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Osmium Sulfide
OsS2
12137-61-0
Product Product Code Order or Specifications
(2N) 99% Osmium Sulfide OS-S-02 Contact American Elements
(3N) 99.9% Osmium Sulfide OS-S-03 Contact American Elements
(4N) 99.99% Osmium Sulfide OS-S-04 Contact American Elements
(5N) 99.999% Osmium Sulfide OS-S-05 Contact American Elements

Sulfide IonOsmium Sulfide is a moderately water and acid soluble Osmium source for uses compatible with sulfates. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells. Osmium Sulfide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Osmium(Os) atomic and molecular weight, atomic number and elemental symbolOsmium is a Block D, Group 8, Period 6 element. The number of electrons in each of Osmium's shells is 2, 8, 18, 32, 14, 2 and its electronic configuration is [Xe] 4f14 5d6 6s2. In its elemental form osmium's CAS number is 7440-04-2. The osmium atom has a radius of 133.8.pm and it's Van der Waals radius is 200.pm. Osmium tetroxide (OsO4) can cause eye, lung and skin damage which makes it very toxic. Osmium has the highest melting point and the lowest vapor pressure of Osmium Bohr Modelany of the platinum group of metals. Osmium tetroxide has recently been used to detect fingerprints Elemental Osmiumand as an aid to stain fatty tissue for microscope slides. The metal is almost entirely used to produce very hard alloys with other metals of the platinum group. Osmium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Osmium was first discovered by Smithson Tennant in 1803. The origin of the name Osmium comes from the Greek word osme meaning a smell or odor. See Osmium research below.

Sulfur(S) Aluminum(Al) atomic and molecular weight, atomic number and elemental symbolSulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms.  In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine Sulfur Bohr Modeland cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.

American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:

  • Crystal "pulling" by the Czochaiski method for production of semiconductor materials
  • Flux growth and gradient freeze
  • Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
Formula CAS No. Appearance Molecular Weight
OsS2 12137-61-0 Powder 254.362

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Recent Research & Development for Osmium

  • Coronary artery wall imaging in mice using osmium tetroxide and micro-computed tomography (micro-CT). Pai VM, Kozlowski M, Donahue D, Miller E, Xiao X, Chen MY, Yu ZX, Connelly P, Jeffries K, Wen H. J Anat. 2012 Feb 23. doi: 10.1111/j.1469-7580.2012.01483.x. [Epub ahead of print] PMID: 22360411 [PubMed - as supplied by publisher]

  • Spirobifluorene Bridged Ir(III) and Os(II) Polypyridyl Arrays: Synthesis, Photophysical Characterization, and Energy Transfer Dynamics. Ventura B, Barbieri A, Degli Esposti A, Seneclauze JB, Ziessel R. Inorg Chem. 2012 Mar 5;51(5):2832-40. Epub 2012 Feb 22. PMID: 22356478 [PubMed - in process]

  • Probes for narcotic receptor mediated phenomena. 44. Synthesis of an N-substituted 4-hydroxy-5-(3-hydroxyphenyl)morphan with high affinity and selective ?-antagonist activity. Iyer MR, Lee YS, Deschamps JR, Dersch CM, Rothman RB, Jacobson AE, Rice KC. Eur J Med Chem. 2012 Jan 20. [Epub ahead of print] PMID: 22341895 [PubMed - as supplied by publisher]

  • From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts. Spasyuk D, Smith S, Gusev DG. Angew Chem Int Ed Engl. 2012 Feb 8. doi: 10.1002/anie.201108956. [Epub ahead of print] PMID: 22319022 [PubMed - as supplied by publisher]

  • Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium: biological relevance and synthetic strategies. Barry NP, Sadler PJ. Chem Soc Rev. 2012 Feb 3. [Epub ahead of print] PMID: 22307021 [PubMed - as supplied by publisher]

