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Cobalt Carbonate Hydrate
CoCO3 · xH2O
Product Product Code Order or Specifications
(2N) 99% Cobalt Carbonate Hydrate CO-CB-02-HYD Contact American Elements
(3N) 99.9% Cobalt Carbonate Hydrate CO-CB-03-HYD Contact American Elements
(4N) 99.99% Cobalt Carbonate Hydrate CO-CB-04-HYD Contact American Elements
(5N) 99.999% Cobalt Carbonate Hydrate CO-CB-05-HYD Contact American Elements

 

CHEMICAL
IDENTIFICATION		 Formula CAS No. PubChem
SID		 PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No. 		SMILES
Identifier 		InChI
Identifier 		InChI
Key
CoCO3 • xH2O 137506-60-6 24863704 16211458 MFCD00149654 235-112-0 cobaltous carbonate hydrate   C(=O)(O)O.[Co+2] InChI=1S/CH2O3.Co/c2-1(3)4;/h(H2,2,3,4);/q;+2 ZOTKGJBKKKVBJZ-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
CH2CoO3 118.94 Red Powder 4.13 g/cm3 120.932495 120.932495 Da 0 Safety Data Sheet


Carbonate IonCobalt Carbonate Hydrate is a water insoluble Cobalt source that can easily be converted to other Cobalt compounds, such as the oxide by heating (calcination). Carbonate compounds also give off carbon dioxide when treated with dilute acids. Cobalt Carbonate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cobalt(Co) atomic and molecular weight, atomic number and elemental symbolCobalt is a Block D, Group 9, Period 4 element. The number of electrons in each of Cobalt's shells is 2, 8, 15, 2 and its electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. The cobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm. Cobalt and its compounds are somewhat toxic by skin contact and moderately toxic by inhalation. Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many Cobalt Bohr Modelimportant Elemental Cobaltuses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Toxicity of cobalt and its compounds are mild by skin contact and moderate by ingestion. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Cobalt was first discovered by George Brandt in 1737. The origin of the word Cobalt comes from the German word 'Kobalt or Kobold' which translates as "goblin", "elf" or "evil spirit". See Cobalt research below.

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Toxicity
Safety & Handling
  Exclamation Mark-Acute Toxicity Health Hazard        
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Warning H302-H315-H317-H319-H335-H351 Xn 22-36/37/38-40-43 26-36/37 N/A N/A 3

 

Synonyms for Cobalt Carbonate Include:


CARBONIC ACID, COBALT COMPLEX
cobaltous carbonate hydrate
cobalt(II) carbonate hydrate
cobalt(2+) carbonate hydrate (1:1:1)
cobalt(+2) cation carbonate hydrate

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 


Recent Research & Development for Cobalt

  • Tetra-kis(3-cyano-pyridine-?N)bis-(thio-cyanato-?N)cobalt(II) 1,4-dioxane disolvate. Diehr S, Wöhlert S, Boeckmann J, Näther C. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1898. Epub 2011 Nov 30. PMID: 22199656 [PubMed - as supplied by publisher]

  • Bis(2,4-dioxo-5,5-diphenyl-imidazol-idin-ido-?N)bis-(propane-1,3-diamine-?N,N')cobalt(II). Hu X, Jiang Q, Wang D, Liu H. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1885. Epub 2011 Nov 30. PMID: 22199646 [PubMed - as supplied by publisher]

  • Poly[aqua-{?(3)-5-[(pyridin-2-ylmeth-yl)amino]-isophthalato-?N,N':O,O:O}cobalt(II)]. Zhu XH, Cheng XC. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1862. Epub 2011 Nov 30. PMID: 22199630 [PubMed - as supplied by publisher]

  • catena-Poly[[[cis-aqua-dibromido-cobalt(II)]-?-(pyrazine-2-carb-oxy-lic acid)-?N,O:N] monohydrate]. Dares C, Fournier R, Lever AB. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1798-m1799. Epub 2011 Nov 23. PMID: 22199583 [PubMed - as supplied by publisher]

