Potassium Acetylacetonate Hemihydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Potassium is a Block S, Group 1, Period 4 element. The number of electrons in each of Potassium's shells is 2, 8, 8, 1 and its electronic configuration is [Ar] 4s1. In its elemental form potassium's CAS number is 7440-09-7. The potassium atom has a radius of 227.2 .pm and it's Van der Waals radius is 275.pm. Potassium is not toxic. Potassium is the seventh most abundant element on earth. In its metallic form it is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other metals of the alkali group, the metal decomposes in water with the evolution of hydrogen. It catches fire spontaneously in water. In high purity, potassium compounds have numerous pharmacological, medical, and electronics applications. Important compounds include the hydroxide, nitrate, carbonate, chloride, bromide, iodide, and sulfate. Lower purity compounds are used in pyrotechnics for its violet color on ignition and in glass and ceramic glazes to produce this color. Potassium also used as a nutrient in plant growth. Potassium was first discovered by Sir Humphrey Davy in 1807. The origin of the element name comes from the English word 'potash' meaning pot ashes and the Arabic word 'qali' which means alkali. The symbol K originates from the Latin word 'kalium'. See Potassium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Aluminum potassium sulfate and tannic Acid injection for hemorrhoids.
Lim SW.
J Korean Soc Coloproctol. 2012 Apr;28(2):73-7. Epub 2012 Apr 30.
PMID:
22606645
[PubMed - in process]
Suppression of Ribosomal Function Triggers Innate Immune Signaling through Activation of the NLRP3 Inflammasome.
Vyleta ML, Wong J, Magun BE.
PLoS One. 2012;7(5):e36044. Epub 2012 May 14.
PMID:
22606244
[PubMed - as supplied by publisher]
Stroke preceding autoimmune encephalitis with neuronal potassium channel antibody.
Simal P, Garcia-García AM, Serna-Candel C, Egido JA.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0820114637. doi: 10.1136/bcr.08.2011.4637.
PMID:
22605845
[PubMed - in process]
Life-threatening hyperkalemia - an overlooked acute kidney injury with a serum creatinine rise in the 'normal' range.
Latus J, Braun N, Alscher MD, Kimmel M.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0120125691. doi: 10.1136/bcr.01.2012.5691.
PMID:
22605836
[PubMed - in process]
Ethylene glycol ingestion masked by concomitant ethanol intoxication.
Head JM.
BMJ Case Rep. 2012 Mar 20;2012. pii: bcr1220115326. doi: 10.1136/bcr.12.2011.5326.
PMID:
22605713
[PubMed - in process]
Neuroanatomy of melanocortin-4 receptor pathway in the lateral hypothalamic area.
Cui H, Sohn JW, Gautron L, Funahashi H, Williams KW, Elmquist JK, Lutter M.
J Comp Neurol. 2012 May 17. doi: 10.1002/cne.23145. [Epub ahead of print]
PMID:
22605619
[PubMed - as supplied by publisher]
Microvascular responses to aldosterone in hamster cheek pouch microcirculation.
Lapi D, Emdin M, Mastantuono T, Sapio D, Santillo M, Colantuoni A.
Clin Hemorheol Microcirc. 2012 May 16. [Epub ahead of print]
PMID:
22596229
[PubMed - as supplied by publisher]
Prevalence and Factors Associated with Hyperkalemia in Predialysis Patients Followed in a Low-Clearance Clinic.
Sarafidis PA, Blacklock R, Wood E, Rumjon A, Simmonds S, Fletcher-Rogers J, Ariyanayagam R, Al-Yassin A, Sharpe C, Vinen K.
Clin J Am Soc Nephrol. 2012 May 17. [Epub ahead of print]
PMID:
22595825
[PubMed - as supplied by publisher]
Chemical punch packed in venoms makes centipedes excellent predators.
Yang S, Liu Z, Xiao Y, Li Y, Rong M, Liang S, Zhang Z, Yu H, King GF, Lai R.
Mol Cell Proteomics. 2012 May 17. [Epub ahead of print]
PMID:
22595790
[PubMed - as supplied by publisher]
21 Days head-down bed rest induces weakening of cell-mediated immunity - Some spaceflight findings confirmed in a ground-based analog.
Kelsen J, Bartels LE, Dige A, Hvas CL, Frings-Meuthen P, Boehme G, Thomsen MK, Fenger-Grøn M, Dahlerup JF.
Cytokine. 2012 May 15. [Epub ahead of print]
PMID:
22595648
[PubMed - as supplied by publisher]
Efficient production of ultrapure manganese oxides via electrodeposition.
Cheney MA, Joo SW, Banerjee A, Min BK.
J Colloid Interface Sci. 2012 Apr 25. [Epub ahead of print]
PMID:
22595552
[PubMed - as supplied by publisher]
Radiolytic formation of non-toxic Cr(III) from toxic Cr(VI) in formate containing aqueous solutions: A system for water treatment.
