Improving barium ion adsorption on two-dimensional titanium carbide by surface modification.

Title Improving barium ion adsorption on two-dimensional titanium carbide by surface modification.
Authors W. Mu; S. Du; Q. Yu; X. Li; H. Wei; Y. Yang
Journal Dalton Trans
DOI 10.1039/c8dt00917a
Abstract

Recently, 2D-MXene materials have attracted much attention. However, their low adsorption capacities for metal ions have limited their application in nuclear wastewater disposal. Here, we describe the unprecedentedly high adsorption by Ti3C2Tx for the removal of radionuclides by a simple and efficient surface modification strategy. We have produced an Alk-Ti3C2Tx material possessing desirable properties such as wide layer spacing and abundant active adsorption sites, with excellent ability to remove barium ions from aqueous solution. Maximum Ba2+ adsorption by Alk-Ti3C2Tx is 46.46 mg g-1, almost three times higher than that of unmodified Ti3C2Tx and much higher than that reported in previous studies. The remarkable selectivity for the removal of Ba2+ from simulated mixed nuclear wastewater is highly desirable for application in environmental wastewater treatment.

Citation W. Mu; S. Du; Q. Yu; X. Li; H. Wei; Y. Yang.Improving barium ion adsorption on two-dimensional titanium carbide by surface modification.. Dalton Trans. 2018. doi:10.1039/c8dt00917a

Related Elements

Barium

See more Barium products. Barium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental BariumIn its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getter," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum in load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4); it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy.

Titanium

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

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