Tantalum Hafnium Carbide is generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Tantalum is a Block D, Group 5, Period 6 element. The number of electrons in each of Tantalum's shells is 2, 8, 18, 32, 11, 2 and its electronic configuration is [Xe] 4f14 5d3 6s2. In its elemental form tantalum's CAS number is 7440-25-7. The tantalum atom has a radius of 143.pm and it's Van der Waals radius is 200.pm. Tantalum is not toxic. Tantalum has a number of interesting properties that make it particularly useful in electronic applications. Tantalum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has the third highest melting point, surpassed only by rhenium and tungsten, yet it is highly conductive to heat and electricity. This has made it the material of choice for electronic capacitors for most telecommunications and hand held electronics equipment, such as cell phones, laptop computers and pagers. Tantalum compounds, such as the oxide and chloride, are the basis for di-electric coatings. Tantalum is added to glass for its high refractive index. It has various applications in nuclear energy. Due to the close relation of tantalum to niobium in the periodic table, Tantalum's name originates from the Greek word Tantalos meaning Father of Niobe in Greek mythology. See Tantalum research below. See Tantalum research below.
Hafnium is a Block D, Group 4, Period 6 element. The number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electronic configuration is [Xe] 4f14 5d2 6s2. In its elemental form hafnium's CAS number is 7440-58-6.The hafnium atom has a radius of 156.4.pm and it's Van der Waals radius is 200.pm. Hafnium is not toxic. Hafnium is one of the Group IV transition elements that is refined from various zirconic mineral deposits. Hafnium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It's primary uses are due to its ability as a nuclear "getter" or absorber of neutrons. It is a primary component in nuclear control rods for this purpose. It also finds uses as a dopant in the alloy of steel and titanium. It is also used in the production of mantles for high intensity incandescent lamps. Hafnium is replacing polysilicon as the principle gate or electrode material in metaloxide semiconductor field effect transistors (MOSFETs) which are the basis for all modern semiconductors. As semiconductors have gotten smaller, the limiting factor in further size reduction has been the ability of the silicon oxide gate to perform below 10 angstroms where leakage occurs. Recent research has been devoted to the development of High-k materials which can function as a di-electric barrier or gate with lower leakage. Using hafnium based alloys as this di-electric gate has allowed for the development of MOSFET gates smaller than 10 angstroms. This allows for further size reduction, reduced switching power requirements and improved performance. Hafnium was first discovered by Dirk Coster in 1923. See Hafnium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Mitral Valve Annuloplasty : A Quantitative Clinical and Mechanical Comparison of Different Annuloplasty Devices.
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Ann Biomed Eng. 2011 Oct 25. [Epub ahead of print]
PMID:
22037916
[PubMed - as supplied by publisher]
The Tetrahydrometalate Species VH2(H2), NbH4, and TaH4: Matrix Infrared Spectra and Quantum Chemical Calculations.
Wang X, Andrews L.
J Phys Chem A. 2011 Oct 24. [Epub ahead of print]
PMID:
22017260
[PubMed - as supplied by publisher]
Controlled Synthesis of Tantalum Oxynitride and Nitride Nanoparticles.
Gao Q, Giordano C, Antonietti M.
Small. 2011 Oct 19. doi: 10.1002/smll.201101207. [Epub ahead of print]
PMID:
22009942
[PubMed - as supplied by publisher]
Surgical Technique: Porous Tantalum Reconstruction for Destructive Nonprimary Periacetabular Tumors.
Khan FA, Rose PS, Yanagisawa M, Lewallen DG, Sim FH.
Clin Orthop Relat Res. 2011 Oct 12. [Epub ahead of print]
PMID:
21989784
[PubMed - as supplied by publisher]
Carbon Radical Generation by d(0) Tantalum Complexes with ?-Diimine Ligands through Ligand-Centered Redox Processes.
Tsurugi H, Saito T, Tanahashi H, Arnold J, Mashima K.
J Am Chem Soc. 2011 Oct 26. [Epub ahead of print]
PMID:
21981364
[PubMed - as supplied by publisher]
Trabecular metal cup without augments for acetabular revision in case of extensive bone loss and low bone-prosthesis contact.
Pierannunzii L, Mambretti A, D'Imporzano M.
Int J Immunopathol Pharmacol. 2011 Jan-Mar;24(1 Suppl 2):133-7.
PMID:
21669152
[PubMed - indexed for MEDLINE]
Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(N(t)Bu)(CH2R)2 with pentafluorophenol.
Cole JM, Chan MC, Gibson VC, Howard JA.
Acta Crystallogr B. 2011 Oct;67(Pt 5):416-24. Epub 2011 Aug 31.