Djouider F.
J Hazard Mater. 2012 May 3. [Epub ahead of print]
PMID:
22595544
[PubMed - as supplied by publisher]
Comparative effect of angiotensin II type I receptor blockers and calcium channel blockers on laboratory parameters in hypertensive patients with type 2 diabetes.
Nishida Y, Takahashi Y, Nakayama T, Asai S.
Cardiovasc Diabetol. 2012 May 17;11(1):53. [Epub ahead of print]
PMID:
22594344
[PubMed - as supplied by publisher]
Functional significance of M-type potassium channels in nociceptive cutaneous sensory endings.
Passmore GM, Reilly JM, Thakur M, Keasberry VN, Marsh SJ, Dickenson AH, Brown DA.
Front Mol Neurosci. 2012;5:63. Epub 2012 May 14.
PMID:
22593734
[PubMed - in process]
Growth, root formation, and nutrient value of triticale plants fertilized with biosolids.
Rauw WM, Teglas MB, Chandra S, Forister ML.
ScientificWorldJournal. 2012;2012:467052. Epub 2012 Apr 19.
PMID:
22593686
[PubMed - in process]
Electrochemistry/mass spectrometry as a tool in the investigation of the potent skin sensitizer p-phenylenediamine and its reactivity toward nucleophiles.
Jahn S, Faber H, Zazzeroni R, Karst U.
Rapid Commun Mass Spectrom. 2012 Jun 30;26(12):1453-64. doi: 10.1002/rcm.6249.
PMID:
22592989
[PubMed - in process]
One-step sonochemical synthesis of a graphene oxide-manganese oxide nanocomposite for catalytic glycolysis of poly(ethylene terephthalate).
Park G, Bartolome L, Lee KG, Lee SJ, Kim DH, Park TJ.
Nanoscale. 2012 May 16. [Epub ahead of print]
PMID:
22592889
[PubMed - as supplied by publisher]
Interventions for non-oliguric hyperkalaemia in preterm neonates.
Vemgal P, Ohlsson A.
Cochrane Database Syst Rev. 2012 May 16;5:CD005257.
PMID:
22592703
[PubMed - in process]
Ultrasound assisted free radical polymerization of glycidyl methacrylate by a new disite phase-transfer catalyst system: A kinetic study.
Sankar K, Rajendran V.
Ultrason Sonochem. 2012 Feb 22. [Epub ahead of print]
PMID:
22592149
[PubMed - as supplied by publisher]
Comparison of the Effects of Sevoflurane, Isoflurane, and Desflurane on Microcirculation in Coronary Artery Bypass Graft Surgery.
Ozarslan NG, Ayhan B, Kanbak M, Celebiog?lu B, Demircin M, Ince C, Aypar U.
J Cardiothorac Vasc Anesth. 2012 May 14. [Epub ahead of print]
PMID:
22592139
[PubMed - as supplied by publisher]
Recent Research & Development for Acetylacetonates
Unfairly forgotten member of the iodocarborane family: synthesis and structural characterization of 8-iodo-1,2-dicarba-closo-dodecaborane, its precursors, and derivatives.
Safronov AV, Sevryugina YV, Jalisatgi SS, Kennedy RD, Barnes CL, Hawthorne MF.
Inorg Chem. 2012 Feb 20;51(4):2629-37. Epub 2012 Feb 1.
PMID:
22296243
[PubMed - in process]
A thermolysis approach to simultaneously achieve crystal phase- and shape-control of ternary M-Fe-O metal oxide nanoparticles.
Huang CC, Chang CN, Yeh CS.
Nanoscale. 2011 Oct 5;3(10):4254-60. Epub 2011 Aug 31.
PMID:
21879122
[PubMed - indexed for MEDLINE]
Chemical fluid deposition of monometallic and bimetallic nanoparticles on ordered mesoporous silica as hydrogenation catalysts.
Yen CH, Lin HW, Phan TD, Tan CS.
J Nanosci Nanotechnol. 2011 Mar;11(3):2465-9.
PMID:
21449408
[PubMed - indexed for MEDLINE]
Hydrolytic synthesis and structural characterization of lanthanide-acetylacetonato/hydroxo cluster complexes--a systematic study.
Wu Y, Morton S, Kong X, Nichol GS, Zheng Z.
Dalton Trans. 2011 Feb 7;40(5):1041-6. Epub 2010 Dec 14.
PMID:
21152668
[PubMed]
Notes on the photo-induced characteristics of transition metal-doped and undoped titanium dioxide thin films.
Kment S, Kmentova H, Kluson P, Krysa J, Hubicka Z, Cirkva V, Gregora I, Solcova O, Jastrabik L.
J Colloid Interface Sci. 2010 Aug 1;348(1):198-205. Epub 2010 Apr 8.
