'Turn-on' fluorescent chemosensors based on naphthaldehyde-2-pyridinehydrazone compounds for the detection of zinc ion in water at neutral pH.

Title 'Turn-on' fluorescent chemosensors based on naphthaldehyde-2-pyridinehydrazone compounds for the detection of zinc ion in water at neutral pH.
Authors Y. Liu; Y. Li; Q. Feng; N. Li; K. Li; H. Hou; B. Zhang
Journal Luminescence
DOI 10.1002/bio.3368
Abstract

A series of naphthaldehyde-2-pyridinehydrazone derivatives were discovered to display interesting 'turn-on' fluorescence response to Zn(2+) in 99% water/DMSO (v/v) at pH 7.0. Mechanism study indicated that different substituent groups in the naphthaldehyde moiety exhibited significant influence on the detection of Zn(2+) . The electron rich group resulted in longer fluorescence wavelengths but smaller fluorescence enhancement for Zn(2+) . Among these compounds, 1 showed the highest fluorescence enhancement of 19-fold with the lowest detection limit of 0.17 ?mol/L toward Zn(2+) . The corresponding linear range was at least from 0.6 to 6.0 ?mol/L. Significantly, 1 showed an excellent selectivity toward Zn(2+) over other metal ions including Cd(2+) .

Citation Y. Liu; Y. Li; Q. Feng; N. Li; K. Li; H. Hou; B. Zhang.'Turn-on' fluorescent chemosensors based on naphthaldehyde-2-pyridinehydrazone compounds for the detection of zinc ion in water at neutral pH.. Luminescence. 2017. doi:10.1002/bio.3368

Related Elements

Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. Zinc Bohr ModelThe zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.