Fe5Mo Cluster with Iron-Carbide and Molybdenum-Carbide Bonding Motifs: Structure and Selective Alkyne Reductions.

Title Fe5Mo Cluster with Iron-Carbide and Molybdenum-Carbide Bonding Motifs: Structure and Selective Alkyne Reductions.
Authors C. Joseph; S. Kuppuswamy; V.M. Lynch; M.J. Rose
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b02615
Abstract

Herein we report the synthesis, X-ray structure, and characterization of the title pentairon (molybdo)carbido cluster. The reaction of the pentairon (?5-carbido) dianion [Fe5(?6-C)(?2-CO)2(CO)12]2- (1) with [Mo(CO)3(chpt)] (chpt = cycloheptatriene) forms the heterohexanuclear cluster [K(benzo-18-crown-6)]2[Fe5Mo(?6-C)(?2-CO)3(CO)14] (2). The dianion exhibits a Fe5Mo(?6-C) core structure supported by three bridging (?CO = 1788 cm-1) and terminal (?CO = 1943 cm-1) CO ligands. Cluster 2 provides the selective reduction of diphenylacetylene to cis-diphenylethylene via a spectroscopically observed cluster-hydride intermediate (1H NMR: ? -26).

Citation C. Joseph; S. Kuppuswamy; V.M. Lynch; M.J. Rose.Fe5Mo Cluster with Iron-Carbide and Molybdenum-Carbide Bonding Motifs: Structure and Selective Alkyne Reductions.. Inorg Chem. 2018;57(1):2023. doi:10.1021/acs.inorgchem.7b02615

Related Elements

Iron

See more Iron products. Iron (atomic symbol: Fe, atomic number: 26) is a Block D, Group 8, Period 4 element with an atomic weight of 55.845. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electron configuration is [Ar] 3d6 4s2. Iron Bohr ModelThe iron atom has a radius of 126 pm and a Van der Waals radius of 194 pm. Iron was discovered by humans before 5000 BC. In its elemental form, iron has a lustrous grayish metallic appearance. Iron is the fourth most common element in the Earth's crust and the most common element by mass forming the earth as a whole. Iron is rarely found as a free element, since it tends to oxidize easily; it is usually found in minerals such as magnetite, hematite, goethite, limonite, or siderite.Elemental Iron Though pure iron is typically soft, the addition of carbon creates the alloy known as steel, which is significantly stronger.

Molybdenum

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