  • A mediated glucose/oxygen enzymatic fuel cell based on printed carbon inks containing aldose dehydrogenase and laccase as anode and cathode. Jenkins P, Tuurala S, Vaari A, Valkiainen M, Smolander M, Leech D. Enzyme Microb Technol. 2012 Mar 10;50(3):181-7. Epub 2011 Dec 24. PMID: 22305173 [PubMed - in process]

  • DNA/nickel oxide nanoparticles/osmium(III)-complex modified electrode toward selective oxidation of l-cysteine and simultaneous detection of l-cysteine and homocysteine. Sharifi E, Salimi A, Shams E. Bioelectrochemistry. 2012 Jan 14. [Epub ahead of print] PMID: 22296821 [PubMed - as supplied by publisher]

  • Production of human tissue-engineered skin trilayer on a plasma-based hypodermis. Monfort A, Soriano-Navarro M, García-Verdugo JM, Izeta A. J Tissue Eng Regen Med. 2012 Jan 31. doi: 10.1002/term.548. [Epub ahead of print] PMID: 22294482 [PubMed - as supplied by publisher]

  • Zinc compartmentation in Halimione portulacoides (L.) Aellen and some effects on leaf ultrastructure. Reboredo F. Environ Sci Pollut Res Int. 2012 Feb 1. [Epub ahead of print] PMID: 22293906 [PubMed - as supplied by publisher]

  • What is the best bonding model of the (?-H-BR) species bound to a transition metal? Bonding analysis in complexes [(H)(2)Cl(PMe(3))(2)M(?-H-BR)] (M = Fe, Ru, Os). Pandey KK. Dalton Trans. 2012 Feb 24;41(11):3278-86. Epub 2012 Jan 31. PMID: 22290219 [PubMed - in process]

  • Electrocatalysis in proteins, nucleic acids and carbohydrates. Palecek E, Bartosík M, Ostatná V, Trefulka M. Chem Rec. 2012 Feb 10;12(1):27-45. doi: 10.1002/tcr.201100029. Epub 2012 Jan 30. PMID: 22287069 [PubMed - in process]

  • Electrochemical Surface Plasmon Resonance Measurement Based on Gold Nanohole Array Fabricated by Nanoimprinting Technique. Nakamoto K, Kurita R, Niwa O. Anal Chem. 2012 Jan 30. [Epub ahead of print] PMID: 22283116 [PubMed - as supplied by publisher]

  • A useful method for observing intracellular structures of free and cultured cells by scanning electron microscopy. Koga D, Nakajima M, Ushiki T. J Electron Microsc (Tokyo). 2012 Jan 18. [Epub ahead of print] PMID: 22257590 [PubMed - as supplied by publisher]

  • High-contrast en bloc staining of neuronal tissue for field emission scanning electron microscopy. Tapia JC, Kasthuri N, Hayworth KJ, Schalek R, Lichtman JW, Smith SJ, Buchanan J. Nat Protoc. 2012 Jan 12;7(2):193-206. doi: 10.1038/nprot.2011.439. PMID: 22240582 [PubMed - in process]

  • Estimation of the total number of hippocampal CA1 pyramidal neurons: New methodology applied to helpless rats. Miettinen R, Hajszan T, Riedel A, Szigeti-Buck K, Leranth C. J Neurosci Methods. 2012 Mar 30;205(1):130-8. Epub 2012 Jan 2. PMID: 22230770 [PubMed - in process]

  • Characterization of different FAD-dependent glucose dehydrogenases for possible use in glucose-based biosensors and biofuel cells. Zafar MN, Beden N, Leech D, Sygmund C, Ludwig R, Gorton L. Anal Bioanal Chem. 2012 Feb;402(6):2069-77. Epub 2012 Jan 6. PMID: 22222911 [PubMed - in process]

