Burgess iridium(I)-catalyst for selective hydrogen isotope exchange.

Title Burgess iridium(I)-catalyst for selective hydrogen isotope exchange.
Authors A. Burhop; R. Prohaska; R. Weck; J. Atzrodt; V. Derdau
Journal J Labelled Comp Radiopharm
DOI 10.1002/jlcr.3512
Abstract We have evaluated the commercially available Burgess catalyst in hydrogen isotope exchange reactions with several substrates bearing different directing group functionalities and have obtained moderate to high (50%-97%D) deuterium incorporations. The broad applicability in hydrogen isotope exchange reactions makes the Burgess catalyst a possible alternative compared to other commercially available iridium(I)-catalysts.
Citation A. Burhop; R. Prohaska; R. Weck; J. Atzrodt; V. Derdau.Burgess iridium(I)-catalyst for selective hydrogen isotope exchange.. J Labelled Comp Radiopharm. 2017;60(7):343348. doi:10.1002/jlcr.3512

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Iridium

See more Iridium products. Iridium (atomic symbol: Ir, atomic number: 77) is a Block D, Group 9, Period 6 element with an atomic weight of 192.217. The number of electrons in each of iridium's shells is [2, 8, 18, 32, 15, 2] and its electron configuration is [Xe] 4f14 5d7 6s2. Iridium Bohr ModelThe iridium atom has a radius of 136 pm and a Van der Waals radius of 202 pm. Iridium was discovered and first isolated by Smithson Tennant in 1803. In its elemental form, Iridium has a silvery white appearance. Iridium is a member of the platinum group of metals.Elemental Iridium It is the most corrosion resistant metal known and is the second-densest element (after osmium). It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. Iridium is found as an uncombined element and in iridium-osmium alloys. Iridium's name is derived from the Greek goddess Iris, personification of the rainbow, on account of the striking and diverse colors of its salts.

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