American Elements specializes in producing spray dry and non-spray dry high purity Ytterbium Oxide Powder with the smallest possible average grain sizes for use in preparation of pressed and bonded sputtering targets and in Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Powders are also useful in any application where high surface areasare desired such as water treatment and in fuel cell and solar applications. Nanoparticles (See also Nanotechnology Information and Quantum Dots) also produce very high surface areas. Our standard Powder particle sizes average in the range of - 325 mesh, - 100 mesh, 10-50 microns and submicron (< 1 micron) and our spray dried powder with binder provides an extremely narrow particle size distribution (PSD) for use in thermal and plasma spray guns and other coating applications. We can also provide many materials in the nanoscale range. We also produce Ytterbium Oxide as pellets, pieces, tablets, and sputtering target. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. See safety data and research below and pricing/lead time above. Other shapes are available by request.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 element. Ytterbium isbeing applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
Formula
CAS No.
Appearance
Molecular Weight
Density
Melting Point
Boiling Point
Solubility
Stability
Yb2O3
1314-37-0
White
394.08
9200 kg/m³
2435 °C
Insoluble in water, moderately soluble in strong mineral acids
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Bis(?(2)-2-phen-oxy-propionato-?O:O')bis-[(1,10-phenanthroline-?N,N')bis-(2-phen-oxy-propionato-?O,O')ytterbium(III)].
Shen JB, Liu JL, Zhao GL.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. Epub 2011 Sep 14.
PMID:
22058692
[PubMed]
"Covalency in the 4f Shell of tris-cyclopentadienyl Ytterbium (YbCp3) - a Spectroscopic Evaluation."
Denning RG, Harmer JR, Green JC, Irwin M.
J Am Chem Soc. 2011 Nov 4. [Epub ahead of print]
PMID:
22053917
[PubMed - as supplied by publisher]
Fingermark detection on non-porous and semi-porous surfaces using YVO(4):Er,Yb luminescent upconverting particles.
Ma R, Shimmon R, McDonagh A, Maynard P, Lennard C, Roux C.
Forensic Sci Int. 2011 Oct 31. [Epub ahead of print]
PMID:
22047749
[PubMed - as supplied by publisher]
Synthesis, Structure, and Reactivity of a Supramolecular Ytterbium(III)-Aqua Complex Featuring Infinite Stacks of C?C Bonds for Photocycloaddition Reactions.
Komori-Orisaku K, Yamashita S, Isozaki T, Sugiura K, Koide Y.
Chemistry. 2011 Oct 21. doi: 10.1002/chem.201102292. [Epub ahead of print] No abstract available.
PMID:
22021148
[PubMed - as supplied by publisher]
Label-free in vivo fiber-based optical-resolution photoacoustic microscopy.
Hajireza P, Shi W, Zemp RJ.
Opt Lett. 2011 Oct 15;36(20):4107-9. doi: 10.1364/OL.36.004107.
PMID:
22002401
[PubMed - in process]
Energy transfer and enhanced 1.54 ?m emission in Erbium-Ytterbium disilicate thin films.
Miritello M, Cardile P, Lo Savio R, Priolo F.
Opt Express. 2011 Oct 10;19(21):20761-72. doi: 10.1364/OE.19.020761.
PMID:
21997086
[PubMed - in process]
Photo darkening of rare earth doped silica.
Mattsson KE.
Opt Express. 2011 Oct 10;19(21):19797-812. doi: 10.1364/OE.19.019797.
PMID:
21996988
[PubMed - in process]
Beam quality and noise properties of coherently combined ytterbium doped single frequency fiber amplifiers.
Tünnermann H, Pöld JH, Neumann J, Kracht D, Willke B, Wessels P.
Opt Express. 2011 Sep 26;19(20):19600-6. doi: 10.1364/OE.19.019600.
PMID:
21996901
[PubMed - in process]
p-Wave Cold Collisions in an Optical Lattice Clock.
Lemke ND, von Stecher J, Sherman JA, Rey AM, Oates CW, Ludlow AD.
Phys Rev Lett. 2011 Sep 2;107(10):103902. Epub 2011 Aug 30.
