A Terminal Fluoride Ligand Generates Highly Axial Magnetic Anisotropy in Dysprosium Complexes.

Title A Terminal Fluoride Ligand Generates Highly Axial Magnetic Anisotropy in Dysprosium Complexes.
Authors L. Norel; L.Elizabeth Darago; B. le Guennic; K. Chakarawet; M.Carlos Gonzalez; J.H. Olshansky; S. Rigaut; J.R. Long
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201712139
Abstract

The first dysprosium complexes with a terminal fluoride ligand are obtained as air-stable compounds. The strong, highly electrostatic dysprosium-fluoride bond generates a large axial crystal field splitting of the J = 15/2 ground state, as evidenced by high-resolution luminescence spectroscopy and correlated with the single-molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.

Citation L. Norel; L.Elizabeth Darago; B. le Guennic; K. Chakarawet; M.Carlos Gonzalez; J.H. Olshansky; S. Rigaut; J.R. Long.A Terminal Fluoride Ligand Generates Highly Axial Magnetic Anisotropy in Dysprosium Complexes.. Angew Chem Int Ed Engl. 2017. doi:10.1002/anie.201712139

Related Elements

Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.

Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

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