PMID:
21931211
[PubMed]
Surgical Technique: A Cup-in-Cup Technique to Restore Offset in Severe Protrusio Acetabular Defects.
Blumenfeld TJ, Bargar WL.
Clin Orthop Relat Res. 2011 Sep 14. [Epub ahead of print]
PMID:
21915769
[PubMed - as supplied by publisher]
Tantalum (oxy)nitrides: Preparation, characterisation and enhancement of photo-Fenton-like degradation of atrazine under visible light.
Du Y, Zhao L, Su Y.
J Hazard Mater. 2011 Nov 15;195:291-7. Epub 2011 Aug 22.
PMID:
21885191
[PubMed - in process]
Prospective Results of Uncemented Tantalum Monoblock Tibia in Total Knee Arthroplasty Minimum 5-Year Follow-up in Patients Younger Than 55 Years.
Kamath AF, Lee GC, Sheth NP, Nelson CL, Garino JP, Israelite CL.
J Arthroplasty. 2011 Aug 25. [Epub ahead of print]
PMID:
21872424
[PubMed - as supplied by publisher]
X-ray absorption, photoemission spectroscopy, and Raman scattering analysis of amorphous tantalum oxide with a large extent of oxygen nonstoichiometry.
Tsuchiya T, Imai H, Miyoshi S, Glans PA, Guo J, Yamaguchi S.
Phys Chem Chem Phys. 2011 Oct 14;13(38):17013-8. Epub 2011 Aug 24.
PMID:
21863188
[PubMed - in process]
Evaluation of gene expression in MG63 human osteoblastlike cells exposed to tantalum powder by microarray technology.
Sollazzo V, Pezzetti F, Massari L, Palmieri A, Brunelli G, Zollino I, Lucchese A, Caruso G, Carinci F.
Int J Periodontics Restorative Dent. 2011 Jul-Aug;31(4):e17-28.
PMID:
21837296
[PubMed - in process]
Hemocompatibility investigation of the NiTi alloy implanted with tantalum.
Zhao T, Li Y, Gao Y, Xiang Y, Chen H, Zhang T.
J Mater Sci Mater Med. 2011 Oct;22(10):2311-8. Epub 2011 Aug 11.
PMID:
21833606
[PubMed - in process]
[Treatment of adult early femur head necrosis with the tantalum screw].
Luo HY, Chen CW.
Zhongguo Gu Shang. 2011 Jun;24(6):482-5. Chinese.
PMID:
21786551
[PubMed - indexed for MEDLINE]
A comparison of calibration methods for stereo fluoroscopic imaging systems.
Kaptein BL, Shelburne KB, Torry MR, Giphart JE.
J Biomech. 2011 Sep 2;44(13):2511-5. Epub 2011 Jul 23.
PMID:
21783196
[PubMed - in process]
Titanium and tantalum as mesenchymal stem cell scaffolds for spinal fusion: an in vitro comparative study.
Blanco JF, Sánchez-Guijo FM, Carrancio S, Muntion S, García-Briñon J, del Cañizo MC.
Eur Spine J. 2011 Aug;20 Suppl 3:353-60. Epub 2011 Jul 16.
PMID:
21779858
[PubMed - in process]
Synthetic and structural studies of monocyclopentadienyl cyclometalated aryl tantalum(V) compounds.
Galajov M, Galindo A, García C, Gómez M, Gómez-Sal P, Parra A.
Dalton Trans. 2011 Sep 7;40(33):8399-406. Epub 2011 Jul 22.
PMID:
21779602
[PubMed - in process]
Designing catalysts for nitrene transfer using early transition metals and redox-active ligands.
Heyduk AF, Zarkesh RA, Nguyen AI.
Inorg Chem. 2011 Oct 17;50(20):9849-63. Epub 2011 Jul 20.
PMID:
21774482
[PubMed - in process]
A randomised study of peri-prosthetic bone density after cemented versus trabecular fixation of a polyethylene acetabular component.
Periasamy K, Watson WS, Mohammed A, Murray H, Walker B, Patil S, Meek RM.
J Bone Joint Surg Br. 2011 Aug;93(8):1033-44.
PMID:
21768625
[PubMed - indexed for MEDLINE]
Bis(?-2-tert-butyl-phenyl-imido-1:2?N:N)chlorido-2?Cl-(diethyl ether-1?O)(2?-penta-methyl-cyclo-penta-dien-yl)lithiumtantalum(V).
Cole JM, Chan MC, Gibson VC, Howard JA.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m688-9. Epub 2011 May 7.
PMID:
21754594
[PubMed]