Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand.

Title Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand.
Authors C.N. de Bruin-Dickason; T. Sutcliffe; C.Alvarez Lamsfus; G.B. Deacon; L. Maron; C. Jones
Journal Chem Commun (Camb)
DOI 10.1039/c7cc09362d
Abstract

Two extremely bulky amidinate ligands, [RC{N(Dip)}{N(Ar?)}]- (Dip = 2,6-diisopropylphenyl; Ar? = C6H2{C(H)Ph2}2Pri-2,6,4; R = 1-adamantyl (LAd), tert-butyl (LtBu)) have been developed and utilised for the kinetic stabilisation of the strontium and magnesium hydride complexes, [LAdSr(?-H)]2 and [LRMg(?-H)]2 (R = Ad or But). The former represents the missing link in the series of dimeric systems, [LAe(?-H)]2 (Ae = alkaline earth metal). The structure and bonding of the complexes have been studied by crystallographic, spectroscopic and computational techniques.

Citation C.N. de Bruin-Dickason; T. Sutcliffe; C.Alvarez Lamsfus; G.B. Deacon; L. Maron; C. Jones.Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand.. Chem Commun (Camb). 2018. doi:10.1039/c7cc09362d

Related Elements

Strontium

See more Strontium products. Strontium (atomic symbol: Sr, atomic number: 38) is a Block S, Group 2, Period 5 element with an atomic weight of 87.62 . Strontium Bohr ModelThe number of electrons in each of Strontium's shells is [2, 8, 18, 8, 2] and its electron configuration is [Kr] 5s2. The strontium atom has a radius of 215 pm and a Van der Waals radius of 249 pm. Strontium was discovered by William Cruickshank in 1787 and first isolated by Humphry Davy in 1808. In its elemental form, strontium is a soft, silvery white metallic solid that quickly turns yellow when exposed to air. Elemental StrontiumCathode ray tubes in televisions are made of strontium, which are becoming increasingly displaced by other display technologies pyrotechnics and fireworks employ strontium salts to achieve a bright red color. Radioactive isotopes of strontium have been used in radioisotope thermoelectric generators (RTGs) and for certain cancer treatments. In nature, most strontium is found in celestite (as strontium sulfate) and strontianite (as strontium carbonate). Strontium was named after the Scottish town where it was discovered.

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