy. The ionization energy for Lutetium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
| 1st Ionization Energy |
523.52 kJ mol-1 |
| 2nd Ionization Energy |
1341.16 kJ mol-1 |
| 3rd Ionization Energy |
2022.29 kJ mol-1 |
Conductivity. As to Lutetium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 şC is 79 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1. The thermal conductivity of Lutetium is 16.4 W m-1 K-1.
Thermal Properties of Lutetium. The melting point and boiling point for Lutetium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
| Heat of Fusion |
19.2 kJ mol-1 |
| Heat of Vaporization |
428 kJ mol-1 |
| Heat of Atomization |
427.37 kJ mol-1 |
Recent Research & Development for Lutetium
Use of internal scintillator radioactivity to calibrate DOI function of a PET detector with a dual-ended-scintillator readout.
Bircher C, Shao Y.
Med Phys. 2012 Feb;39(2):777.
PMID:
22320787
[PubMed - in process]
Phthalocyanine with a giant dielectric constant.
Yazici A, Unüs N, Altindal A, Salih B, Bekaroglu O.
Dalton Trans. 2012 Feb 7. [Epub ahead of print]
PMID:
22310939
[PubMed - as supplied by publisher]
Towards the Real Octupolar Cube: ABAB Bis(phthalocyaninato)lutetium(III) Complex exhibiting Out-standing Quadratic Hyperpolarizability.
Ayhan MM, Singh A, Hirel C, Gürek AG, Ahsen V, Jeanneau E, Ledoux-Rak I, Zyss J, Andraud C, Bretonničre Y.
J Am Chem Soc. 2012 Feb 6. [Epub ahead of print]
PMID:
22308960
[PubMed - as supplied by publisher]
Rare-Earth-Metal-Hydrocarbyl Complexes Bearing Linked Cyclopentadienyl or Fluorenyl Ligands: Synthesis, Catalyzed Styrene Polymerization, and Structure-Reactivity Relationship.
Jian Z, Cui D, Hou Z.
Chemistry. 2012 Jan 26. doi: 10.1002/chem.201102682. [Epub ahead of print]
PMID:
22282393
[PubMed - as supplied by publisher]
Outpatient therapeutic nuclear oncology.
Turner JH.
Ann Nucl Med. 2012 Jan 7. [Epub ahead of print]
PMID:
22222779
[PubMed - as supplied by publisher]
Poly[tetra-aquadi-µ(4)-oxalato-lutetium(III)potassium].
Zhang FM, Sun TZ, Hou GF, Yan PF, Li GM.
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):m1591. Epub 2011 Oct 22.
PMID:
22219822
[PubMed - in process]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Nuclear chemical transformations of ytterbium and lutetium radionuclides following (n,?) and beta decay reactions in Tris(2,2,6,6-tetramethyle-3,5-heptanedionato)Yb(III).
Nassan L, Achkar B, Yassine T.
Appl Radiat Isot. 2011 Dec 6. [Epub ahead of print]
PMID:
22189373
[PubMed - as supplied by publisher]
Influence of cations on the complexation yield of DOTATATE with yttrium and lutetium: a perspective study for enhancing the (90)Y and (177)Lu labeling conditions.
Asti M, Tegoni M, Farioli D, Iori M, Guidotti C, Cutler CS, Mayer P, Versari A, Salvo D.
Nucl Med Biol. 2011 Dec 13. [Epub ahead of print]
PMID:
22172388
[PubMed - as supplied by publisher]
A novel compensation method for the anode gain non-uniformity of multi-anode photomultiplier tubes.
Lee CM, Il Kwon S, Ko GB, Ito M, Yoon HS, Lee DS, Hong SJ, Lee JS.
Phys Med Biol. 2012 Jan 7;57(1):191-207.
PMID:
22156011
[PubMed - in process]
Automated Module Radiolabeling of Peptides and Antibodies with Gallium-68, Lutetium-177 and Iodine-131.
De Decker M, Turner JH.
Cancer Biother Radiopharm. 2011 Dec 7. [Epub ahead of print]
PMID:
22149590
[PubMed - as supplied by publisher]
An unusual organoyttrium alkyl complex containing a [C5HMe3(?(3)-CH2)-C5H4N-?]- ligand and an elusive cyclopentadienide-based scandium tuck-over zwitterion obtained by C-H bond activation.
Jian Z, Cui D.
Chemistry. 2011 Dec 16;17(51):14578-85. doi: 10.1002/chem.201102378. Epub 2011 Nov 14.
PMID:
22083978
[PubMed - in process]
Evaluation of 177Lu-DOTA-sst2 antagonist versus 177Lu-DOTA-sst2 agonist binding in human cancers in vitro.
Cescato R, Waser B, Fani M, Reubi JC.
J Nucl Med. 2011 Dec;52(12):1886-90. Epub 2011 Nov 8.
PMID:
22068898
[PubMed - indexed for MEDLINE]
Reactions of late lanthanide metal atoms and methanol in solid argon: a matrix isolation infrared spectroscopic and theoretical study.
Gong Y, Andrews L, Chen M, Dixon DA.
J Phys Chem A. 2011 Dec 29;115(51):14581-92. Epub 2011 Dec 5.
PMID:
22054215
[PubMed - in process]
Nuclear medicine techniques for the imaging and treatment of neuroendocrine tumours.
Teunissen JJ, Kwekkeboom DJ, Valkema R, Krenning EP.
Endocr Relat Cancer. 2011 Oct 17;18 Suppl 1:S27-51. Print 2011 Oct. Review.
PMID:
22005114
[PubMed - indexed for MEDLINE]
A Positron Emission Tomograph Based on LSO-APD Modules with a Sampling ADC Read-out System for a Students' Advanced Laboratory Course.
Schneider FR, Mann AB, Konorov I, Delso G, Paul S, Ziegler SI.
Z Med Phys. 2011 Oct 20. [Epub ahead of print]
PMID:
22019183
[PubMed - as supplied by publisher]
Preparation and scintillating properties of sol-gel eu, tb co-doped lu(2)o(3) nanopowders.
de Jesús Morales Ramírez A, Murillo AG, de Jesús Carrillo Romo F, Hernández MG, Palmerin JM, Guerrero RR.
Int J Mol Sci. 2011;12(9):6240-54. Epub 2011 Sep 23.
PMID:
22016655
[PubMed - in process]
Timing and optimized acquisition parameters for the whole-body imaging of ą77Lu-EDTMP toward performing bone pain palliation treatment.
Liu C, Brašic JR, Liu X, Li H, Xiang X, Luo Z, Wang Y, Kuai D, Zhang G, Zaknun JJ.
Nucl Med Commun. 2012 Jan;33(1):90-6.
PMID:
22001721
[PubMed - in process]
Physical performance of the new hybrid PET/CT Discovery-690.
Bettinardi V, Presotto L, Rapisarda E, Picchio M, Gianolli L, Gilardi MC.
Med Phys. 2011 Oct;38(10):5394-411.
PMID:
21992359
[PubMed - indexed for MEDLINE]
Dihydrogen addition in a dinuclear rare-earth metal hydride complex supported by a metalated TREN ligand.
Venugopal A, Fegler W, Spaniol TP, Maron L, Okuda J.
J Am Chem Soc. 2011 Nov 9;133(44):17574-7. Epub 2011 Oct 18. |