  • Poly[di-?(2)-aqua-?(5)-(pyridine-2,6-dicarboxyl-ato)-?(3)-(pyridine-2,6-dicarboxyl-ato)-cobalt(II)disodium]. Boyko AN, Golenya IA, Izotova YA, Haukka M, Prisyazhnaya EV. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1782-m1783. Epub 2011 Nov 19. PMID: 22199572 [PubMed - as supplied by publisher]

  • Diaqua-bis-(pyridine-2-sulfonato-?N,O)cobalt(II). Li ZS, Ng SW. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1781. Epub 2011 Nov 19. PMID: 22199571 [PubMed - as supplied by publisher]

  • Bis[tris-(ethyl-enediamine-?N,N')cobalt(III)] octa-kis-?-(3)-oxido-hexa-deca-?(2)-oxido-tetra-deca-oxido-?(12)-tetra-oxo-silicato-octa-molybdenum(VI)hexa-vanadium(IV,V) hexa-hydrate. Lu YK, Tian MM, Xu SG, Lü RQ, Liu YQ. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1776-m1777. Epub 2011 Nov 19. PMID: 22199568 [PubMed - as supplied by publisher]

  • Tetra-aqua-bis-(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetato)-cobalt(II) monohydrate. Yang GR, Li GT. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1746-m1747. Epub 2011 Nov 12. PMID: 22199545 [PubMed - as supplied by publisher]

  • Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-?N]cobalt(II). Wang HR, Li GT. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1743. Epub 2011 Nov 12. PMID: 22199542 [PubMed - as supplied by publisher]

  • Poly[[tetra-aqua-(?(4)-imidazole-4,5-dicarboxyl-ato)(?(3)-imidazole-4,5-dicarboxyl-ato)-?(3)-sulfato-?(2)-sulfato-cobalt(II)digadolinium(III)] monohydrate]. Zhu LC. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1741-m1742. Epub 2011 Nov 12. PMID: 22199541 [PubMed - as supplied by publisher]

  • Hexaaqua-cobalt(II) bis-(5-acetyl-2-hy-droxy-benzoate) dihydrate. Han LJ, Yang SP, Fu LL, Gao HL. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1733. Epub 2011 Nov 9. PMID: 22199535 [PubMed - as supplied by publisher]

  • Dichlorido[(4E,11E)-5,7,12,14-tetra-benzyl-7,14-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene]cobalt(III) perchlorate. Roy TG, Hazari SK, Barua KK, Ng SW, Tiekink ER. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1722-m1723. Epub 2011 Nov 9. PMID: 22199529 [PubMed - as supplied by publisher]

  • {1,2-Bis[(3,5-dimethyl-1H-pyrazol-1-yl-?N)meth-yl]benzene}-dichloridozinc(II). Guzei IA, Spencer LC, Budhai A, Darkwa J. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1715-m1716. Epub 2011 Nov 9. PMID: 22199525 [PubMed - as supplied by publisher]

  • catena-Poly[[bis-(2,4-dichloro-benzoato)bis-(methanol-?O)cobalt(II)]-?-4,4'-bipyridine-?N:N']. Hyun MY, Kim PG, Kim C, Kim Y. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1705. Epub 2011 Nov 9. PMID: 22199519 [PubMed - as supplied by publisher]

  • Bis(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')cobalt(II). Perdih F. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1697. Epub 2011 Nov 5. PMID: 22199513 [PubMed - as supplied by publisher]

  • Diaqua-bis-(dihydrogen 3-aza-niumyl-1-hy-droxy-propyl-idene-1,1-di-phos-phon-ato-?O,O')cobalt(II). Tsaryk NV, Dudko AV, Kozachkova AN, Pekhnyo VI. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1694. Epub 2011 Nov 5. PMID: 22199511 [PubMed - as supplied by publisher]

  • Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-?O}cobalt(II) dihydrate. Bai L, Zhao J. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1689. Epub 2011 Nov 5. PMID: 22199506 [PubMed - as supplied by publisher]

  • Tetra-aqua-bis-(2-methyl-1H-imidazole-?N)cobalt(II) naphthalene-1,5-disulfonate. Jin Y. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1686. Epub 2011 Nov 5. PMID: 22199503 [PubMed - as supplied by publisher]

  • Diaqua-bis-(dimethyl sulfoxide-?O)bis(saccharinato-?N)cobalt(II). Potwana FS, Van Zyl WE. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1667-m1668. Epub 2011 Nov 5. PMID: 22199492 [PubMed - as supplied by publisher]

  • Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles. Roedel EQ, Cafasso DE, Lee KW, Pierce LM. Toxicol Appl Pharmacol. 2011 Dec 16. [Epub ahead of print] PMID: 22198552 [PubMed - as supplied by publisher]

Recent Research & Development for Carbonate

  • An in-situ study investigating dentine tubule occlusion of dentifrices following acid challenge. Olley RC, Pilecki P, Hughes N, Jeffery P, Austin RS, Moazzez R, Bartlett D. J Dent. 2012 Apr 4. [Epub ahead of print] PMID: 22484377 [PubMed - as supplied by publisher]

  • FT-IR spectral studies on certain human urinary stones in the patients of rural area. Selvaraju R, Thiruppathi G, Raja A. Spectrochim Acta A Mol Biomol Spectrosc. 2012 Mar 17;93C:260-265. [Epub ahead of print] PMID: 22484261 [PubMed - as supplied by publisher]

  • Ionic Nucleophilic Catalysis of Chiral Ammonium Betaines for Highly Stereoselective Aldol Reaction from Oxindole-Derived Vinylic Carbonates. Uraguchi D, Koshimoto K, Ooi T. J Am Chem Soc. 2012 Apr 6. [Epub ahead of print] PMID: 22482889 [PubMed - as supplied by publisher]

  • Large-scale first-principles molecular dynamics for electrochemical systems with O(N) methods. Ohwaki T, Otani M, Ikeshoji T, Ozaki T. J Chem Phys. 2012 Apr 7;136(13):134101. PMID: 22482534 [PubMed - in process]

  • Conceptual models for carbonate aquifers. 1969. White WB. Ground Water. 2012 Mar-Apr;50(2):180-6. No abstract available. PMID: 22482126 [PubMed - in process]

  • Shape-controlled synthesis of high tap density cathode oxides for lithium ion batteries. Cao A, Manthiram A. Phys Chem Chem Phys. 2012 Apr 5. [Epub ahead of print] PMID: 22481275 [PubMed - as supplied by publisher]

  • Pre-terminal renal insufficiency in a patient with enteric hyperoxaluria: effect of medical management on renal function. Pipeleers L, Wissing KM, Pirson Y, Cosyns JP, Geers C, Tielemans C. Acta Clin Belg. 2012 Jan-Feb;67(1):39-41. PMID: 22480038 [PubMed - in process]

  • Removal of Cu, Zn, and Cd from aqueous solutions by the dairy manure-derived biochar. Xu X, Cao X, Zhao L, Wang H, Yu H, Gao B. Environ Sci Pollut Res Int. 2012 Apr 5. [Epub ahead of print] PMID: 22477163 [PubMed - as supplied by publisher]

  • Lanthanum carbonate: a postmarketing observational study of efficacy and safety. Rombolà G, Londrino F, Corbani V, Falqui V, Ardini M, Zattera T, Lanthanum Experience Litolae Group OB. J Nephrol. 2012 Apr 4:0. doi: 10.5301/jn.5000118. [Epub ahead of print] PMID: 22476966 [PubMed - as supplied by publisher]