PMID:
21981504
[PubMed - in process]
Mode-locked 0.5 ?J fiber laser at 976 nm.
Lhermite J, Lecaplain C, Machinet G, Royon R, Hideur A, Cormier E.
Opt Lett. 2011 Oct 1;36(19):3819-21. doi: 10.1364/OL.36.003819.
PMID:
21964108
[PubMed - in process]
Acid-responsive microcapsules: the loading-unloading processes.
Samanta D, Sankar RM, Jaisankar SN, Alam MS, Mandal AB.
Chem Commun (Camb). 2011 Oct 25;47(43):11975-7. Epub 2011 Sep 30.
PMID:
21963934
[PubMed - in process]
Electrochemical spectroscopic investigations on the interaction of an ytterbium complex with DNA and their analytical applications such as biosensor.
Ilkhani H, Ganjali MR, Arvand M, Hejazi MS, Azimi F, Norouzi P.
Int J Biol Macromol. 2011 Dec 1;49(5):1117-23. Epub 2011 Sep 16.
PMID:
21939686
[PubMed - in process]
A family of 13 tetranuclear zinc(ii)-lanthanide(iii) complexes of a [3 + 3] Schiff-base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene.
Feltham HL, Klöwer F, Cameron SA, Larsen DS, Lan Y, Tropiano M, Faulkner S, Powell AK, Brooker S.
Dalton Trans. 2011 Oct 25;40(43):11425-32. Epub 2011 Sep 21.
PMID:
21935549
[PubMed - in process]
Generation of 578-nm yellow light over 10 mW by second harmonic generation of an 1156-nm external-cavity diode laser.
Lee WK, Park CY, Yu DH, Park SE, Lee SB, Kwon TY.
Opt Express. 2011 Aug 29;19(18):17453-61. doi: 10.1364/OE.19.017453.
PMID:
21935111
[PubMed - in process]
In vivo near-realtime volumetric optical-resolution photoacoustic microscopy using a high-repetition-rate nanosecond fiber-laser.
Shi W, Hajireza P, Shao P, Forbrich A, Zemp RJ.
Opt Express. 2011 Aug 29;19(18):17143-50. doi: 10.1364/OE.19.017143.
PMID:
21935076
[PubMed - in process]
Self-referenceable frequency comb from a gigahertz diode-pumped solid-state laser.
Pekarek S, Südmeyer T, Lecomte S, Kundermann S, Dudley JM, Keller U.
Opt Express. 2011 Aug 15;19(17):16491-7. doi: 10.1364/OE.19.016491.
PMID:
21935013
[PubMed - in process]
Thermal effects in kilowatt all-fiber MOPA.
Fan Y, He B, Zhou J, Zheng J, Liu H, Wei Y, Dong J, Lou Q.
Opt Express. 2011 Aug 1;19(16):15162-72. doi: 10.1364/OE.19.015162.
PMID:
21934878
[PubMed - in process]
Background-free broadband CARS spectroscopy from a 1-MHz ytterbium laser.
Kumar V, Osellame R, Ramponi R, Cerullo G, Marangoni M.
Opt Express. 2011 Aug 1;19(16):15143-8. doi: 10.1364/OE.19.015143.
PMID:
21934875
[PubMed - in process]
Fabrication and characterization of new Yb-doped zirconia-germano-alumino silicate phase-separated nano-particles based fibers.
Kir'yanov AV, Paul MC, Barmenkov YO, Das S, Pal M, Bhadra SK, Zarate LE, Guzman-Chavez AD.
Opt Express. 2011 Aug 1;19(16):14823-37. doi: 10.1364/OE.19.014823.
PMID:
21934843
[PubMed - in process]
White emission of lithium ytterbium tetraphosphate nanocrystals.
Strek W, Marciniak L, Bednarkiewicz A, Lukowiak A, Wiglusz R, Hreniak D.
Opt Express. 2011 Jul 18;19(15):14083-92. doi: 10.1364/OE.19.014083.
