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Chromium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose. Recently, chromites have formed the basis for cathode compositions for oxygen generation and fuel cell applications.

Chromium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Chromium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Chromium is a Block D, Group 6, Period 4 element. The electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Chromium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Chromium was first discovered by Anders Ekeberg in 1802.

French chrome German Chrom Italian cromo Portuguese Crômo Spanish cromo Swedish Krom

Abundance. The following table shows the abundance of chromium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Cr-50
49.946050
4.35
Cr-52
51.940512
83.79
Cr-53
52.940654
9.50
Cr-54
53.938885
2.37

Safety Data. The safety data for chromium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for chromium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
652.87 kJ mol-1
2nd Ionization Energy
1590.64 kJ mol-1
3rd Ionization Energy
2987.21 kJ mol-1

Conductivity. As to chromium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 12.9 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.66. The thermal conductivity of chromium is 93.7 W m-1 K-1.

Thermal Properties. The melting point and boiling point for chromium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
15.3 kJ mol-1
Heat of Vaporization
341.8 kJ mol-1
Heat of Atomization
394.51 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Cr 24 51.996 g.mol -1 1.6 7.19 g.cm-3 at 20 °C 1907 °C 2672 °C 200.pm 0.061 nm (+3) ; 0.044 nm (+6) 652.87 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Chromium

  • Comparison of in vitro Cr(VI) reduction by CFEs of chromate resistant bacteria isolated from chromate contaminated soil. Bioresour Technol. 2008 Jul;99(10):4130-7. Epub 2007 Oct 24.

  • Kinetic and equilibrium modeling of chromium (VI) biosorption on fresh and spent Spirulina platensis/Chlorella vulgaris biomass. Bioresour Technol. 2008 Jun;99(9):3600-8. Epub 2007 Sep 27.

  • Molecular basis of chromium insulin interactions. Biochem Biophys Res Commun. 2008 May 2;369(2):725-9. Epub 2008 Feb 26.

  • Biosorption of chromium(VI) using a Sargassum sp. packed-bed column. Bioresour Technol. 2008 May;99(8):3094-9. Epub 2007 Aug 6.

  • Low-cost supports used to immobilize fungi and reliable technique for removal hexavalent chromium in wastewater. Bioresour Technol. 2008 May;99(7):2234-2241. Epub 2007 Jul 2.

  • Removal of chromium(VI) from water and wastewater using surfactant modified coconut coir pith as a biosorbent. Bioresour Technol. 2008 May;99(7):2218-25. Epub 2007 Jun 29.

  • Hexavalent chromium uptake and its effects on mineral uptake, antioxidant defence system and photosynthesis in Amaranthus viridis L. Bioresour Technol. 2008 May;99(7):2628-36. Epub 2007 Jun 13.

  • Trace element exposure in the environment from MSW landfill leachate sediments measured by a sequential extraction technique. J Hazard Mater. 2008 May 1;153(1-2):751-8. Epub 2007 Sep 8.

  • Biosorption of Cr(VI) by three different bacterial species supported on granular activated carbon-A comparative study. J Hazard Mater. 2008 May 1;153(1-2):799-809. Epub 2007 Sep 12.

  • Hexavalent chromium reduction with scrap iron in continuous-flow system Part 1: Effect of feed solution pH. J Hazard Mater. 2008 May 1;153(1-2):655-62. Epub 2007 Sep 6.

  • Solid phase extraction method for the determination of iron, lead and chromium by atomic absorption spectrometry using Amberite XAD-2000 column in various water samples. J Hazard Mater. 2008 May 1;153(1-2):454-61. Epub 2007 Aug 31.

  • Characterization of the fine fraction of the argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry. J Hazard Mater. 2008 May 1;153(1-2):89-95. Epub 2007 Aug 15.

  • Kinetic and thermodynamic studies of the biosorption of Cr(VI) by Pinus sylvestris Linn. J Hazard Mater. 2008 May 1;153(1-2):52-9. Epub 2007 Aug 12.

  • Geochemical stability of chromium in sediments from the lower Hackensack River, New Jersey. Sci Total Environ. 2008 May 1;394(1):103-11. Epub 2008 Mar 4.

  • Hexavalent chromium causes the oxidation of thioredoxin in human bronchial epithelial cells. Toxicology. 2008 Apr 18;246(2-3):222-33. Epub 2008 Feb 2.

  • Rapid quantification of global DNA methylation by isocratic cation exchange high-performance liquid chromatography. Anal Biochem. 2008 Apr 15;375(2):354-60. Epub 2008 Jan 9.

  • Purification of spent chromium bath by membrane electrolysis. J Hazard Mater. 2008 Apr 15;152(3):960-7. Epub 2007 Aug 6.

  • Evaluation of batch adsorption of chromium ions on natural and crosslinked chitosan membranes. J Hazard Mater. 2008 Apr 15;152(3):1155-63. Epub 2007 Aug 3.

  • Chromate reduction by waste iron from electroplating wastewater using plug flow reactor. J Hazard Mater. 2008 Apr 15;152(3):1092-7. Epub 2007 Jul 31.

  • Anion effects on the electrochemical regeneration of Ce(IV) in nitric acid used for etching chromium. J Hazard Mater. 2008 Apr 15;152(3):922-8. Epub 2007 Jul 27.

 

 

 

 

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