  • Bio-filler from waste shellfish shell: Preparation, characterization, and its effect on the mechanical properties on polypropylene composites. Li HY, Tan YQ, Zhang L, Zhang YX, Song YH, Ye Y, Xia MS. J Hazard Mater. 2012 Mar 19. [Epub ahead of print] PMID: 22476096 [PubMed - as supplied by publisher]

  • Asymmetric Total Synthesis and Absolute Stereochemistry of the Neuroactive Marine Macrolide Palmyrolide A. Tello-Aburto R, Johnson EM, Valdez CK, Maio WA. Org Lett. 2012 Apr 4. [Epub ahead of print] PMID: 22475318 [PubMed - as supplied by publisher]

  • Stereoselective Assembly of Complex Oligosaccharides Using Anomeric Sulfonium Ions as Glycosyl Donors. Fang T, Mo KF, Boons GJ. J Am Chem Soc. 2012 Apr 4. [Epub ahead of print] PMID: 22475263 [PubMed - as supplied by publisher]

  • Predictable and tunable half-life extension of therapeutic agents by controlled chemical release from macromolecular conjugates. Santi DV, Schneider EL, Reid R, Robinson L, Ashley GW. Proc Natl Acad Sci U S A. 2012 Apr 2. [Epub ahead of print] PMID: 22474378 [PubMed - as supplied by publisher]

  • Novel Molluskan Biomineralization Proteins Retrieved from Proteomics: A Case Study with Upsalin. Ramos-Silva P, Benhamada S, Le Roy N, Marie B, Guichard N, Zanella-Cléon I, Plasseraud L, Corneillat M, Alcaraz G, Kaandorp J, Marin F. Chembiochem. 2012 Apr 4. doi: 10.1002/cbic.201100708. [Epub ahead of print] PMID: 22474002 [PubMed - as supplied by publisher]

  • Biomimetic approach to forming chitin/aragonite composites. Munro NH, McGrath KM. Chem Commun (Camb). 2012 Apr 4. [Epub ahead of print] PMID: 22473223 [PubMed - as supplied by publisher]

  • Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives. Wuensch C, Glueck SM, Gross J, Koszelewski D, Schober M, Faber K. Org Lett. 2012 Apr 3. [Epub ahead of print] PMID: 22471935 [PubMed - as supplied by publisher]

  • Diastereo- and Enantioselective [3+2] Cycloaddition Reaction of Morita-Baylis-Hillman Carbonates of Isatins with N-Phenylmaleimide Catalyzed by Me-DuPhos. Wang Y, Liu L, Zhang T, Zhong NJ, Wang D, Chen YJ. J Org Chem. 2012 Apr 3. [Epub ahead of print] PMID: 22471756 [PubMed - as supplied by publisher]

  • The effect of gastric acid suppression with pantoprazole on the efficacy of calcium carbonate as a phosphate binder in haemodialysis patients. Cervelli MJ, Shaman A, Meade A, Carroll R, McDonald SP. Nephrology (Carlton). 2012 Apr 4. doi: 10.1111/j.1440-1797.2012.01604.x. [Epub ahead of print] PMID: 22471559 [PubMed - as supplied by publisher]

  • Analysis of the molecular structure of human enamel with fluorosis using micro-Raman spectroscopy. Zavala-Alonso V, Loyola-Rodríguez JP, Terrones H, Patiño-Marín N, Martínez-Castañón GA, Anusavice K. J Oral Sci. 2012;54(1):93-8. PMID: 22466892 [PubMed - in process]

  • Stone-isolated carbonatogenic bacteria as inoculants in bioconsolidation treatments for historical limestone. Jroundi F, Gómez-Suaga P, Jimenez-Lopez C, González-Muñoz MT, Fernandez-Vivas MA. Sci Total Environ. 2012 Mar 30. [Epub ahead of print] PMID: 22464961 [PubMed - as supplied by publisher]

     

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