SECTION 2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Oxidizing solids Category 2
Acute oral toxicity Category 4
Skin Corrosion/Irritation Category 1 B
Serious Eye Damage/Eye Irritation Category 1
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system. Specific target organ toxicity - (repeated exposure) Category 2
Target Organs - Brain.
Signal Word
Danger
Hazard Statements
May intensify fire; oxidize
Harmful if swallowed
Causes severe skin burns and eye damage
May cause respiratory irritation
May cause damage to organs through prolonged or repeated exposure
Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
Rinse mouth
Do NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Harmful to aquatic life with long lasting effects
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component / CAS-No / Weight %:
Manganese(II) nitrate hexahydrate / 17141-63-8 / <=100
SECTION 4. FIRST AID MEASURES
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison
control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled
the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Ingestion
Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person.
Most important symptoms and effects
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation
Notes to Physician
Treat symptomatically
SECTION 5. FIREFIGHTING MEASURES
Suitable Extinguishing Media Not combustible. CO 2, dry chemical, dry sand, alcohol-resistant foam. Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Oxidizing Properties Oxidizer
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).
Hazardous Combustion Products
Nitrogen oxides (NOx). Manganese oxides.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health
3
Flammability
0
Instability
1
Physical hazards
- OX
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing.
Environmental Precautions
Should not be released into the environment. Do not allow material to contaminate ground water system. See Section 12 for additional Ecological Information. Avoid release to the environment. Collect spillage. Do not flush into surface water or sanitary sewer system.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Sweep up and shovel into suitable containers for disposal
SECTION 7. HANDLING AND STORAGE
Handling
Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials.
Storage
Store under an inert atmosphere. Protect from moisture. Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near combustible materials
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures
Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State Solid
Appearance Pink
Odor Odorless
Odor Threshold No information available
pH No information available
Melting Point/Range ~ 26 °C / 78.8 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula MnN2 O6.6H2 O
Molecular Weight 287.04 (178.95anhy)
SECTION 10. STABILITY AND REACTIVITY
Reactive Hazard Yes
Stability Hygroscopic. Oxidizer: Contact with combustible/organic material may cause fire.
Conditions to Avoid Exposure to moist air or water. Incompatible products. Excess heat.
Combustible material.
Incompatible Materials Strong reducing agents, Combustible material
Hazardous Decomposition Products Nitrogen oxides (NOx), Manganese oxides
Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available. Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure Brain
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.
Persistence and Degradability based on information available. May persist
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.
SECTION 14. TRANSPORT INFORMATION
DOT
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
TDG
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
IATA
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
IMDG/IMO
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
SECTION 15. REGULATORY INFORMATION
U.S. Federal Regulations
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals. Other International Regulations
Mexico - Grade No information available
