Large Piezoelectric Strain with Superior Thermal Stability and Excellent Fatigue Resistance of Lead-free Potassium Sodium Niobate-Based Grain Orientation-Controlled Ceramics.

Title Large Piezoelectric Strain with Superior Thermal Stability and Excellent Fatigue Resistance of Lead-free Potassium Sodium Niobate-Based Grain Orientation-Controlled Ceramics.
Authors Y. Quan; W. Ren; G. Niu; L. Wang; J.Yan Zhao; N. Zhang; M. Liu; Z.G. Ye; L. Liu; T. Karakit
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.8b01554
Abstract

Environment-friendly lead-free piezoelectric materials with high piezoelectric response which is stable in a wide temperature range are urgently needed for various applications. In this work, grain orientation-controlled (with a 90% <001>c-oriented texture) (K,Na)NbO3 (KNN)-based ceramics with large piezoelectric response (d33*) = 505 pm V-1 and a high Curie temperature (TC) of 247 oC have been developed. Such a high d33* value varies by less than 5% from 30 oC to 180 oC, showing a superior thermal stability. Furthermore, the high piezoelectricity exhibits an excellent fatigue resistance with the d33* value decreasing within only by 6% at a field of 20 kV cm-1 up to 107 cycles. These exceptional properties can be attributed to the vertical morphotropic phase boundary (MPB) and the highly <001>c-oriented textured ceramic microstructure. These results open a pathway to promote lead-free piezoelectric ceramics as a viable alternative to lead-based piezoceramics for various practical applications, such as actuators, transducers, sensors and acoustic devices in a wide temperature range.

Citation Y. Quan; W. Ren; G. Niu; L. Wang; J.Yan Zhao; N. Zhang; M. Liu; Z.G. Ye; L. Liu; T. Karakit.Large Piezoelectric Strain with Superior Thermal Stability and Excellent Fatigue Resistance of Lead-free Potassium Sodium Niobate-Based Grain Orientation-Controlled Ceramics.. ACS Appl Mater Interfaces. 2018. doi:10.1021/acsami.8b01554

Related Elements

Niobium

See more Niobium products. Niobium (atomic symbol: Nb, atomic number: 41) is a Block D, Group 5, Period 5 element with an atomic weight of 92.90638. Niobium Bohr ModelThe number of electrons in each of niobium's shells is 2, 8, 18, 12, 1 and its electron configuration is [Kr] 4d4 5s1. The niobium atom has a radius of 146 pm and a Van der Waals radius of 207 pm. Niobium was discovered by Charles Hatchett in 1801 and first isolated by Christian Wilhelm Blomstrand in 1864. In its elemental form, niobium has a gray metallic appearance. Niobium has the largest magnetic penetration depth of any element and is one of three elemental type-II superconductors (Elemental Niobiumalong with vanadium and technetium). Niobium is found in the minerals pyrochlore, its main commercial source, and columbite. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus.

Potassium

Elemental PotassiumSee more Potassium products. Potassium (atomic symbol: K, atomic number: 19) is a Block S, Group 1, Period 4 element with an atomic weight of 39.0983. The number of electrons in each of Potassium's shells is [2, 8, 8, 1] and its electron configuration is [Ar] 4s1. The potassium atom has a radius of 227.2 pm and a Van der Waals radius of 275 pm. Potassium was discovered and first isolated by Sir Humphrey Davy in 1807. Potassium is the seventh most abundant element on earth. It is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other alkali metals, potassium decomposes in water with the evolution of hydrogen because of its reacts violently with water, it only occurs in nature in ionic salts.Potassium Bohr Model In its elemental form, potassium has a silvery gray metallic appearance, but its compounds (such as potassium hydroxide) are more frequently used in industrial and chemical applications. The origin of the element's name comes from the English word 'potash,' meaning pot ashes, and the Arabic word qali, which means alkali. The symbol K originates from the Latin word kalium.

Sodium

Sodium Bohr ModelSee more Sodium products. Sodium (atomic symbol: Na, atomic number: 11) is a Block D, Group 5, Period 4 element with an atomic weight of 22.989769. The number of electrons in each of Sodium's shells is [2, 8, 1] and its electron configuration is [Ne] 3s1. The sodium atom has a radius of 185.8 pm and a Van der Waals radius of 227 pm. Sodium was discovered and first isolated by Sir Humphrey Davy in 1807. In its elemental form, sodium has a silvery-white metallic appearance. It is the sixth most abundant element, making up 2.6 % of the earth's crust. Sodium does not occur in nature as a free element and must be extracted from its compounds (e.g., feldspars, sodalite, and rock salt). The name Sodium is thought to come from the Arabic word suda, meaning "headache" (due to sodium carbonate's headache-alleviating properties), and its elemental symbol Na comes from natrium, its Latin name.

Related Forms & Applications