PMID:
20466384
[PubMed]
Clewlike ZnV2O4 hollow spheres: nonaqueous sol-gel synthesis, formation mechanism, and lithium storage properties.
Xiao L, Zhao Y, Yin J, Zhang L.
Chemistry. 2009 Sep 21;15(37):9442-50.
PMID:
19672904
[PubMed - indexed for MEDLINE]
Nickelacyclic-cobaltocene vs. nickelacyclic-nickelocene. Synthesis, X-ray structures, electron transfer activity, EPR spectroscopy, and theoretical calculations.
Buchalski P, Kamińska E, Piwowar K, Suwińska K, Jerzykiewicz L, Rossi F, Laschi F, de Biani FF, Zanello P.
Inorg Chem. 2009 Jun 1;48(11):4934-41.
PMID:
19405491
[PubMed]
Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates.
Pugliese T, Godbert N, Aiello I, La Deda M, Ghedini M, Amati M, Belviso S, Lelj F.
Dalton Trans. 2008 Dec 14;(46):6563-72. Epub 2008 Oct 10.
PMID:
19030618
[PubMed - indexed for MEDLINE]
Well-defined N-heterocyclic carbenes-palladium(II) precatalysts for cross-coupling reactions.
Marion N, Nolan SP.
Acc Chem Res. 2008 Nov 18;41(11):1440-9.
PMID:
18774825
[PubMed]
Colloidal chemical synthesis and formation kinetics of uniformly sized nanocrystals of metals, oxides, and chalcogenides.
Kwon SG, Hyeon T.
Acc Chem Res. 2008 Dec;41(12):1696-709.
PMID:
18681462
[PubMed]
Generalized nonaqueous sol-gel synthesis of different transition-metal niobate nanocrystals and analysis of the growth mechanism.
Zhang L, Garnweitner G, Djerdj I, Antonietti M, Niederberger M.
Chem Asian J. 2008 Apr 7;3(4):746-52.
PMID:
18335422
[PubMed - indexed for MEDLINE]
One-minute synthesis of crystalline binary and ternary metal oxide nanoparticles.
Bilecka I, Djerdj I, Niederberger M.
Chem Commun (Camb). 2008 Feb 21;(7):886-8. Epub 2007 Dec 19.
PMID:
18253537
[PubMed - indexed for MEDLINE]
EPR study on ligand-exchange reaction between bis(diethyldiselenocarbamato)copper(II) and some bis(acetylacetonato)copper(II) complexes.
Dimitrova A, Taseva C, Yordanov ND.
Spectrochim Acta A Mol Biomol Spectrosc. 2008 Oct;70(5):953-7. Epub 2007 Oct 2.
PMID:
17988937
[PubMed - indexed for MEDLINE]
Metal acetylacetonate domains grown on H-terminated porous silicon at room temperature and their specific I-V behavior.
Chao J, Wang HT, Xia B, Liu HB, Xiao ZD, Xiao SJ.
J Phys Chem B. 2006 Dec 7;110(48):24565-70.
PMID:
17134216
[PubMed]
Organic reaction pathways in the nonaqueous synthesis of metal oxide nanoparticles.
Niederberger M, Garnweitner G.
Chemistry. 2006 Sep 25;12(28):7282-302.
PMID:
16927442
[PubMed]
Chemisorption and thermodynamic data of the interaction between a chelate free acidic center with basic groups attached to grafted silicas.
Arakaki LN, de Sousa AN, Espínola JG, Oliveira SF, Airoldi C.
J Colloid Interface Sci. 2002 May 15;249(2):290-4.
PMID:
16290599
[PubMed]
FT-IR studies of acetylacetonates in supercritical CO2 using a capillary cell at pressures up to 3.1 kbar.
Henry MC, Yonker CR.
Anal Chem. 2004 Aug 15;76(16):4684-9.
PMID:
15307777
[PubMed]
The way into the bridge: a new bonding mode of tertiary phosphanes, arsanes, and stibanes.
Werner H.
Angew Chem Int Ed Engl. 2004 Feb 13;43(8):938-54.
PMID:
14966876
[PubMed]
Calculated and experimental geometries and infrared spectra of metal tris-acetylacetonates: vibrational spectroscopy as a probe of molecular structure for ionic complexes. Part II.
Diaz-Acosta I, Baker J, Hinton JF, Pulay P.
Spectrochim Acta A Mol Biomol Spectrosc. 2003 Jan 15;59(2):363-77.
PMID:
12685911
[PubMed - indexed for MEDLINE]
Detection of inorganic species by chemical reaction laser desorption ionization mass spectrometry.
Matsumoto K, Ajiro H, Habaue S, Okamoto Y.
Rapid Commun Mass Spectrom. 2003;17(7):678-84.
PMID:
12661020
[PubMed]
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