PMID:
21934770
[PubMed - in process]
Material Safety Data Sheet
1 Identification of substance
Product details
Trade name Ytterbium oxide
2 Composition/Data on components:
Chemical characterization: Designation: (CAS#)
Ytterbium oxide (CAS# 1314-37-0), 100%
Identification number(s):
EINECS Number: 215-234-0
3 Hazards identification
Hazard designation: · void
Information pertaining to particular dangers for man and environment
Not applicable
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek medical treatment.
5 Fire fighting measures
Suitable extinguishing agents
Use fire fighting measures that suit the environment.
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Collect mechanically.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
No special precautions necessary if used correctly.
Information about protection against explosions and fires:
The product is not flammable
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
This product is hygroscopic.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Lump
Colour: White
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: 2227 ° C
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous) Product is not inflammable.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density at 20 ° C 9.17 g/cm³
Solubility in / Miscibility with
Water: Insoluble
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided:
Oxidizing agents
Carbon dioxide
Dangerous reactions: No dangerous reactions known
Dangerous products of decomposition: None known.
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Powder: irritant effect
on the eye: Powder: irritant effect
Sensitization: No sensitizing effect known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Generally not hazardous for water.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
ADR/RID-GGVS/E Class: None
Maritime transport IMDG/GGVSea:
IMDG/GGVSea Class: None
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: None
Transport/Additional information:
Not dangerous according to the above specifications.
15 Regulatory information
Designation according to EC guidelines:
Observe the normal safety regulations when handling chemicals
The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Water hazard class: Generally not hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Lanthanide reagents in solid phase synthesis. Chem Soc Rev. 2006 Dec;35(12):1221-9. Epub 2006 Jun 28.
Second-harmonic generation of light at 544 and 272 nm from an ytterbium-doped distributed-feedback fiber laser. Opt Lett. 2007 Feb 1;32(3):268-70.
Synthesis, structure and oxidation of new ytterbium(ii) bis(phenolate) compounds and their catalytic activity towards epsilon-caprolactone. Dalton Trans. 2007 Jan 7;(1):143-53. Epub 2006 Nov 7.
Role of donor and secondary interactions in the structures and thermal properties of alkaline-earth and rare-earth metal pyrazolates. Inorg Chem. 2006 Dec 11;45(25):10329-37.
Lanthanide-transition metal carbonyl complexes: condensation of solvent-separated ion-pair compounds into extended structures. Inorg Chem. 2006 Dec 11;45(25):10115-25.
Sensitized near-infrared lanthanide luminescence from Nd(III)- and Yb(III)-based cyclen-ruthenium coordination conjugates. Inorg Chem. 2006 Dec 11;45(25):10040-2.
Quenching of IR luminescence of erbium, neodymium, and ytterbium beta-diketonate complexes by ligand C-H and C-D bonds. J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Dec 7;110(48):24476-9.
Heterobimetallic Zn(II)-Ln(III) phenylene-bridged schiff base complexes, computational studies, and evidence for singlet energy transfer as the main pathway in the sensitization of near-infrared Nd3+ luminescence. Inorg Chem. 2006 Nov 13;45(23):9315-25.
Experimental demonstration of novel end-pumping method for double-clad fiber devices. Opt Lett. 2006 Nov 15;31(22):3240-2.
Reactions of hypersilyl potassium with rare-earth metal bis(trimethylsilylamides): addition versus peripheral deprotonation. Inorg Chem. 2006 Oct 30;45(22):9085-95.
American Elements specializes in producing spray dry and non-spray dry high purity Ytterbium Oxide Powder with the smallest possible average grain sizes for use in preparation of pressed and bonded sputtering targets and in Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Powders are also useful in any application where high surface areas 
are desired such as water treatment and in fuel cell and solar applications. Nanoparticles (See also Nanotechnology Information and Quantum Dots) also produce very high surface areas. Our standard Powder particle sizes average in the range of - 325 mesh, - 100 mesh, 10-50 microns and submicron (< 1 micron) and our spray dried powder with binder provides an extremely narrow particle size distribution (PSD) for use in thermal and plasma spray guns and other coating applications. We can also provide many materials in the nanoscale range. We also produce Ytterbium Oxide as pellets, pieces, tablets, and sputtering target. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. See safety data and research below and pricing/lead time above. Other shapes are available by request.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 
element. Ytterbium is
being applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