  • Luminescent bis-tridentate ruthenium(ii) and osmium(ii) complexes based on terpyridyl-imidazole ligand: synthesis, structural characterization, photophysical, electrochemical, and solvent dependence studies. Bhaumik C, Das S, Maity D, Baitalik S. Dalton Trans. 2012 Feb 28;41(8):2427-38. Epub 2012 Jan 4. PMID: 22218398 [PubMed - in process]

  • A comparison of glucose oxidase and aldose dehydrogenase as mediated anodes in printed glucose/oxygen enzymatic fuel cells using ABTS/laccase cathodes. Jenkins P, Tuurala S, Vaari A, Valkiainen M, Smolander M, Leech D. Bioelectrochemistry. 2011 Dec 7. [Epub ahead of print] PMID: 22200380 [PubMed - as supplied by publisher]

  • Bis{1,2-bis-[bis-(3-meth-oxy-prop-yl)phosphan-yl]ethane-?P,P'}dichlorido-osmium(II). Szymczak NK, Zakharov LN, Tyler DR. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1808. Epub 2011 Nov 23. PMID: 22199590 [PubMed - in process]

  • Storaged products and presence of acid phosphatase in fat body cells at pre-pupal worker stage of Apis mellifera Linnaeus, 1758 (Hymenoptera, Apidae). Poiani SB, da Cruz-Landim C. Micron. 2012 Feb;43(2-3):475-8. Epub 2011 Nov 26. PMID: 22172344 [PubMed - in process]




Recent Research & Development for Sulfur

  • Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube. Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN. Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print] PMID: 21822259 [PubMed - as supplied by publisher]

  • Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p). Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C. Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27. PMID: 21821903 [PubMed - in process]

  • Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids. Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J. Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print] PMID: 21821743 [PubMed - as supplied by publisher]

  • Characterization of the sulfurtransferase family from Oryza sativa L. Guretzki S, Papenbrock J. Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print] PMID: 21821426 [PubMed - as supplied by publisher]

  • Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek. Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T. J Microbiol Methods. 2011 Jul 28. [Epub ahead of print] PMID: 21821067 [PubMed - as supplied by publisher]

  • In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil. Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A. J Hazard Mater. 2011 Jul 6. [Epub ahead of print] PMID: 21820806 [PubMed - as supplied by publisher]

  • Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei. Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD. Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print] PMID: 21820408 [PubMed - as supplied by publisher]

  • The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates. Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C. Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159. PMID: 21818814 [PubMed - in process]

  • Sulphur isotopes in animal hair track distance to sea. Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O. Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131. PMID: 21818798 [PubMed - in process]

  • Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds. Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA. Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print] PMID: 21818792 [PubMed - as supplied by publisher]

  • Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond. Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C. J Gen Appl Microbiol. 2011;57(3):145-51. PMID: 21817826 [PubMed - in process]

  • Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources. Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE. Bioresour Technol. 2011 Jun 21. [Epub ahead of print] PMID: 21816612 [PubMed - as supplied by publisher]

  • Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province. Sullivan TJ, Cosby BJ, Jackson WA. J Environ Manage. 2011 Aug 2. [Epub ahead of print] PMID: 21816535 [PubMed - as supplied by publisher]

  • Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE. Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM. Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print] PMID: 21816081 [PubMed - as supplied by publisher]

  • Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells. Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC. Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print] PMID: 21815631 [PubMed - as supplied by publisher]

  • The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver. Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB. Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print] PMID: 21815229 [PubMed - as supplied by publisher]

  • A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability. Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA. Amino Acids. 2011 Aug 4. [Epub ahead of print] PMID: 21814788 [PubMed - as supplied by publisher]

  • Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume. Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J. ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print] PMID: 21814288 [PubMed - as supplied by publisher]

  • 1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives. Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y. Molecules. 2011 Aug 3;16(8):6502-11. PMID: 21814162 [PubMed - in process]

  • Towards the Growth of an Aligned Single-Layer MoS2 Film. Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L. Langmuir. 2011 Aug 3. [Epub ahead of print] PMID: 21812475 [PubMed - as supplied by publisher]

     

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